Results 31 to 40 of about 321 (141)
Reaction between Indazole and Pd-Bound Isocyanides—A Theoretical Mechanistic Study
Molecules, 2018 The mechanism of the addition of indazole (Ind)—a bifunctional aromatic N,NH-nucleophile—to cyclohexyl isocyanide coordinated to the palladium(II) center in the model complex cis-[PdCl2(CNMe)(CNCy)] (1) to give the corresponding aminocarbene ...
Girolamo Casella +3 more
doaj +1 more source
On the reaction of diphenylketene with isocyanides
Organic & Biomolecular Chemistry, 2005 The products obtained from the reaction of diphenylketene with a variety of isocyanides are shown to depend heavily on the concentration of diphenylketene; a high concentration results in the precedented dioxolane derivatives, at much lower concentrations the reactions follow an alternative course and polycyclic beta-lactams are generated by a cascade ...
Robertson, J, Bell, S, Krivokapic, A
openaire +3 more sources
Structure and Reactivity of Glycosyl Isocyanides
European Journal of Organic Chemistry, 2018 3D structural information was obtained from mono‐, di‐ and trisaccharide formamide and isocyanide derivatives by analysis of their X‐ray crystal structure and NMR spectroscopy. The isocyanide anomeric effect was observed. Data mining of the Cambridge Structural Database (CSD) was performed and statistically confirmed our findings.
Constantinos G. Neochoritis +6 more
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Green Chemistry, 2020 Isocyanides are important chemicals, with limited availability, thus reducing their general use. Our highly improved isocyanide synthesis performed on mole to μ-mole scale, individually or in a 96-well parallel fashion enables unprecedented exploration of novel chemistries.
Pravin Patil +2 more
openaire +3 more sources
Angewandte Chemie, EarlyView.Myxoglucamid A – ein neuartiges, aus Myxobakterien isoliertes Glykolipopeptid – wurde erstmals totalsynthetisch hergestellt. Mittels aktivitätsbasierter Proteinprofilierung (ABPP) wurde die Aldo‐Keto‐Reduktase 1C3 (AKR1C3) als primäres Zielprotein in menschlichen Zellen identifiziert.
Thomas Siemon +9 more
wiley +1 more source
Gold Liquid Crystals in the XXI Century
Inorganics, 2014 Since the first gold liquid crystal was described in 1986, much effort has been done to prepare new compounds bearing this property. The review deals with the last results obtained in this new century.
Manuel Bardají
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Investigating the bioorthogonality of isocyanides
Chemical CommunicationsIsocyanides have been explored as bioorthogonal triggers for uncaging reactions. However, our findings show they can covalently label proteins, indicating they may not be fully bioorthogonal in biological systems.
Ryota Nakao +7 more
openaire +4 more sources
A trustworthy mechanochemical route to isocyanides
Beilstein Journal of Organic Chemistry, 2022 Isocyanides are hardly produced, dramatically sensitive to purification processes, and complex to handle as synthetic tools. Notwithstanding, they represent one of the most refined and valuable compounds for accessing sophisticated and elegant synthetic ...
Francesco Basoccu +5 more
doaj +1 more source
Molecules, 2022 5-(Alkylamino)-6-aryl/alkylpyrazine-2,3-dicarbonitriles were successfully synthesized in good to moderate yields by reacting alkyl isocyanides with aryl/alkyl carbonyl chlorides, followed by the addition of diaminomaleonitrile.
Amal Al-Azmi, Elizabeth John
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Synthesis of 3-aminoimidazo[1,2-a]pyridines via three-component reaction in the 2,2,2-trifluoroethanol-water two-phase systems [PDF]
شیمی کاربردی روز, 2020 An efficient synthesis of 3-aminoimidazo[1,2-a]pyridines via three-component reaction from aromatic aldehydes, 2-aminopyridines and isonitriles at room temperature in water/2,2,2-trifluoroethanol two-phase systems is described.
Mobina Alizade-Majd +2 more
doaj +1 more source