Results 51 to 60 of about 22,465 (222)

Structure and Reactivity of Glycosyl Isocyanides

open access: yesEuropean Journal of Organic Chemistry, 2018
3D structural information was obtained from mono‐, di‐ and trisaccharide formamide and isocyanide derivatives by analysis of their X‐ray crystal structure and NMR spectroscopy. The isocyanide anomeric effect was observed. Data mining of the Cambridge Structural Database (CSD) was performed and statistically confirmed our findings.
Constantinos G. Neochoritis   +6 more
openaire   +5 more sources

Mechanism of Catalytic Nitrene Transfer Using Iron(I)–Isocyanide Complexes [PDF]

open access: yes, 2016
Low-spin iron­(I) complexes supported by bulky β-diketiminate ligands catalyze the formation of unsymmetric carbodiimides (RNCNR′, R ≠ R′) from isocyanides and organoazides.
Matthew R. Golder (1678135)   +4 more
core   +3 more sources

Gold Liquid Crystals in the XXI Century

open access: yesInorganics, 2014
Since the first gold liquid crystal was described in 1986, much effort has been done to prepare new compounds bearing this property. The review deals with the last results obtained in this new century.
Manuel Bardají
doaj   +1 more source

Isocyanide synthase domains, newick trees and alignments [PDF]

open access: yes, 2017
Maximum likelihood phylogenies and associated alignments of isocyanide synthase domains proteins across the tree of ...
Jennifer Wisecaver (820976)
core   +1 more source

A trustworthy mechanochemical route to isocyanides

open access: yesBeilstein Journal of Organic Chemistry, 2022
Isocyanides are hardly produced, dramatically sensitive to purification processes, and complex to handle as synthetic tools. Notwithstanding, they represent one of the most refined and valuable compounds for accessing sophisticated and elegant synthetic ...
Francesco Basoccu   +5 more
doaj   +1 more source

Construction of 5-(Alkylamino)-6-aryl/alkylpyrazine-2,3-dicarbonitriles via the One-Pot Reaction of Alkyl Isocyanides with Aryl/Alkyl Carbonyl Chlorides and Diaminomaleonitrile: Fluorescence and Antimicrobial Activity Evaluation

open access: yesMolecules, 2022
5-(Alkylamino)-6-aryl/alkylpyrazine-2,3-dicarbonitriles were successfully synthesized in good to moderate yields by reacting alkyl isocyanides with aryl/alkyl carbonyl chlorides, followed by the addition of diaminomaleonitrile.
Amal Al-Azmi, Elizabeth John
doaj   +1 more source

Synthesis of 3-aminoimidazo[1,2-a]pyridines via three-component reaction in the 2,2,2-trifluoroethanol-water two-phase systems [PDF]

open access: yesشیمی کاربردی روز, 2020
An efficient synthesis of 3-aminoimidazo[1,2-a]pyridines via three-component reaction from aromatic aldehydes, 2-aminopyridines and isonitriles at room temperature in water/2,2,2-trifluoroethanol two-phase systems is described.
Mobina Alizade-Majd   +2 more
doaj   +1 more source

Exploiting the Reactivity of Isocyanide: Coupling Reaction between Isocyanide and Toluene Derivatives Using the Isocyano Group as an N1 Synthon [PDF]

open access: yes, 2016
An unusual oxidative coupling reaction of isocyanide and toluene derivatives using tetrabutylammonium iodide (TBAI) as a catalyst is disclosed. The experimental results and mechanistic study show that the isocyano group acts formally as an N1 synthon ...
Feng Li (30515)   +6 more
core   +1 more source

Studies on the interaction of isocyanides with imines: reaction scope and mechanistic variations

open access: yesBeilstein Journal of Organic Chemistry, 2014
The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon–nitrogen double bond of the imine to form the 4 ...
Ouldouz Ghashghaei   +4 more
doaj   +1 more source

One‐Pot Synthesis of a Small Synthetic Ligand for Antibody Purification

open access: yesBiotechnology and Bioengineering, EarlyView.
One‐pot liquid‐phase synthesis of the synthetic ligand B1Al2A2 enables controllable ligand density and efficient capture of IgG and IgY with high recovery and purity, streamlining small‐ligand affinity purification workflows. ABSTRACT The development of synthetic affinity ligands offers a cost‐effective alternative to traditional biological ligands ...
Carolina Mota Natal   +8 more
wiley   +1 more source

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