Results 41 to 50 of about 22,465 (222)
Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium [PDF]
, 2021 The reaction of [U(NR2)3] (R = SiMe3) with 2 equiv of 2,6-dimethylphenyl isocyanide results in the isolation of the U(III) bis(isocyanide) complex [U(NR2)3(CNXyl)2] (1) in 50% yield.
Trevor W. Hayton +11 more
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Isocyanide-Based Multicomponent Reactions for the Synthesis of Heterocycles
Molecules, 2015 Multicomponent reactions (MCRs) are extremely popular owing to their facile execution, high atom-efficiency and the high diversity of products. MCRs can be used to access various heterocycles and highly functionalized scaffolds, and thus have been ...
András Váradi +3 more
doaj +1 more source
Blue Phosphorescence from Mixed Cyano−Isocyanide Cyclometalated Iridium(III) Complexes [PDF]
, 2016 The synthesis, structure, and photophysical and electrochemical properties of cyclometalated iridium complexes with ancillary cyano and isocyanide ligands are described.
Peter Y. Zavalij (616937) +4 more
core +3 more sources
Molecules, 2017 A facile access to polysubstituted 3-(isoxazol-5-yl)pyrroles was developed through [3+2] cycloaddition of tosylmethyl isocyanide (TosMIC) and styrylisoxazoles.
Xueming Zhang, Xianxiu Xu, Dawei Zhang
doaj +1 more source
Molecules, 2023 α-Ketoamide moieties, as privileged units, may represent a valuable option to develop compounds with favorable biological activities, such as low toxicity, promising PK and drug-like properties.
Jia Xu +6 more
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Isocyanide-based Multicomponent Reactions [PDF]
, 2020 This eBook is a collection of articles from a Frontiers Research Topic. Frontiers Research Topics are very popular trademarks of the Frontiers Journals Series: they are collections of at least ten articles, all centered on a particular subject.
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Stefano Marcaccini: a pioneer in isocyanide chemistry [PDF]
, 2023 Comprehensive ReviewStefano Marcaccini was one of the pioneers in the use of isocyanide-based multicomponent reactions in organic synthesis. Throughout his career at the University of Florence he explored many diferent faces of isocyanide chemistry ...
Díaz, Jesús +4 more
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From Isocyanides to Iminonitriles via Silver-mediated Sequential Insertion of C(sp3)–H Bond
iScience, 2019 Summary: Heterocycles are prevalent constituents of many marketing drugs and biologically active molecules to meet modern medical challenges. Isocyanide insertion into C(sp3)–H bonds is challenging especially for the construction of quaternary carbon ...
Huiwen Chi +7 more
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Reaction between Indazole and Pd-Bound Isocyanides—A Theoretical Mechanistic Study
Molecules, 2018 The mechanism of the addition of indazole (Ind)—a bifunctional aromatic N,NH-nucleophile—to cyclohexyl isocyanide coordinated to the palladium(II) center in the model complex cis-[PdCl2(CNMe)(CNCy)] (1) to give the corresponding aminocarbene ...
Girolamo Casella +3 more
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Palladium-Catalyzed Synthesis of Amidines via tert-Butyl isocyanide Insertion [PDF]
, 2018 Para-substituted iodobenzenes were reacted with tert-butyl isocyanide and piperidine as nucleophiles in the presence of palladium−diphosphine catalysts.
Noémi Pálinkás +8 more
core +1 more source