Results 41 to 50 of about 34,359 (255)
Tris(tert-butyl isocyanide-κC)carbonylnickel(0)
Acta Crystallographica Section E, 2008 The title compound, [Ni(C5H9N)3(CO)], was prepared from Ni(CO)4 and a tenfold excess of tert-butyl isocyanide. It crystallizes with two symmetry-independent molecules per asymmetric unit.
Wolfgang Imhof +2 more
doaj +1 more source
Isocyanide-Based Multicomponent Reactions for the Synthesis of Heterocycles
Molecules, 2015 Multicomponent reactions (MCRs) are extremely popular owing to their facile execution, high atom-efficiency and the high diversity of products. MCRs can be used to access various heterocycles and highly functionalized scaffolds, and thus have been ...
András Váradi +3 more
doaj +1 more source
Molecules, 2023 α-Ketoamide moieties, as privileged units, may represent a valuable option to develop compounds with favorable biological activities, such as low toxicity, promising PK and drug-like properties.
Jia Xu +6 more
doaj +1 more source
From Isocyanides to Iminonitriles via Silver-mediated Sequential Insertion of C(sp3)–H Bond
iScience, 2019 Summary: Heterocycles are prevalent constituents of many marketing drugs and biologically active molecules to meet modern medical challenges. Isocyanide insertion into C(sp3)–H bonds is challenging especially for the construction of quaternary carbon ...
Huiwen Chi +7 more
doaj +1 more source
Organic Letters, 2019 Isocyanide multicomponent reactions play a prominent role in drug discovery. This chemistry has hardly been investigated for compatibility with DNA-encoded combinatorial synthesis.
Verena B. K. Kunig +3 more
semanticscholar +1 more source
Nature Communications, 2019 Although isocyanide-based multicomponent reactions were proven to be simple, elegant and facile strategies for the synthesis of highly valuable nitrogen-containing heterocycles, their asymmetric versions accessing to optically active nitrogen ...
Qian Xiong +4 more
semanticscholar +1 more source
Reaction between Indazole and Pd-Bound Isocyanides—A Theoretical Mechanistic Study
Molecules, 2018 The mechanism of the addition of indazole (Ind)—a bifunctional aromatic N,NH-nucleophile—to cyclohexyl isocyanide coordinated to the palladium(II) center in the model complex cis-[PdCl2(CNMe)(CNCy)] (1) to give the corresponding aminocarbene ...
Girolamo Casella +3 more
doaj +1 more source
Gold Liquid Crystals in the XXI Century
Inorganics, 2014 Since the first gold liquid crystal was described in 1986, much effort has been done to prepare new compounds bearing this property. The review deals with the last results obtained in this new century.
Manuel Bardají
doaj +1 more source
Mechanochromic Organic Materials: Molecular Mechanisms and Multidimensional Applications
Advanced Physics Research, EarlyView.Mechanochromic (MC) organic materials change color in response to mechanical force. This review elucidates the molecular mechanisms (e.g., aggregation‐induced emission, AIE) and explores their multidimensional applications in sensors, anti‐counterfeiting, biomedical devices, and structural health monitoring, providing a roadmap for future smart ...
Xiaozhe Yin +5 more
wiley +1 more source
Molecules, 2022 5-(Alkylamino)-6-aryl/alkylpyrazine-2,3-dicarbonitriles were successfully synthesized in good to moderate yields by reacting alkyl isocyanides with aryl/alkyl carbonyl chlorides, followed by the addition of diaminomaleonitrile.
Amal Al-Azmi, Elizabeth John
doaj +1 more source