Results 61 to 70 of about 22,422 (224)
A Rh(III)‐catalyzed [4 + 2] annulation of 2‐aryl imidazoles/benzimidazoles with α‐diazocarbonyl compounds is developed for the synthesis of π‐conjugated imidazo/benzimidazo[2,1‐a]isoquinolinones systems. Mechanistic studies and control experiment reveal that the reaction proceeds via imidazole‐directed ortho C(sp2)–H activation, followed by carbene C–H
Ganesh P. Pawar +4 more
wiley +1 more source
Reductive Coupling of Xylyl Isocyanide Mediated by Low-Valent Uranium
The reaction of [U(NR2)3] (R = SiMe3) with 2 equiv of 2,6-dimethylphenyl isocyanide results in the isolation of the U(III) bis(isocyanide) complex [U(NR2)3(CNXyl)2] (1) in 50% yield.
Trevor W. Hayton +11 more
core +1 more source
Fungal Isocyanide Synthases and Xanthocillin Biosynthesis in
Microbial secondary metabolites, including isocyanide moieties, have been extensively mined for their repertoire of bioactive properties. Although the first naturally occurring isocyanide (xanthocillin) was isolated from the fungus Penicillium notatum ...
Fang Yun Lim +7 more
doaj +1 more source
Superlattice Architectures for Advancing Photothermal Catalysis: Mechanisms and Applications
This paper provides a timely overview of superlattice architectures in photothermal catalysis, with a systematic review on mechanisms at both atomic and macroscopic scales in different processes, challenges, and future opportunities. ABSTRACT Photothermal catalysis has emerged as a powerful strategy to complement photocatalysis by harnessing full ...
Yuzhao Wu +5 more
wiley +1 more source
Blue Phosphorescence from Mixed Cyano−Isocyanide Cyclometalated Iridium(III) Complexes
The synthesis, structure, and photophysical and electrochemical properties of cyclometalated iridium complexes with ancillary cyano and isocyanide ligands are described.
Peter Y. Zavalij (616937) +4 more
core +2 more sources
Isocyanide-based Multicomponent Reactions
This eBook is a collection of articles from a Frontiers Research Topic. Frontiers Research Topics are very popular trademarks of the Frontiers Journals Series: they are collections of at least ten articles, all centered on a particular subject.
core +1 more source
Stefano Marcaccini: a pioneer in isocyanide chemistry
Comprehensive ReviewStefano Marcaccini was one of the pioneers in the use of isocyanide-based multicomponent reactions in organic synthesis. Throughout his career at the University of Florence he explored many diferent faces of isocyanide chemistry ...
Díaz, Jesús +4 more
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Smiles/Pudovik/Phospha–Brook Cascades from Passerini–Smiles Adducts
The Passerini–Smiles reaction of aliphatic ketophosphonates affords starting materials for complex cascades triggered by a first Smiles rearrangement. The cascade showcases the power of phosphorous based transformations. Here the reversibility of the Pudovik reaction allows a further Truce–Smiles reaction enol before final Pudovik/Phosph–Brook sequence.
Cristina Cheibas +2 more
wiley +1 more source
Optimized Conditions for Passerini-Smiles Reactions and Applications to Benzoxazinone Syntheses
Initial conditions disclosed for the Passerini-Smiles reaction are associated with a lack of efficiency that has prevented chemists from using it since its discovery.
Elodie Martinand-Lurin +6 more
doaj +1 more source
Fungal‐Bacterial Interactions in Polymicrobial Infections: Hidden Threats
ABSTRACT Polymicrobial infections involving fungi and bacteria represent a major and increasingly recognized clinical challenge, in which interkingdom interactions significantly amplify disease severity, antimicrobial resistance, and treatment failure. Rather than passive co‐existence, fungal–bacterial communities form highly coordinated systems driven
Mohammad Javad Roustaye Gourabi +3 more
wiley +1 more source

