Results 121 to 130 of about 128,452 (331)

3-Formylchromones as diverse building blocks in heterocycles synthesis [PDF]

open access: diamond, 2013
Tarik E. Ali   +3 more
openalex   +1 more source

Hydroxylated Rh Single‐Atom Antennas Assembled on Carbon Nitride Toward Stable Photocatalytic Hydrogen Evolution

open access: yesAdvanced Science, EarlyView.
PCN‐Rh single‐atom catalyst shows a dual‐cycle reaction path for photocatalytic hydrogen evolution (PHE). PCN‐Rh‐0.5 achieves 32.5 times the PHE rate of PCN/Pt, which exhibits a longer operation time (192 h) with a higher amount of hydrogen production (654.5 mmol g−1) than the reported PCN‐based single‐atom catalysts and other high‐stability catalysts ...
Chunmei Li   +8 more
wiley   +1 more source

A Generalized Approach for Distal C–H Arylation of Organic Building Blocks: Unveiling the Role of Counter Anion

open access: yesAdvanced Science, EarlyView.
We report a general strategy for meta‐selective C–H arylation using aryl iodides and a Pd(II)/Pd(IV) catalytic system guided by a removable directing group. DFT and experimental studies reveal that counter anion tuning (acetate to trifluoroacetate) significantly enhances selectivity.
Jagrit Grover   +6 more
wiley   +1 more source

Toward Charge-neutral ‘soft scorpionates’: Coordination Chemistry and Lewis Acid Promoted Isomerization of tris(1-organo-imidazol-2-ylthio)methanes [PDF]

open access: yes, 2009
Two tris(1-organo-imidazol-2-ylthio)methanes, HC(S-timR)3 (R = organo = methyl, tert-butyl), have been prepared by a triphasic reaction between chloroform, the appropriate heterocycle, and saturated aqueous solutions of Na2CO3, in the presence of a phase
Gardinier, James R.   +4 more
core   +1 more source

Photochromic Molybdate for Advancing Anode Capacity of Lithium‐Ion Battery

open access: yesAdvanced Science, EarlyView.
Photochromic polyoxomolybdate is first used to enhance the anode capacity and rate performance of Li‐ion batteries. Abstract Decoupling strategies can effectively enhance lithium‐ion battery (LIB) capacity, but suffer from the need for complex equipment, preventing widespread applicability. This work offers, for the first time, a decoupling strategy of
Xiao‐Yue Zhang   +4 more
wiley   +1 more source

Enzyme‐Inspired Hydrogen‐Bonded Organic Frameworks for Synergistic Capture, Detection, and Degradation of Nerve Agent Simulants

open access: yesAdvanced Science, EarlyView.
FDU‐HOF‐5, an enzyme‐inspired hydrogen‐bonded framework, enables targeted capture, real‐time visual alert, and detoxification of nerve agent simulants through biomimetic sites and multivalent interactions. Integrable into protective gear, it pioneers on‐site threat monitoring strategies for persistent neurotoxic hazards, advancing smart, responsive ...
Jiabao Liu   +14 more
wiley   +1 more source

<em>In silico</em> study of thiophenic heterocycles against <em>Staphylococcus aureus</em> targets [PDF]

open access: hybrid, 2019
Alex Monteiro   +6 more
openalex   +1 more source

Dirhenium Carbonyl Complexes Bearing 2-Vinylpyridine, Morpholine and 1-Methylimidazole Ligands [PDF]

open access: yes, 2008
Treatment of the labile compound [Re2(CO)8(MeCN)2] with 2-vinylpyridine in refluxing benzene affords exclusively the new compound [Re2(CO)8(μ-η1:η2-NC5H4CHCH2)] (1) in 39% yield in which the μ-η1:η2-vinylpyridine ligand is coordinated to one Re atom ...
Ahmed, Faruque   +7 more
core   +1 more source

Electronic Modulation of K⁺‐Intercalated Polymeric Carbon Nitride via ─C≡N/─OH Functionalization for Efficient Photocatalytic H2O2 Production

open access: yesAdvanced Science, EarlyView.
K+ is successfully embedded in the PCN interlayers via a high‐temperature polymerization. The incorporation of K+ perturbs the local electronic structure via interaction with nitrogen lone pairs, narrowing the PCN bandgap, which exhibits superior photocatalytic performance, achieving a high H2O2 generation rate both in situ and under sunlight ...
Qingquan Xue   +8 more
wiley   +1 more source

Unsupervised Hierarchical Symbolic Regression for Interpretable Property Modeling in Complex Multi‐Variable Systems

open access: yesAdvanced Science, EarlyView.
UHSR translates complex chemical behavior into clear and explainable equations. Applied to thin‐layer chromatography, it automatically uncovers the mathematical rules linking a molecule's structure to its polarity. This approach matches the accuracy of advanced AI while providing interpretable results, earning greater trust from chemists. The method is
Siyu Lou   +4 more
wiley   +1 more source

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