Results 71 to 80 of about 28,542 (223)

2D Rhodium‐Isocyanide Frameworks

Advanced Materials
Abstract2D metal‐organic frameworks (2D MOFs) are emerging organic van der Waals materials with great potential in various applications owing to their structural diversity, and tunable optoelectronic properties. So far, most reported 2D MOFs rely on metal‐heteroatom coordination (e.g., metal–nitrogen, metal–oxygen, and metal–sulfur); synthesis of metal‐
Senhe Huang, Pu Yan, Zhiya Han, Hongyu Wu, Youcheng Wang, Jichao Zhang, Lei Yuan, Shuai Fu, Guanzhao Wen, Jinhui Zhu, Mischa Bonn, Hai I. Wang, Kecheng Cao, Xiaodong Zhuang   +13 more
openaire   +3 more sources

Self‐Assembled Luminescent Au(I)–Adamantylamine Coordination Polymer Needles With Thermoresponsive Optical Properties

Chemistry – A European Journal, EarlyView.
A self‐assembled hydrophobic and red phosphorescent Au(I) coordination polymer (CP) was synthesized under mild conditions. Single‐crystal X‐ray diffraction (XRD) demonstrated linear Au(I) chains stabilized by aurophilic and hydrogen bonding interactions.
Miguel Justo‐Tirado, Jorge Escorihuela, Elena Zaballos‐García, Guillermo Mínguez Espallargas, Julia Pérez‐Prieto   +4 more
wiley   +1 more source

Near‐Infrared‐Light‐Driven Photochemistry and Photocatalysis: Mechanisms, Recent Applications, and Opportunities in Organic Synthesis and Biology

Angewandte Chemie, Volume 138, Issue 17, 20 April 2026.
This minireview highlights recent advances in catalyst development and mechanistic strategies that enable photochemical and photocatalytic reactivity under 700–1000 nm NIR light, emphasizing how long‐wavelength excitation expands opportunities in both synthetic chemistry and biology.
Santosh K. Pagire, Wesley J. Olivier, Debabrata Maiti, Alex C. Bissember   +3 more
wiley   +2 more sources

Crystal structures of methyl 3,5-dibromo-4-cyanobenzoate and methyl 3,5-dibromo-4-isocyanobenzoate

Acta Crystallographica Section E: Crystallographic Communications, 2018
The title crystals, C9H5Br2NO2, are the first reported 2,6-dihalophenyl cyanide–isocyanide pair that have neither three- nor two-dimensional isomorphism. Both crystals contain contacts between the carbonyl O atom and a Br atom.
Wayland E. Noland, Ryan J. Herzig, Abigail J. Engwall, Renee C. Jensen, Kenneth J. Tritch   +4 more
doaj   +1 more source

Alkyl Bismuth Cations: Synthesis, Characterization, and Application as Z‐Type Ligands

Chemistry – A European Journal, EarlyView.
Rare examples of alkyl bismuth cations [BiR2(SbF6)] are presented, including cyclopropyl ligands and a bismacyclic structure. The bismuth‐centered Lewis acids act as Z‐type ligands toward the electron‐rich platinum atom in [Pt(PCy3)2], generating a set of metal‐only Lewis pairs. The structural and spectroscopic properties of these rare types of bismuth
Johannes Schwarzmann, Joel Nitzsche, Cissie Slopianka, Liva Hartmann, William Augustinov, Alexandre Gagnon, Carsten von Hänisch, Crispin Lichtenberg   +7 more
wiley   +1 more source

Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions

European Journal of Inorganic Chemistry, EarlyView.
This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley   +1 more source

Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes [PDF]

, 2018
Isocyanides insert into gold(III)-hydrogen bonds to give the first examples of gold iminoformyl complexes. The reaction is initiated by catalytic amounts of radicals; DFT calculations indicate that this is an equilibrium reaction driven forward by ...
Bochmann, Manfred, Budzelaar, Peter H. M., Fernandez-Cestau, Julio, Pintus, Anna, Rama, Raquel J., Rocchigiani, Luca   +5 more
core   +1 more source

1,2‐Diazetidines − Structure, Synthesis, and Functionalization

European Journal of Organic Chemistry, EarlyView.
1,2‐Diazetidines are saturated four‐membered heterocycles featuring two adjacent nitrogen atoms. Despite recent advances in their synthesis and promising potential in medicinal chemistry, the chemistry of these cyclic hydrazines remains underexplored.
Stefan Roesner
wiley   +1 more source

Fungal Isocyanide Synthases and Xanthocillin Biosynthesis in Aspergillus fumigatus

mBio, 2018
Microbial secondary metabolites, including isocyanide moieties, have been extensively mined for their repertoire of bioactive properties. Although the first naturally occurring isocyanide (xanthocillin) was isolated from the fungus Penicillium notatum ...
Fang Yun Lim, Tae Hyung Won, Nicholas Raffa, Joshua A. Baccile, Jen Wisecaver, Antonis Rokas, Frank C. Schroeder, Nancy P. Keller   +7 more
doaj   +1 more source

Spectroscopic Parameters of HTiCN/HTiNC: New Titanium Compounds of Astrochemical Interest [PDF]

, 2019
Producción CientíficaA theoretical study of the [C, Ti, H, N] isomers, which are species of possible interstellar interest, has been carried out. We have employed different ab initio and density functional theory methodologies.
Barrientos Benito, María Carmen, Largo Cabrerizo, Antonio, Redondo Cristóbal, María del Pilar   +2 more
core   +2 more sources