Results 11 to 20 of about 23,536 (214)
2‐Nitrobenzyl Isocyanide as a Universal Convertible Isocyanide [PDF]
Asian Journal of Organic Chemistry, 2017 Abstract2‐Nitrobenzyl isocyanide is reported as a universal convertible isocyanide with extensive applicability in both Ugi four‐component reaction (Ugi‐4CR) and Ugi‐tetrazole reaction. The cleavage of this isocyanide from 17 examples in both acidic and basic conditions is presented.
Chandgude +3 more
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Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex
Crystals, 2022 Gold(I) isocyanide complexes featuring Au···Au interactions attract considerable attention because of their tunable photophysical properties. Although the synthetic exploration of isocyanide gold(I) complexes seems reasonable, their structural diversity ...
Mariya V. Grudova +6 more
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The mode of action of isocyanide in three aquatic organisms, Balanus amphitrite, Bugula neritina and Danio rerio. [PDF]
PLoS ONE, 2012 Isocyanide is a potential antifouling compound in marine environments. In this study, we investigated its mode of action in three aquatic organisms. Two of them, the bryozoan Bugula neritina and the barnacle Balanus amphitrite, are major marine fouling ...
Yi-Fan Zhang +4 more
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Synthesis, Characterization and Chemistry of Tetrakis(Propargylisocyanide) Copper(I) Complex
Molbank, 2023 The kinetically unstable propargylisocyanide was reacted with the tetrakis(acetonitrile) copper(I) hexafluorophosphate and the formed complex was then involved in a copper-catalyzed alkyne-azide cycloaddition reaction (CuAAC). After the decomplexation of
Alexandre Quelhas +3 more
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Molecules, 2023 Four couples of 5,6-membered bis(metallacyclic) Pt(II) complexes with acetylide and isocyanide auxiliary ligands have been prepared and characterized.
Jing Jing +7 more
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ChemInform Abstract: Efficient Isocyanide‐Less Isocyanide‐Based Multicomponent Reactions. [PDF]
ChemInform, 2015 AbstractFormamides are found to be a general substitute for the toxic and bad smelling isocyanides in Passerini‐ and Ugi‐type multicomponent reactions.
Neochoritis +4 more
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Isocyanides: Promising Functionalities in Bioorthogonal Labeling of Biomolecules
Frontiers in Chemistry, 2021 Isocyanides have drawn increasing attention in biological applications due to their attractive properties and unique reactivities, which can undergo various reactions, such as multicomponent reactions, α-addition reactions, [4 + 1] cycloaddition ...
Yuchen Zhu +6 more
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Green Chemistry, 2020 Isocyanides are important chemicals, with limited availability, thus reducing their general use. Our highly improved isocyanide synthesis performed on mole to μ-mole scale, individually or in a 96-well parallel fashion enables unprecedented exploration of novel chemistries.
Pravin Patil +2 more
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Magnesium Cyanide or Isocyanide? [PDF]
Angewandte Chemie International Edition, 2019 AbstractPreference for the binding mode of the CN− ligand to Mg (Mg−CN vs. Mg−NC) is investigated. A monomeric Mg complex with a terminal CN ligand was prepared using the dipyrromethene ligand MesDPM which successfully blocks dimerization. While reaction of (MesDPM)MgN(SiMe3)2 with Me3SiCN gave the coordination complex (MesDPM)MgN(SiMe3)2⋅NCSiMe3 ...
Gerd Ballmann +2 more
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Divergent isoindolinone synthesis through palladium-catalyzed isocyanide bridging C–H activation
Cell Reports Physical Science, 2022 Summary: The formation of thermodynamically accessible metallacycle is crucial to achieve site-selective C–H bond activation. Here, we report an isocyanide-bridging C–H activation through the formation of a five-membered palladacycle. As such, a proximal
Fulin Zhang +6 more
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