Results 11 to 20 of about 22,465 (222)
Efficient Isocyanide-less Isocyanide-Based Multicomponent Reactions [PDF]
Organic Letters, 2015 Isocyanides are the "Jekyll and Hyde" of organic chemistry allowing for extremely interesting transformations that are not only extremely odorous but also noxious. Therefore, an isocyanide-less isocyanide-based multicomponent reaction (IMCR) has been developed, and this protocol is expected to replace many of the old procedures in the future not only ...
Neochoritis +4 more
openaire +6 more sources
Green Chemistry, 2020 Isocyanides are important chemicals, with limited availability, thus reducing their general use. Our highly improved isocyanide synthesis performed on mole to μ-mole scale, individually or in a 96-well parallel fashion enables unprecedented exploration of novel chemistries.
Pravin Patil +2 more
openaire +5 more sources
(tert-Butyl isocyanide-κC)trichloridogallium(III) [PDF]
IUCrData, 2016 The crystal structure of (tert-butyl isocyanide-κC)trichloridogallium(III), [GaCl3(C5H9N)], features the first reported isocyanide–gallium trihalide complex. The Ga—C—N—C fragment is essentially linear.
Jeremy L. Bourque +2 more
doaj +2 more sources
Tris(tert-butyl isocyanide-κC)carbonylnickel(0) [PDF]
Acta Crystallographica Section E, 2008 The title compound, [Ni(C5H9N)3(CO)], was prepared from Ni(CO)4 and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent molecules per asymmetric unit.
Wolfgang Imhof +2 more
doaj +2 more sources
Isocyanide-Induced Annulation Leading to Cyclopento Methano, and Cyclopentano-[60]Fullerene Derivatives [PDF]
, 2021 The three-component annulation reactions of C60, alkyl isocyanide, and dimethyl acetylenedicarboxylate (DMAD) or unsymmetric alkynes are investigated to afford cyclopent-2-en-1-imino- and ketenimine methano-[60]fullerene derivatives, which, upon ...
Yue Sun (197395) +9 more
core +1 more source
Isocyanide-based cascade reactions in the synthesis of aza-heterocycles: A marriage of convenience [PDF]
, 2022 Background: The design and performing of cascade reactions is a challenging but stimulating and interesting facet of organic synthesis, yet one that can convey conspicuous novelty, efficiency as well as elegance and sophistication to synthetic approaches.
Niousha Nazari (11994504) +1 more
core +1 more source
Ugi Four-Component Reactions Using Alternative Reactants
Molecules, 2023 The Ugi four-component reaction (Ugi-4CR) undoubtedly is the most prominent multicomponent reaction (MCRs) that has sparked organic chemists’ interest in the field.
Seyyed Emad Hooshmand, Wei Zhang
doaj +1 more source
Aurophilic Interactions in Cationic Three-Coordinate Gold(I) Bipyridyl/Isocyanide Complex
Crystals, 2022 Gold(I) isocyanide complexes featuring Au···Au interactions attract considerable attention because of their tunable photophysical properties. Although the synthetic exploration of isocyanide gold(I) complexes seems reasonable, their structural diversity ...
Mariya V. Grudova +6 more
doaj +1 more source
Isocyanide-based multicomponent reactions in the synthesis of heterocycles [PDF]
, 2022 In this review, we update our previous presentation, underscoring the recent applications of isocyanides as privileged synthons in the synthesis of various heterocyclic compounds, especially focused on those synthesized via multicomponent reactions.
Niousha Nazari (11994504) +2 more
core +1 more source
Synthesis, Characterization and Chemistry of Tetrakis(Propargylisocyanide) Copper(I) Complex
Molbank, 2023 The kinetically unstable propargylisocyanide was reacted with the tetrakis(acetonitrile) copper(I) hexafluorophosphate and the formed complex was then involved in a copper-catalyzed alkyne-azide cycloaddition reaction (CuAAC). After the decomplexation of
Alexandre Quelhas +3 more
doaj +1 more source