Results 121 to 130 of about 1,583 (164)

Isocyanides inhibit bacterial pathogens by covalent targeting of essential metabolic enzymes. [PDF]

Chem Sci
Geißler A, Junca H, Kany AM, Daumann LJ, Hirsch AKH, Pieper DH, Sieber SA.   +6 more
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Phosphinoisocyanide/Alkyne Cycloaddition: Generation of Azaphospholylidene (NPHC) Ligands. [PDF]

Angew Chem Int Ed Engl
Kirk RM, Hill AF.
europepmc   +1 more source

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Isocyanides

2022
Isocyanides are powerful functionalities by virtue of the carbene-like terminal carbon that imparts unique reactivity. Capable of functioning as electrophiles, nucleophiles, radical acceptors, and in transition metal-catalyzed insertions, isocyanides engage in a plethora of methodologies that generate complex molecules from relatively simple starting ...
Abdullah Bilal Altundas, Fraser F. Fleming   +1 more
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2,4,6-Trimethylphenyl isocyanide

Acta Crystallographica Section C Crystal Structure Communications, 2002
The title compound, C(10)H(11)N, displays a crystallographic mirror plane that incorporates all the non-H atoms, as well as the H atoms attached to the aromatic ring. The isocyano group is almost linear and shows an N[triple bond]C bond distance of 1.158 (3) A.
Manuel A, Fernandes, Marcus, Layh, Bernard, Omondi   +2 more
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Fluoromethyl isocyanide and difluoromethyl isocyanide

Journal of Fluorine Chemistry, 1991
Abstract Whereas methyl isocyanide is known since more than a hundred years, the chemistry of its perfluorinated derivative CNCF 3 , has been developed only recently. Both compounds differ drastically. Herein we report the syntheses of the missing partially fluorinated compounds CNCH 2 F and CNCHF 2 via their pentacarbonyl chromium complexes.
Dagmar Preugschat, Dieter Lentz
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Isocyanide-Based Multicomponent Reaction ‘without’ Isocyanides

Synlett, 2009
We present here a one-pot, four-component sequence that affords Ugi-type adducts starting from simple benzyl or allyl bromides. The isocyanides are prepared in situ under alkylation of silver cyanide salts and the resulting mixture is directly used in a Ugi―Smiles coupling.
El Kaim, Laurent, Grimaud, Laurence, Schiltz, Aurelie   +2 more
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Homoleptic Isocyanide Metalates

Angewandte Chemie International Edition, 1998
Novelties and surprises in the chemistry of metal isocyanides: The synthesis and structure determination of homoleptic isocyanide metalates [M(CNXyl)m ]- (M=Co, m=4; M=Mn, m=5; Xyl=2,6-Me2 C6 H3 ) indicate that we need to revise our understanding of transition metal-isocyanide interactions.
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Functional Isocyanide-Based Polymers

Accounts of Chemical Research, 2020
Research interest in the isocyanide-based reaction can be traced back to 1921 when the Passerini reaction was first reported. However, most of these research efforts did not lead to important progress in the synthesis of isocyanide-based polymers (IBPs).
Zhengxu Cai, Yue Ren, Xiaofang Li, Jianbing Shi, Bin Tong, Yuping Dong   +5 more
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p-Nitrophenyl isocyanide

Acta Crystallographica Section C Crystal Structure Communications, 2004
Achiral p-nitrophenyl isocyanide, C(7)H(4)N(2)O(2), crystallizes in the orthorhombic chiral space group P2(1)2(1)2(1). Attractive intermolecular interactions between the nitro O atoms and both aromatic H and nitro N atoms of neighbouring molecules are observed.
Matthias, Zeller, Allen D, Hunter
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Multicomponent Reactions with Isocyanides

Angewandte Chemie, 2000
Multicomponent reactions (MCRs) are fundamentally different from two-component reactions in several aspects. Among the MCRs, those with isocyanides have developed into popular organic-chemical reactions in the pharmaceutical industry for the preparation of compound libraries of low-molecular druglike compounds.
, Dömling, , Ugi
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