Results 71 to 80 of about 22,422 (224)
Palladium-Catalyzed Synthesis of Amidines via tert-Butyl isocyanide Insertion
Para-substituted iodobenzenes were reacted with tert-butyl isocyanide and piperidine as nucleophiles in the presence of palladium−diphosphine catalysts.
Noémi Pálinkás +8 more
core +1 more source
The planar tetrapalladium cluster Pd4{Si(iPr)2}3(CNtBu)4 (4) was synthesised in 86% isolated yield by the reaction of palladium(0) bis(isocyanide) Pd(CNtBu)2 with octaisopropylcyclotetrasilane (3).
Yusuke Sunada +4 more
doaj +1 more source
Citation: 'isocyanides' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.I03270 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire +1 more source
2D Rhodium‐Isocyanide Frameworks
Abstract2D metal‐organic frameworks (2D MOFs) are emerging organic van der Waals materials with great potential in various applications owing to their structural diversity, and tunable optoelectronic properties. So far, most reported 2D MOFs rely on metal‐heteroatom coordination (e.g., metal–nitrogen, metal–oxygen, and metal–sulfur); synthesis of metal‐
Senhe Huang +13 more
openaire +3 more sources
A self‐assembled hydrophobic and red phosphorescent Au(I) coordination polymer (CP) was synthesized under mild conditions. Single‐crystal X‐ray diffraction (XRD) demonstrated linear Au(I) chains stabilized by aurophilic and hydrogen bonding interactions.
Miguel Justo‐Tirado +4 more
wiley +1 more source
Titanocene phosphinidenes react with terminal alkynes in formal [2 + 2] cycloadditions to give unsaturated [C2PTi] metallcycles. Diphosphene complexes in combination with aryl‐substituted alkynes react similarly to provide metallacyclopentenes. Titanocene‐phosphinidene and diphosphanediide (or diphosphene) complexes Cp2Ti(PMe3)PMesTer and Cp2Ti(P2Ar2) (
Andrey Petrov +1 more
wiley +1 more source
1,2‐Diazetidines − Structure, Synthesis, and Functionalization
1,2‐Diazetidines are saturated four‐membered heterocycles featuring two adjacent nitrogen atoms. Despite recent advances in their synthesis and promising potential in medicinal chemistry, the chemistry of these cyclic hydrazines remains underexplored.
Stefan Roesner
wiley +1 more source
Mechanism of Catalytic Nitrene Transfer Using Iron(I)–Isocyanide Complexes
Low-spin iron(I) complexes supported by bulky β-diketiminate ligands catalyze the formation of unsymmetric carbodiimides (RNCNR′, R ≠ R′) from isocyanides and organoazides.
Matthew R. Golder (1678135) +4 more
core +2 more sources
The one‐pot synthesis of 3‐benzylidenbenzo[c]thiophen‐1‐amines was achieved through the nickel‐catalyzed three‐component coupling reaction of 1‐ethynyl‐2‐iodobenzenes, tert‐butyl isocyanide, and hexamethyldisilathiane. This procedure is applicable to the preparation of secondary thioamides using aryl iodides.
Norio Sakai +4 more
wiley +1 more source
Isocyanide synthase domains, newick trees and alignments
Maximum likelihood phylogenies and associated alignments of isocyanide synthase domains proteins across the tree of ...
Jennifer Wisecaver (820976)
core +1 more source

