Results 71 to 80 of about 34,359 (255)

Optimized Conditions for Passerini-Smiles Reactions and Applications to Benzoxazinone Syntheses

Molecules, 2016
Initial conditions disclosed for the Passerini-Smiles reaction are associated with a lack of efficiency that has prevented chemists from using it since its discovery.
Elodie Martinand-Lurin, Aurélie Dos Santos, Emmanuelle Robineau, Pascal Retailleau, Philippe Dauban, Laurence Grimaud, Laurent El Kaïm   +6 more
doaj   +1 more source

isocyanides

, 2014
Citation: 'isocyanides' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.I03270 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Scalable and Chromatography‐Free Synthesis of Settlement Inhibition Glucosamine Derivative

Chemistry &Biodiversity, Volume 23, Issue 1, January 2026.
A scalable synthesis (>10 g) of a glucosamine derivative withsettlement inhibition activity against the barnacles of Amphibalanusamphitrite is described. The synthesis is chromatography‐free throughoutthe entire synthetic scheme, enabling efficient and cost‐effective preparationof the final product to provide a pure product with potent ...
Taiki Umezawa, Hyuga Okumura, Kazuki Tachibana, Erina Yoshimura, Yasuyuki Nogata   +4 more
wiley   +1 more source

Construction of a Planar Tetrapalladium Cluster by the Reaction of Palladium(0) Bis(isocyanide) with Cyclic Tetrasilane

Inorganics, 2017
The planar tetrapalladium cluster Pd4{Si(iPr)2}3(CNtBu)4 (4) was synthesised in 86% isolated yield by the reaction of palladium(0) bis(isocyanide) Pd(CNtBu)2 with octaisopropylcyclotetrasilane (3).
Yusuke Sunada, Nobuhiro Taniyama, Kento Shimamoto, Soichiro Kyushin, Hideo Nagashima   +4 more
doaj   +1 more source

One‐Pot Morita–Baylis–Hillman/Allylic Substitution in Deep Eutectic Solvents: Access to γ‐Hydroxy Derivatives via Sequential CC and CX (X = P, N, S, B, Si) Bond Formation

ChemSusChem, Volume 19, Issue 1, January 2026.
Sustainable one‐pot synthesis of functionalized γ‐hydroxy derivatives in deep eutectic solvents. A green, sequential CC/CX bond‐forming strategy enables diverse γ‐hydroxy derivatives via Morita–Baylis–Hillman and nucleophilic functionalization in ChCl/Gly deep eutectic solvent.
Marina Ramos‐Martín, Ignacio del Río, Joaquín García‐Álvarez, Alejandro Presa Soto   +3 more
wiley   +1 more source

Synthesis of Aza‐indeno‐aza‐fluoranthene and Constitutional Isomers by Ring‐Size Selective C–H Activation

Chemistry – A European Journal, Volume 31, Issue 72, December 23, 2025.
A series of constitutional isomers of aza‐indeno‐aza‐fluoranthene with different ring sizes has been synthesized. Their product distribution was controlled by adjusting parameters such as base, temperature, solvent, or additive in the Pd‐catalyzed direct arylation step, thereby providing an overview about the options to control ring‐size selectivity in
Christoph Keck, Frank Rominger, Sonali Garg, Marcus Elstner, Michael Mastalerz   +4 more
wiley   +1 more source

Synthetic Strategies to Access Fluorinated Azoles

European Journal of Organic Chemistry, Volume 28, Issue 47, December 15, 2025.
This review highlights recent synthetic strategies for introducing fluorine groups (mono‐, di‐, and trifluoromethylation) into 11 major azole classes, identifying research gaps to inform future innovations in materials science, medicinal chemistry, and biomedical research.
Mohammed K. Abd El‐Gaber, Mario Djugovski, Tzu‐Yu Huang, Sweta Adhikari, Sudeshna Roy   +4 more
wiley   +1 more source

1,5‐Diisocyanonaphthalene: The Lowest Molecular Weight Fluorescent Probe for the Determination of Trace Amounts of Sulfoxides in Both Organic and Aqueous Media

ChemPhotoChem, Volume 9, Issue 12, December 13, 2025.
We present 1,5‐DIN as a low‐cost, efficient fluorescent probe for trace DMSO detection in organic and aqueous media. It shows strong quenching, with LODs from 5–50 ppm, even in complex matrices. Theoretical insights support its mechanism, highlighting its promise for practical applications.
Attila Kovács, Rajmond Schiwert, Péter Kun, Zoltán Mucsi, László Vanyorek, Béla Viskolcz, Miklós Nagy   +6 more
wiley   +1 more source

Exploring the Immobilization Strategies of Lewis Bases on Lignocellulosic Bamboo Shavings and their Applications in Cycloaddition of CO2 and CO2 Derivatives

Advanced Sustainable Systems, Volume 9, Issue 12, December 2025.
Biobased bamboo shavings are used to immobilize Lewis base catalysts for CO2 valorization. Two methods are investigated for immobilization of catalysts: covalent isocyanate coupling and silane condensation. The isocyanate method achieves 100% conversion of cyclic carbonate starting from epoxides, whereas the silane method yields glycerol carbonate with
Giorgia Albonetti, Alessandro Massi, Daniele Ragno, Lorenzo Poletti, Carmela De Risi, Elena Tamburini, Daniela Summa, Omar Ginoble Pandoli, Graziano Di Carmine   +8 more
wiley   +1 more source

A New Method for the Synthesis of 1-(1-Isocyanoethyl)adamantane

Molbank
A novel single-step method has been developed for the synthesis of 1-(1-isocyanoethyl)adamantane from 1-(1-adamantylethyl)amine, chloroform, and t-BuOK, in a dichloromethane/tert-butanol (1:1) medium, yielding 92%, which is 27% higher compared to the ...
Dmitry Pitushkin, Gennady Butov
doaj   +1 more source