Results 71 to 80 of about 23,536 (214)

Synthesis of α-amino amidines through molecular iodine-catalyzed three-component coupling of isocyanides, aldehydes and amines

Beilstein Journal of Organic Chemistry, 2014
A facile and efficient synthetic protocol for the synthesis of α-amino amidines has been developed using a molecular iodine-catalyzed three-component coupling reaction of isocyanides, amines, and aldehydes. The presented strategy offers the advantages of
Praveen Reddy Adiyala, D. Chandrasekhar, Jeevak Sopanrao Kapure, Chada Narsimha Reddy, Ram Awatar Maurya   +4 more
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Crystal structures of 2,6-dibromo-4-methylbenzonitrile and 2,6-dibromo-4-methylphenyl isocyanide

Acta Crystallographica Section E: Crystallographic Communications, 2017
In the title crystals, C8H5Br2N, which are isomorphous, the steric bulk of the methyl group causes neighboring molecules to become mutually inclined. This prevents the formation of planar or nearly planar sheets, which were observed in the trichloro and ...
Wayland E. Noland, Jessica E. Shudy, Janel L. Rieger, Zoe H. Tu, Kenneth J. Tritch   +4 more
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Synthesis, characterization, DFT and Td-dfT study of the [Fe(mnt)(L)(t-BuNC) 2] octahedral complex (L = phen, bipy)

Química Nova, 2009
FeBr2 has reacted with an equivalent of mnt2- (mnt = cis-1,2-dicyanoethylene-1,2-dithiolate) and the α-diimine L (L = 1,10'-phenantroline, 2,2'-bipyridine) in THF solution, and followed by adding of t-butyl-isocyanide to give [Fe(mnt)(L)(t-BuNC)2 ...
Milton K. MorigakiI, Elias M. da Silva, Carlos V. P. de Melo, Jamile R. Pavan, Renzo C. Silva, Armando Biondo, Jair C. C. Freitas, Gilson H. M. Dias   +7 more
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Bond Forming Reactions Involving Isocyanides at Diiron Complexes

Inorganics, 2019
The versatility of isocyanides (CNR) in organic chemistry has been tremendously enhanced by continuous advancement in transition metal catalysis. On the other hand, the urgent need for new and more sustainable synthetic strategies based on abundant and ...
Rita Mazzoni, Fabio Marchetti, Andrea Cingolani, Valerio Zanotti   +3 more
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Multiple Isocyanide insertions promoted by protic and Lewis acids

Tetrahedron Chem
The protonation, or Lewis Acid complexation, of electrophiles can trigger the sequential insertion of two or more isocyanides resulting in valuable iminonitriles or heterocycles.
John Kornfeind, Fraser F. Fleming
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Optimized Conditions for Passerini-Smiles Reactions and Applications to Benzoxazinone Syntheses

Molecules, 2016
Initial conditions disclosed for the Passerini-Smiles reaction are associated with a lack of efficiency that has prevented chemists from using it since its discovery.
Elodie Martinand-Lurin, Aurélie Dos Santos, Emmanuelle Robineau, Pascal Retailleau, Philippe Dauban, Laurence Grimaud, Laurent El Kaïm   +6 more
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Construction of a Planar Tetrapalladium Cluster by the Reaction of Palladium(0) Bis(isocyanide) with Cyclic Tetrasilane

Inorganics, 2017
The planar tetrapalladium cluster Pd4{Si(iPr)2}3(CNtBu)4 (4) was synthesised in 86% isolated yield by the reaction of palladium(0) bis(isocyanide) Pd(CNtBu)2 with octaisopropylcyclotetrasilane (3).
Yusuke Sunada, Nobuhiro Taniyama, Kento Shimamoto, Soichiro Kyushin, Hideo Nagashima   +4 more
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Reduction of Cyanide and Isocyanide by Nitrogenase of Azotobacter chroococcum [PDF]

, 1967
M T Kelly, J. R. Postgate, Raymond L. Richards   +2 more
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(tert‐Butyl isocyanide) (ethanol)nickel(II) chloride [PDF]

, 1973
R.W. Stephany, Roeland J. M. Nolte, W. Drenth   +2 more
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Thermal explosions of methyl isocyanide: a re-examination of the data [PDF]

, 1979
H. O. Pritchard
openalex   +1 more source