Results 11 to 20 of about 321 (141)

Synthesis, Characterization and Chemistry of Tetrakis(Propargylisocyanide) Copper(I) Complex

open access: yesMolbank, 2023
The kinetically unstable propargylisocyanide was reacted with the tetrakis(acetonitrile) copper(I) hexafluorophosphate and the formed complex was then involved in a copper-catalyzed alkyne-azide cycloaddition reaction (CuAAC). After the decomplexation of
Alexandre Quelhas   +3 more
doaj   +1 more source

Synthesis and Biological Activities of Luminescent 5,6-Membered Bis(Metallacyclic) Platinum(II) Complexes

open access: yesMolecules, 2023
Four couples of 5,6-membered bis(metallacyclic) Pt(II) complexes with acetylide and isocyanide auxiliary ligands have been prepared and characterized.
Jing Jing   +7 more
doaj   +1 more source

Isocyanides: Promising Functionalities in Bioorthogonal Labeling of Biomolecules

open access: yesFrontiers in Chemistry, 2021
Isocyanides have drawn increasing attention in biological applications due to their attractive properties and unique reactivities, which can undergo various reactions, such as multicomponent reactions, α-addition reactions, [4 + 1] cycloaddition ...
Yuchen Zhu   +6 more
doaj   +1 more source

Divergent isoindolinone synthesis through palladium-catalyzed isocyanide bridging C–H activation

open access: yesCell Reports Physical Science, 2022
Summary: The formation of thermodynamically accessible metallacycle is crucial to achieve site-selective C–H bond activation. Here, we report an isocyanide-bridging C–H activation through the formation of a five-membered palladacycle. As such, a proximal
Fulin Zhang   +6 more
doaj   +1 more source

Potential Original Drug for Aspergillosis: In Vitro and In Vivo Effects of 1-N,N-Dimethylamino-5-Isocyanonaphthalene (DIMICAN) on Aspergillus fumigatus

open access: yesJournal of Fungi, 2022
As the recent outbreak of coronavirus disease 2019 (COVID-19) has shown, viral infections are prone to secondary complications like invasive aspergillosis with a high mortality rate, and therefore the development of novel, effective antifungals is of ...
Zsuzsa Máthéné Szigeti   +8 more
doaj   +1 more source

2,6-Dibromo-4-chlorophenyl isocyanide

open access: yesIUCrData, 2018
Molecules of the title compound, C7H2Br2ClN (RNC), are bisected by a mirror plane that passes through the chloro and isocyano groups. The isocyano C atom is bisected by two NC...Br contacts, one per Br atom.
Wayland E. Noland, Kenneth J. Tritch
doaj   +1 more source

Cyclopentadienone triisocyanide iron complexes: general synthesis and crystal structures of tris(2,6-dimethylphenyl isocyanide)(η4-tetraphenylcyclopentadienone)iron and tris(naphthalen-2-yl isocyanide)(η4-tetraphenylcyclopentadienone)iron acetone hemisolvate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2023
Irradiation of a toluene solution containing cyclopentadienone tricarbonyl iron complexes and isocyanides with blue LEDs afforded the formation and isolation of 12 triisocyanide complexes, two of which, namely tris(2,6-dimethylphenyl isocyanide)(η4 ...
André Bütikofer, Peter Chen
doaj   +1 more source

Efficient one-pot, four-component synthesis of N,N-dibenzyl-N-{1-[5-(3-aryl)-1,3,4-oxadiazol-2-yl]cyclobutyl}amine derivatives from the reaction of (isocyanoimino)triphenylphosphorane, dibenzylamine, an aromatic carboxylic acid and cyclobutanone [PDF]

open access: yesJournal of the Serbian Chemical Society, 2012
Four-component reaction of cyclobutanone, dibenzylamine and (Nisocyanimino) triphenylphosphorane in the presence of aromatic carboxylic acids proceed smoothly at room temperature and under neutral conditions to afford N,N-dibenzyl-N-{1-[5-(3-aryl)-1,3,
Shajari Nahid   +2 more
doaj   +1 more source

Mutual Placement of Isocyanide and Phosphine Ligands in Platinum(II) Complexes [PtHal2L1L2] (Hal = Cl, Br, I; L1,L2 = CNCy, PPh3) Leads to Highly-Efficient Photocatalysts for Hydrosilylation of Alkynes

open access: yesMolecules, 2023
A series of platinum complexes featuring phosphine and isocyanide ligands [PtX2(PPh3)(CNCy)] (X = Cl, Br, and I) as well as their parent phosphine [PtX2(PPh3)2] and isocyanide [PtX2(CNCy)2] analogues have been prepared and evaluated as catalysts for the ...
Maria V. Kashina   +4 more
doaj   +1 more source

Synthesis of (macro)heterocycles by consecutive/repetitive isocyanide-based multicomponent reactions

open access: yesBeilstein Journal of Organic Chemistry, 2019
Isocyanide-based multicomponent reactions are a versatile tool in the synthesis of heterocycles. This review describes recently developed approaches based on the combination of consecutive or repetitive isocyanide-based multicomponent reactions for the ...
Angélica de Fátima S. Barreto   +1 more
doaj   +1 more source

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