Results 61 to 70 of about 28,542 (223)
Cationic complexes of platinum and palladium with p-tolyl isocyanide [PDF]
, 1977 Cationic complexes of platinum and palladium of the type [MCl(p-CH3C6H4NC)L2]ClO4 (M = Pt, Pd; L = p-tolyl3P, o-tolyl3P, Cy3P, Ph2MeAs, Ph2EtAs, Ph2PrAs, Cy3As; Cy = cyclohexyl) have been isolated. These show a v(CN) band at ca.
Gowda, N.M.N. +2 more
core +1 more source
Palladium(II)-Mediated Addition of Benzenediamines to Isocyanides: Generation of Three Types of Diaminocarbene Ligands Depending on the Isomeric Structure of the Nucleophile [PDF]
, 2016 Coupling of the palladium-bis(isocyanide) complexes cis-[PdCl2(CNR)2] (R = 2,6-Me2C6H3 1, 2-Cl-6-MeC6H3 2) with benzene-1,3-diamine (BDA1) leads to the diaminocarbene species cis-[PdCl2(CNR){C(NHR)NH(1,3-C6H4NH2)}] (5 and 6, respectively).
Boyarskiy, Vadim P +6 more
core +8 more sources
Isonitrile-responsive and bioorthogonally removable tetrazine protecting groups. [PDF]
, 2020 In vivo compatible reactions have a broad range of possible applications in chemical biology and the pharmaceutical sciences. Here we report tetrazines that can be removed by exposure to isonitriles under very mild conditions.
Eckvahl, Hannah J +7 more
core
Isocyano-triphenylene complexes of gold, copper, silver and platinum. Coordination features and mesomorphic behavior [PDF]
, 2016 Producción CientíficaStable organometallic complexes [AuX(CN-TriPh)] [X = Cl, C6F5, C6F4O-C10H21), C6F4O- (R)-2-octyl)], [(-4,4’-C6F4C6F4){Au(CN-TriPh)}2], [AuX(CN-TriPh)], [CuCl(CN-TriPh)], trans-[PtI2(CN-TriPh)2] and [Ag(CN-TriPh)2]BF4, bearing the ...
Benoît Heinrich (1315245) +5 more
core +6 more sources
Gold Liquid Crystals in the XXI Century
Inorganics, 2014 Since the first gold liquid crystal was described in 1986, much effort has been done to prepare new compounds bearing this property. The review deals with the last results obtained in this new century.
Manuel Bardají
doaj +1 more source
Angewandte Chemie International Edition, EarlyView.Cross‐coupling/homologation sequence between a stable three‐membered‐ring carbene and isocyanides enables facile and rapid access to novel methyleneketenimines and the first bis(methyleneketenimine). Reactivity studies gave rise to the first methyleneketenimine‐transition metal complexes, unique multimodal reactivity ranging from CO2, isocyanate ...
Taichi Koike +3 more
wiley +1 more source
Synthesis of 3-aminoimidazo[1,2-a]pyridines via three-component reaction in the 2,2,2-trifluoroethanol-water two-phase systems [PDF]
شیمی کاربردی روز, 2020 An efficient synthesis of 3-aminoimidazo[1,2-a]pyridines via three-component reaction from aromatic aldehydes, 2-aminopyridines and isonitriles at room temperature in water/2,2,2-trifluoroethanol two-phase systems is described.
Mobina Alizade-Majd +2 more
doaj +1 more source
, 2015 We present a systematic ab-initio study of the length dependence of the thermopower in molecular junctions. The systems under consideration are small saturated and conjugated molecular chains of varying length attached to gold electrodes via a number of ...
Hüser, Falco, Solomon, Gemma C.
core +2 more sources
Molecules, 2023 α-Ketoamide moieties, as privileged units, may represent a valuable option to develop compounds with favorable biological activities, such as low toxicity, promising PK and drug-like properties.
Jia Xu +6 more
doaj +1 more source
Catalysis direction selective asymmetric polymerization in chiral liquid crystal medium [PDF]
, 2014 A series of optically inactive aryl isocyanide derivatives were polymerized with an achiral nickel catalyst (Ni(II)Cl2) in a cholesteric liquid crystal (CLC) medium.
Goto Hiromasa +4 more
core +1 more source