Results 181 to 190 of about 1,117 (251)

Layered π Systems Based on Ferrocenophanes

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Syntheses of a variety of ferrocenophanes and extensions of their π systems are reported. These are performed by Knoevenagel reactions and predominantly lead to syn diastereomers. Eight ferrocenophanes were crystallographically characterized. [1.1]Ferrocenophane was prepared by the literature method along with a small amount of [1.1.1.1]ferrocenophane,
Wing‐Yin Tsang, Holger Butenschön
wiley   +1 more source

Synthesis and Structural Study of Iodonium Ylides Derived From 2‐Iodosylbenzenesulfonic Acid: Reagents for Preparation of Annulated Thiazoles

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
New ylides of two different types were prepared by reaction of 2‐iodosylbenzenesulfonic acid with the corresponding 1,3‐cyclohexanediones under acidic or basic conditions. These compounds have a typical for iodonium ylides structure with the CIC angles 94.18° –97.25° and the IC bond distances between 2.08 and 2.13 Å.
Dmitry M. Noskov   +7 more
wiley   +1 more source

Sustainable Iron Catalysis for Chemodivergent Oxidation of Lignin‐Based Vanillyl Alcohol: Selective Access to Vanillin and Vanillic Acid

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Green reaction media enable chemodivergent oxidation of vanillyl alcohol, selectively affording vanillin or its fully oxidized counterpart, vanillic acid. The use of an earth‐abundant, inexpensive, and nontoxic iron catalyst for the transformation of lignin‐derived alcohol to fine chemicals underscores the sustainability of the process. A low E‐factor (
Rasmiranjan Hota   +2 more
wiley   +1 more source

Strategies for Identification and Mitigation of Sanguinarine in Mustard Oil Adulterated by Argemone—A Comprehensive Review

open access: yesFood Chemistry International, EarlyView.
Sanguinarine, a toxic alkaloid present in argemone, can lead to epidemic dropsy or chronic diseases through DNA intercalation and immune system suppression. Regulatory efforts face challenges due to economic motivations for adulteration as well as technical, social, and infrastructure barriers.
Gururaj Pejavara Narayana   +4 more
wiley   +1 more source

Spirobifluorene fusion in multiple resonance frameworks enables efficient pure‐red OLEDs with narrowband emission and suppressed efficiency roll‐off

open access: yesFlexMat, EarlyView.
An orthogonal spirobifluorene‐fusion strategy is introduced for B/N/O‐alternated MR frameworks, enabling improved kRISC (5.46 × 103 s−1), high ΦPL (97%), and narrow‐band pure‐red emission. Vacuum‐evaporated OLEDs incorporating this emitter achieve an EQEmax >40% (FWHM = 36 nm) and exhibit exceptionally low efficiency roll‐off at high luminance ...
Yan‐Yun Jing   +7 more
wiley   +1 more source

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