Results 101 to 110 of about 5,434 (218)

The Chemistry of ortho-(Diarylphosphino)aryl Isocyanides

, 2015
The title phosphine-isocyanides were obtained by reaction of 2-lithioaryl isocyanides with diarylchlorophosphines. They cyclize to 1,3-benzazaphospholes with cleavage of their two aryl–P bonds upon treatment with an excess of lithium in THF.
Francois Mathey (1450816), Wenfei Yu (1450813), Youzhi Xu (1450810), Lujun Zhang (506727), Zheng Duan (1450807), Changchun Liu (312471)   +5 more
core   +1 more source

N-Halosuccinimide enables cascade oxidative trifluorination and halogenative cyclization of tryptamine-derived isocyanides

Nature Communications
Both the pyrroloindoline core and N–CF3 moiety hold significant importance in medicinal chemistry. However, to date, no instances of constructing N–CF3-containing pyrroloindolines have been reported.
Jun-Yunzi Wu, Long-Ling Huang, Jia-Luo Fu, Jia-Yi Li, Shuang Lin, Shuang Yang, Zhi-Shu Huang, Honggen Wang, Qingjiang Li   +8 more
doaj   +1 more source

Studies on the interaction of isocyanides with imines: reaction scope and mechanistic variations

Beilstein Journal of Organic Chemistry, 2014
The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon–nitrogen double bond of the imine to form the 4 ...
Ouldouz Ghashghaei, Consiglia Annamaria Manna, Esther Vicente-García, Marc Revés, Rodolfo Lavilla   +4 more
doaj   +1 more source

Palladium-catalyzed synthesis of 2-aminobenzoxazinones by aerobic oxidative coupling of anthranilic acids and isocyanides

, 2013
Isocyanides have emerged as valuable
Ruijter, E.; id_orcid, Vlaar, Tjostil, Vlaar, T., Orru, Romano V.A., Ruijter, Eelco, Maes, B.U.W., Orru, R.V.A.; id_orcid, Maes, Bert U.W.   +7 more
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Oligothiophene Isocyanides for Platinum-Based Molecular Electronic Applications

, 2016
Understanding molecular orientation on a metal surface is key to designing molecular electronic device junctions. Though platinum device electrodes are of particular interest as a more stable alternative to the often used gold electrodes, the ...
Iris Tam (2707051), Ronald Breslow (1835350), Dennis Bong (1563856)   +2 more
core   +1 more source

The Groebke–Blackburn–Bienaymé reaction in its maturity: innovation and improvements since its 21st birthday (2019–2023)

Beilstein Journal of Organic Chemistry
The Groebke–Blackburn–Bienaymé (GBB) three-component reaction, discovered in 1998, is a very efficient strategy to assemble imidazo[1,2-a]-heterocycles starting from amidines, aldehydes and isocyanides.
Cristina Martini, Muhammad Idham Darussalam Mardjan, Andrea Basso   +2 more
doaj   +1 more source

AROMATIC ISOCYANIDES AS NOVEL VISIBLE-LIGHT PHOTOCATALYSTS

Fascinated by the unique electronic properties of isocyanides, we performed the introduction of this functional group on well-known fluorescent structures to exploit their peculiar reactivity.
Andrea Basso, Mariateresa Giustiniano, Cristina Martini, Camilla Russo   +3 more
core  

Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II)

Acta Crystallographica Section E: Crystallographic Communications
In the title compound, [Pt(C14H14N3)Cl(C9H9N)], the platinum atom has a square-planar geometry. In the crystal, dimers with R22(8) motifs are formed by pairs of N—H...N hydrogen bonds.
Olga V. Repina, Elena Yu. Nevskaya, Ilya S. Kritchenkov, Victor N. Khrustalev, Alexander S. Novikov, Alexander G. Tskhovrebov, Namiq Q. Shikhaliyev, Aytan A. Niyazova, Mehmet Akkurt, Ajaya Bhattarai   +9 more
doaj   +1 more source

Synthesis of β‑Aminoenones via Cross-Coupling of In-Situ-Generated Isocyanides with 1,3-Dicarbonyl Compounds

, 2018
An efficient and practical strategy for the synthesis of β-aminoenones from a three-component reaction was developed. Ethyl bromodifluoroacetate serves as a C1 source in this strategy, forming isocyanides in situ with primary amines.
Xingxing Ma (3242427), Qiuling Song (1393048), Yao Zhou (1521676)   +2 more
core   +1 more source

Recent Advances in the Chemistry of Isocyanides with Activated Methylene Group

This review is devoted to the recent advances in the chemistry of methylene isocyanides with C=C, C≡C, C=O, and C=N bonds. In this paper, we show a variety of [3+2] cycloaddition reactions for isocyanides, carried out both under catalytic and non ...
Zhilyaev D.I., Kulikova L.N., Efimov I.V., Voskressensky L.G.   +3 more
core   +1 more source