Results 31 to 40 of about 23,536 (214)

Tris(tert-butyl isocyanide-κC)carbonylnickel(0)

open access: yesActa Crystallographica Section E, 2008
The title compound, [Ni(C5H9N)3(CO)], was prepared from Ni(CO)4 and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent molecules per asymmetric unit.
Wolfgang Imhof   +2 more
doaj   +1 more source

Isocyanide-Based Multicomponent Reactions for the Synthesis of Heterocycles

open access: yesMolecules, 2015
Multicomponent reactions (MCRs) are extremely popular owing to their facile execution, high atom-efficiency and the high diversity of products. MCRs can be used to access various heterocycles and highly functionalized scaffolds, and thus have been ...
András Váradi   +3 more
doaj   +1 more source

Synthesis of 3-aminoimidazo[1,2-a]pyridines via three-component reaction in the 2,2,2-trifluoroethanol-water two-phase systems [PDF]

open access: yesشیمی کاربردی روز, 2020
An efficient synthesis of 3-aminoimidazo[1,2-a]pyridines via three-component reaction from aromatic aldehydes, 2-aminopyridines and isonitriles at room temperature in water/2,2,2-trifluoroethanol two-phase systems is described.
Mobina Alizade-Majd   +2 more
doaj   +1 more source

On the reaction of diphenylketene with isocyanides

open access: yesOrganic & Biomolecular Chemistry, 2005
The products obtained from the reaction of diphenylketene with a variety of isocyanides are shown to depend heavily on the concentration of diphenylketene; a high concentration results in the precedented dioxolane derivatives, at much lower concentrations the reactions follow an alternative course and polycyclic beta-lactams are generated by a cascade ...
Robertson, J, Bell, S, Krivokapic, A
openaire   +4 more sources

From Isocyanides to Iminonitriles via Silver-mediated Sequential Insertion of C(sp3)–H Bond

open access: yesiScience, 2019
Summary: Heterocycles are prevalent constituents of many marketing drugs and biologically active molecules to meet modern medical challenges. Isocyanide insertion into C(sp3)–H bonds is challenging especially for the construction of quaternary carbon ...
Huiwen Chi   +7 more
doaj   +1 more source

[3+2] Cycloaddition of Tosylmethyl Isocyanide with Styrylisoxazoles: Facile Access to Polysubstituted 3-(Isoxazol-5-yl)pyrroles

open access: yesMolecules, 2017
A facile access to polysubstituted 3-(isoxazol-5-yl)pyrroles was developed through [3+2] cycloaddition of tosylmethyl isocyanide (TosMIC) and styrylisoxazoles.
Xueming Zhang, Xianxiu Xu, Dawei Zhang
doaj   +1 more source

Synthesis and Characterization of Organoplatinum(II) Complexes Containing Isocyanide Ligands: Molecular Docking Studies [PDF]

open access: yesشیمی کاربردی روز, 2019
The present work investigates synthesis and characterization of two organoplatinum(II) complexes comprising various isocyanide ligands with general formula of [PtR'2(CNR)2] (R' = p-tolyl, R = 2-chloro-6-methylphenyl (1) and 2-naphtyl (2)).
Hamid Reza Shahsavari   +3 more
doaj   +1 more source

Reaction between Indazole and Pd-Bound Isocyanides—A Theoretical Mechanistic Study

open access: yesMolecules, 2018
The mechanism of the addition of indazole (Ind)—a bifunctional aromatic N,NH-nucleophile—to cyclohexyl isocyanide coordinated to the palladium(II) center in the model complex cis-[PdCl2(CNMe)(CNCy)] (1) to give the corresponding aminocarbene ...
Girolamo Casella   +3 more
doaj   +1 more source

Synthesis of Depsipeptides via Isocyanide-Based Consecutive Bargellini–Passerini Multicomponent Reactions

open access: yesSynOpen, 2021
An efficient and straightforward approach has been established for the preparation of a new class of depsipeptide structures via isocyanide-based consecutive Bargellini–Passerini multicomponent reactions.
Hassan Farhid   +3 more
doaj   +1 more source

Structure and Reactivity of Glycosyl Isocyanides

open access: yesEuropean Journal of Organic Chemistry, 2018
3D structural information was obtained from mono‐, di‐ and trisaccharide formamide and isocyanide derivatives by analysis of their X‐ray crystal structure and NMR spectroscopy. The isocyanide anomeric effect was observed. Data mining of the Cambridge Structural Database (CSD) was performed and statistically confirmed our findings.
Constantinos G. Neochoritis   +6 more
openaire   +6 more sources

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