Results 61 to 70 of about 321 (141)

Tracking Photocatalytic Pathways With In Situ Surface‐Enhanced Raman Spectroscopy

open access: yesTransformative Chemistry, EarlyView.
In situ SERS captures surface molecular fingerprints during photocatalysis, revealing transient intermediates, bond evolution, pathway selectivity, and charge‐coupled molecular transformation beyond catalyst‐ or product‐centered characterization. This review maps SERS‐active platforms and future site‐specific, time‐resolved, intelligent strategies for ...
Chenyang Gao   +5 more
wiley   +1 more source

Isocyanides as a Chemical Tool for Identifying [Fe]‐Hydrogenase‐Dependent Methanogenesis

open access: yesChemBioChem, Volume 27, Issue 17, 14 September 2026.
In model methanogens, [Fe]‐hydrogenase (Hmd) substitutes nickel‐dependent hydrogenases under nickel‐limited conditions. We determined the inhibitory effects of the Hmd inhibitor, isocyanides, on methanogenesis in a cell extract and in a cell suspension.
Shunsuke Nomura, Seigo Shima
wiley   +1 more source

A Chemical Framework for Engineering Extracellular Vesicles’ Biointerface to Advance Precision Therapeutics

open access: yesAdvanced Materials, Volume 38, Issue 52, 16 September 2026.
Extracellular vesicles (EVs) are cell‐derived nanoparticles that mediate intercellular communication through their dynamic biointerfaces. Owing to their intrinsic biological functions, EVs have emerged as promising platforms for biomedical applications.
Leila Pourtalebi Jahromi   +3 more
wiley   +1 more source

2D Rhodium‐Isocyanide Frameworks

open access: yesAdvanced Materials
Abstract 2D metal‐organic frameworks (2D MOFs) are emerging organic van der Waals materials with great potential in various applications owing to their structural diversity, and tunable optoelectronic properties.
Senhe Huang   +13 more
openaire   +3 more sources

A New Method for the Synthesis of 1-(1-Isocyanoethyl)adamantane

open access: yesMolbank
A novel single-step method has been developed for the synthesis of 1-(1-isocyanoethyl)adamantane from 1-(1-adamantylethyl)amine, chloroform, and t-BuOK, in a dichloromethane/tert-butanol (1:1) medium, yielding 92%, which is 27% higher compared to the ...
Dmitry Pitushkin, Gennady Butov
doaj   +1 more source

A One-Pot Synthesis of Oxazepine-Quinazolinone bis-Heterocyclic Scaffolds via Isocyanide-Based Three-Component Reactions

open access: yesFrontiers in Chemistry, 2019
A novel, efficient and environmentally friendly approach has been developed for the synthesis of biologically important bis-heterocyclic oxazepine-quinazolinone derivatives.
Shabnam Shaabani   +3 more
doaj   +1 more source

An Intramolecular Frustrated Lewis‐Pair Based on a Bismuth(III) Acid Site

open access: yesChemistryEurope, Volume 4, Issue 9, September 2026.
Triflate ligands were the key for the design of a frustrated Lewis pair (FLP) that utilizes a soft bismuth(III) center as the Lewis acidic site. The acceptor properties are based on empty p orbitals generated through the ionic binding of the triflate anions to the Bi center.
Martin Borowski   +6 more
wiley   +1 more source

Facile synthesis of 1H-imidazo[1,2-b]pyrazoles via a sequential one-pot synthetic approach

open access: yesBeilstein Journal of Organic Chemistry, 2014
5-Aminopyrazole-4-carbonitrile and ethyl 5-aminopyrazole-4-carboxylate, as potential trifunctional building blocks are introduced in a facile, chemo- and regioselective multicomponent assembly of imidazo[1,2-b]pyrazoles via the Groebke–Blackburn–Bienaymé
András Demjén   +4 more
doaj   +1 more source

Crystal structure of heptakis(2,6-dimethylphenyl isocyanide-κC)vanadium(I) iodide

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title salt, [V(C9H9N)7]+I− or [V(CNXyl)7]+I− (Xyl is 2,6-dimethylphenyl), crystallized from tetrahydrofuran at low temperatures after reacting (Et4N)+[V(CO)6]−, excess of CNXyl and iodine. The complex cation and the two crystallographically different
Mikhail E. Minyaev, John E. Ellis
doaj   +1 more source

Retro‐Hetero‐Michael Addition Strategies in Organic Synthesis

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 32, 24 August 2026.
In this review, synthetic approaches to carbo‐ and heterocyclic compounds, including natural products, published in the last 15 years (2011–2025) which have either relied upon or included a retro‐hetero‐Michael addition step at any stage are discussed.
Dina Scarpi, Ernesto G. Occhiato
wiley   +1 more source

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