Results 41 to 50 of about 28,542 (223)
Ugi multicomponent reaction to prepare peptide–peptoid hybrid structures with diverse chemical functionalities [PDF]
, 2018 Monodisperse sequenced peptides and peptoids present unique nano-structures based on their self-assembled secondary and tertiary structures. However, the generation of peptide and peptoid hybrid oligomers in a sequence-defined manner via Ugi ...
Azevedo, Helena S. +12 more
core +1 more source
Angewandte Chemie, EarlyView.This work details the rapid generation (t ≤ 5 min) of size‐tunable, ultralow dispersity (Ð ≤ 1.01) 2D hexagonal nanosheets by self‐limiting polymerization‐induced crystallization‐driven self‐assembly (SL‐PI‐CDSA) of modular and templating poly(aryl isocyanide) block copolymers, with functions that permit post‐polymerization modifications. Specifically,
Randall A. Scanga +13 more
wiley +2 more sources
The Chemistry of Phenylimidotechnetium(V) Complexes with Isocyanides: Steric and Electronic Factors
Molecules, 2022 Organometallic approaches are of ongoing interest for the development of novel functional 99mTc radiopharmaceuticals, while the basic organotechnetium chemistry seems frequently to be little explored. Thus, structural and reactivity studies with the long-
Guilhem Claude +5 more
doaj +1 more source
d8···d10 RhI···AuI Interactions in Rh 2,6-Xylylisocyanide Complexes with [Au(CN)2]: Bond Analysis and Crystal Effects [PDF]
, 2019 Producción CientíficaThe well known [RhL4]n(anion)n structures, with RhI···RhI d8···d8 interactions, are replaced by others with RhI···AuI d8···d10 interactions such as [{RhL4}{Au(CN)2}] (L = 2,6-Xylylisocyanide) or [{RhL4}{Au(CN)2} {RhL4}{Au2(CN)3}·4(
Conejo Rodríguez, Verónica +2 more
core +2 more sources
(tert-Butyl isocyanide-κC)trichloridogallium(III)
IUCrData, 2016 The crystal structure of (tert-butyl isocyanide-κC)trichloridogallium(III), [GaCl3(C5H9N)], features the first reported isocyanide–gallium trihalide complex. The Ga—C—N—C fragment is essentially linear.
Jeremy L. Bourque +2 more
doaj +1 more source
Mitochondria as a Potential Antifungal Target for Isocyanide Compounds [PDF]
, 2020 The discovery of antibiotics and antifungals greatly impacted medicine and human health, allowing the effective treatment of infections that were previously deadly. However, due to routine and sometimes excessive usage of these compounds, the development
Berkowitz, David +5 more
core +1 more source
Medicinal Chemistry of Isocyanides [PDF]
Chemical Reviews, 2021 In eons of evolution, isocyanides carved out a niche in the ecological systems probably thanks to their metal coordinating properties. In 1859 the first isocyanide was synthesized by humans and in 1950 the first natural isocyanide was discovered. Now, at the beginning of XXI century, hundreds of isocyanides have been isolated both in prokaryotes and ...
Alberto Massarotti +4 more
openaire +4 more sources
Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
Acta Crystallographica Section E, 2008 The title compound, [Ni(C5H9N)3(CO)], was prepared from Ni(CO)4 and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent molecules per asymmetric unit.
Wolfgang Imhof +2 more
doaj +1 more source
13C-Methyl isocyanide as an NMR probe for cytochrome P450 active site [PDF]
, 2009 The cytochromes P450 (CYPs) play a central role in many biologically important oxidation reactions, including the metabolism of drugs and other xenobiotic compounds.
Im, Sang-Choul +4 more
core +2 more sources
Isocyanide-Based Multicomponent Reactions for the Synthesis of Heterocycles
Molecules, 2015 Multicomponent reactions (MCRs) are extremely popular owing to their facile execution, high atom-efficiency and the high diversity of products. MCRs can be used to access various heterocycles and highly functionalized scaffolds, and thus have been ...
András Váradi +3 more
doaj +1 more source