Results 21 to 30 of about 22,422 (224)

Isocyanide-based cascade reactions in the synthesis of aza-heterocycles: A marriage of convenience

, 2022
Background: The design and performing of cascade reactions is a challenging but stimulating and interesting facet of organic synthesis, yet one that can convey conspicuous novelty, efficiency as well as elegance and sophistication to synthetic approaches.
Niousha Nazari (11994504), Majid Mommahed Heravi (9225485)   +1 more
core   +1 more source

Potential Original Drug for Aspergillosis: In Vitro and In Vivo Effects of 1-N,N-Dimethylamino-5-Isocyanonaphthalene (DIMICAN) on Aspergillus fumigatus

Journal of Fungi, 2022
As the recent outbreak of coronavirus disease 2019 (COVID-19) has shown, viral infections are prone to secondary complications like invasive aspergillosis with a high mortality rate, and therefore the development of novel, effective antifungals is of ...
Zsuzsa Máthéné Szigeti, László Tálas, Adrienn Széles, Zoltán Hargitai, Zsolt László Nagy, Miklós Nagy, Alexandra Kiss, Sándor Kéki, Gábor Szemán-Nagy   +8 more
doaj   +1 more source

Isocyanide-based multicomponent reactions in the synthesis of heterocycles

, 2022
In this review, we update our previous presentation, underscoring the recent applications of isocyanides as privileged synthons in the synthesis of various heterocyclic compounds, especially focused on those synthesized via multicomponent reactions.
Niousha Nazari (11994504), Majid Mommahed Heravi (9225485), Samaheh Sadjadi (6846752)   +2 more
core   +1 more source

Cyclopentadienone triisocyanide iron complexes: general synthesis and crystal structures of tris(2,6-dimethylphenyl isocyanide)(η4-tetraphenylcyclopentadienone)iron and tris(naphthalen-2-yl isocyanide)(η4-tetraphenylcyclopentadienone)iron acetone hemisolvate

Acta Crystallographica Section E: Crystallographic Communications, 2023
Irradiation of a toluene solution containing cyclopentadienone tricarbonyl iron complexes and isocyanides with blue LEDs afforded the formation and isolation of 12 triisocyanide complexes, two of which, namely tris(2,6-dimethylphenyl isocyanide)(η4 ...
André Bütikofer, Peter Chen
doaj   +1 more source

2,6-Dibromo-4-chlorophenyl isocyanide

IUCrData, 2018
Molecules of the title compound, C7H2Br2ClN (RNC), are bisected by a mirror plane that passes through the chloro and isocyano groups. The isocyano C atom is bisected by two NC...Br contacts, one per Br atom.
Wayland E. Noland, Kenneth J. Tritch
doaj   +1 more source

Efficient one-pot, four-component synthesis of N,N-dibenzyl-N-{1-[5-(3-aryl)-1,3,4-oxadiazol-2-yl]cyclobutyl}amine derivatives from the reaction of (isocyanoimino)triphenylphosphorane, dibenzylamine, an aromatic carboxylic acid and cyclobutanone [PDF]

Journal of the Serbian Chemical Society, 2012
Four-component reaction of cyclobutanone, dibenzylamine and (Nisocyanimino) triphenylphosphorane in the presence of aromatic carboxylic acids proceed smoothly at room temperature and under neutral conditions to afford N,N-dibenzyl-N-{1-[5-(3-aryl)-1,3,
Shajari Nahid, Kazemizadeh Reza Ali, Ramazani Ali   +2 more
doaj   +1 more source

Aluminium Mediated Isocyanide Insertion and Sequential Ring Opening Cyclization (SROC) Strategy: Synthesis of Azole Fused Benzimidazoquinazoline Skeletons

, 2021
A first report on transition-metal-free aluminium chloride mediated isocyanide insertion between two amine nucleophiles have been presented. Also, an unusual C-N bond cleavage allow for the further development of copper mediated ring open-ing cyclization
D. S., Sharada, Nagarjuna Babu, Venkata, Punith, S., anand , H. Shinde   +3 more
core   +1 more source

Synthesis of (macro)heterocycles by consecutive/repetitive isocyanide-based multicomponent reactions

Beilstein Journal of Organic Chemistry, 2019
Isocyanide-based multicomponent reactions are a versatile tool in the synthesis of heterocycles. This review describes recently developed approaches based on the combination of consecutive or repetitive isocyanide-based multicomponent reactions for the ...
Angélica de Fátima S. Barreto, Carlos Kleber Z. Andrade   +1 more
doaj   +1 more source

Mutual Placement of Isocyanide and Phosphine Ligands in Platinum(II) Complexes [PtHal₂L¹L²] (Hal = Cl, Br, I; L¹,L² = CNCy, PPh₃) Leads to Highly-Efficient Photocatalysts for Hydrosilylation of Alkynes

Molecules, 2023
A series of platinum complexes featuring phosphine and isocyanide ligands [PtX2(PPh3)(CNCy)] (X = Cl, Br, and I) as well as their parent phosphine [PtX2(PPh3)2] and isocyanide [PtX2(CNCy)2] analogues have been prepared and evaluated as catalysts for the ...
Maria V. Kashina, Andrei A. Karcheuski, Mikhail A. Kinzhalov, Konstantin V. Luzyanin, Svetlana A. Katkova   +4 more
doaj   +1 more source

The ALMA-PILS survey: first detection of methyl isocyanide (CH3NC) in a solar-type protostar [PDF]

, 2018
International audienceMethyl isocyanide (CH3NC) is the isocyanide with the largest number of atoms confirmed in the interstellar medium (ISM), but it is not an abundant molecule, having only been detected towards a handful of objects.
Kristensen, L. E., M. N. Drozdovskaya, M\ufcller, H. S. P., R. T. Garrod, Ligterink, N. F. W.,, Ligterink, N.F.W., E. R. Willis, Jorgensen, J. K., Bourke, T. L., Calcutt, Hannah,, Garrod, R.T., Coutens, A., Drozdovskaya, M.N., Fiechter, M. R.,, S. F. Wampfler, Willis, E. R., Wampfler, S.F., A. Coutens, Kristensen, L.E., Bourke, T.L., M. R. Fiechter, Drozdovskaya, M. N.,, Willis, E. R.,, Willis, E.R., Calcutt, Hannah, H. S. P. Müller, Müller, H.S.P., Fiechter, M. R., Calcutt, H., Garrod, R. T.,, Drozdovskaya, M. N., N. F. W. Ligterink, L. E. Kristensen, Jørgensen, J.K., T. L. Bourke, Fiechter, M.R., Jørgensen, J. K., Mueller, H. S. P., Müller, H. S. P., J. K. Jørgensen, Garrod, R. T., Müller, H. S. P.,, Kristensen, L. E.,, H. Calcutt, Wampfler, S. F., Coutens, Audrey, Wampfler, S. F.,, Jorgensen, J. K.,, Coutens, A.,, Ligterink, N. F. W., Bourke, T. L.,   +50 more
core   +1 more source