Results 61 to 70 of about 24,379 (223)
Bulletin of the Korean Chemical Society, EarlyView.Abstract DNA‐encoded libraries (DELs) enable large‐scale screening for hit identification, but accessing sp3‐rich, three‐dimensional chemotypes beyond flat, aromatic scaffolds remains challenging. Multicomponent reactions (MCRs) assemble such complexity from simple building blocks in a single step, and reaction‐engineering strategies have extended on ...
Jimin Moon +3 more
wiley +1 more source
Fungal Isocyanide Synthases and Xanthocillin Biosynthesis in
mBio, 2018 Microbial secondary metabolites, including isocyanide moieties, have been extensively mined for their repertoire of bioactive properties. Although the first naturally occurring isocyanide (xanthocillin) was isolated from the fungus Penicillium notatum ...
Fang Yun Lim +7 more
doaj +1 more source
Antimicrobial Peptides and Peptidomimetics in Foods – A Synthetic Foray
ChemFoodChem, EarlyView.This Review discusses AMPs in foods and their syntheses. It espouses facile methods to make them accessible and suggests their utility in the mitigation and eradication of the burgeoning maladies of antimicrobial and multidrug resistance (AMR and MDR).
Josephat U. Izunobi +2 more
wiley +1 more source
Persilylated and Related Silyl Anion‐Induced Synthesis of Group 3–10 Metal–Silyl Complexes
Chemistry – A European Journal, EarlyView.Persilylated and related silyl anions serve as powerful tools for constructing metal–silyl complexes across group 3–10 elements. Their strong σ‐donating ability and steric bulk stabilize low‐coordinate, reactive species and enable unique bonding motifs.
Yusuke Sunada
wiley +1 more source
Isocyanide insertion into Au-H bonds: First gold iminoformyl complexes [PDF]
, 2018 Isocyanides insert into gold(III)–hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by ...
Fernández Cestau, Julio +15 more
core +1 more source
IMINOACETONITRILE, PREBIOTIC CHEMISTRY, AND THE CYANIDE-ISOCYANIDE REARRANGEMENT.
, 1976 IMINOACETONITRILE, PREBIOTIC CHEMISTRY, AND THE CYANIDE-ISOCYANIDE ...
JONATHAN EDWARD. DUNN (7996697)
core +3 more sources
Uncatalyzed Guanosine Phosphorylation under Potentially Prebiotic Conditions
Chemistry – A European Journal, EarlyView.Pyrophosphate acts as phosphorylating agent of guanosine under simple wet‐dry cycles without condensing agent and inorganic catalysts to afford cyclic guanosine monophosphate derivatives useful for oligomerization in prebiotic processes. ABSTRACT The phosphorylation of nucleosides and their subsequent polymerization are key issues in the study of the ...
Martina Proietti +5 more
wiley +1 more source
Study of cycloplatinated complexes with isocyanide ligands: isomerism, optical properties and mechanochromism [PDF]
, 2018 Platinum(II) cyclometalated derivatives have attracted a great interest dueto their rich photophysical properties, with interesting applications aschemical sensors, photocatalysts or in light emitting diodes (OLEDs).
M. Martínez-Junquera [0000-0002-3647-8052] +3 more
core
C‐Terminal Functionalization Methods of Amino Acids, Peptides, and Proteins
Chemistry – A European Journal, EarlyView.C‐terminal functionalization offers powerful routes to peptide and protein diversification, yet epimerization, hydrolysis, and selectivity remain key challenges. This Review surveys enzymatic, decarboxylative, and condensation strategies, highlighting advances toward chemo‐ and regioselective, protecting‐group‐free, atom‐efficient methods applicable to
Jay Hanssens +3 more
wiley +1 more source
Optimized Conditions for Passerini-Smiles Reactions and Applications to Benzoxazinone Syntheses
Molecules, 2016 Initial conditions disclosed for the Passerini-Smiles reaction are associated with a lack of efficiency that has prevented chemists from using it since its discovery.
Elodie Martinand-Lurin +6 more
doaj +1 more source