Results 101 to 110 of about 4,726 (220)

Copper-Catalyzed Trifluoromethylalkynylation of Isocyanides

, 2015
The title reaction proceeds with acetylenic triflones and isocyanides under mild conditions using copper as a catalyst. This transformation provides an efficient access to (E)-N-alkyl trifluoromethyl alkynyl ketoimines, which are useful building blocks ...
Xiaoxing Wu (467093), Jian Lei, Xiaoxing Wu, Qiang Zhu, Jian Lei (495592), Qiang Zhu (188733)   +5 more
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Studies on the interaction of isocyanides with imines: reaction scope and mechanistic variations

Beilstein Journal of Organic Chemistry, 2014
The interaction of imines with isocyanides has been studied. The main product results from a sequential process involving the attack of two units of isocyanide, under Lewis acid catalysis, upon the carbon–nitrogen double bond of the imine to form the 4 ...
Ouldouz Ghashghaei, Consiglia Annamaria Manna, Esther Vicente-García, Marc Revés, Rodolfo Lavilla   +4 more
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Palladium-Catalyzed Diarylation of Isocyanides with Tetraarylleads for the Selective Synthesis of Imines and α‑Diimines

, 2019
Using tetraaryllead compounds (PbAr4) as arylating reagents, isocyanides undergo selective diarylation in the presence of palladium catalysts such as Pd­(OAc)2 or Pd­(PPh3)4 to afford imines and/or α-diimines based on the isocyanide employed.
Hitomi Matsubara (7340288), Akihiro Nomoto (1447150), Yohsuke Kobiki (1667290), Cong Chi Tran (7340285), Dat Phuc Tran (7340291), Shin-ichi Kawaguchi (1667293), Shintaro Kodama (1768459), Akiya Ogawa (1447147)   +7 more
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Metal-Template-Controlled Stabilization of β‑Functionalized Isocyanides

, 2016
Reaction of 2-azidoethyl isocyanide 1, 2-azidophenyl isocyanide 2, or 2-nitrophenyl isocyanide 3 with complexes [Mo­(CO)3(dppe)­(py)] [4] or [W­(CO)3(dppe)­(NCCH3)] [5] yields the isocyanide complexes [Mo­(CO)3(dppe)­(CNR)] ([6]: CNR = 1; [12]: CNR =
Jutta Kösters (1607449), F. Ekkehardt Hahn (1478299), Tania Pape (1768483), Christian Schulte to Brinke (1589215), Kai-Oliver Feldmann (1880269), A. Carolin Dumke (2003704)   +5 more
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Thiol mediated radical cyclisations of isocyanides : synthesis of N-heterocycles

, 2003
This thesis is concerned with the synthesis and radical cyclisations of alkenyl and alkynl isocyanides with thiols. Special interest is given to developing a fast and efficient synthetic route to functionalised N-heterocycles and polycylic systems ...
Lamberto, Massimiliano
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Relative stability and proton transfer reactions of unsaturated isocyanides and cyanides: Relative Stability and Proton Transfer Reactions of Unsaturated Isocyanides and Cyanides

, 2016
International audienceThe typical Gibbs free energy difference between hydrocarbon substituted isocyanides and the corresponding cyanides is 25 to 28 kcal/mol in favor of the cyanides and is mostly independent of the substituent.
Kaljurand, Ivari, Guillemin, Jean-Claude, Adamson, Aiko, Burk, Peeter   +3 more
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The Groebke–Blackburn–Bienaymé reaction in its maturity: innovation and improvements since its 21st birthday (2019–2023)

Beilstein Journal of Organic Chemistry
The Groebke–Blackburn–Bienaymé (GBB) three-component reaction, discovered in 1998, is a very efficient strategy to assemble imidazo[1,2-a]-heterocycles starting from amidines, aldehydes and isocyanides.
Cristina Martini, Muhammad Idham Darussalam Mardjan, Andrea Basso   +2 more
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AROMATIC ISOCYANIDES AS NOVEL VISIBLE-LIGHT PHOTOCATALYSTS

Fascinated by the unique electronic properties of isocyanides, we performed the introduction of this functional group on well-known fluorescent structures to exploit their peculiar reactivity.
Andrea Basso, Mariateresa Giustiniano, Cristina Martini, Camilla Russo   +3 more
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Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II)

Acta Crystallographica Section E: Crystallographic Communications
In the title compound, [Pt(C14H14N3)Cl(C9H9N)], the platinum atom has a square-planar geometry. In the crystal, dimers with R22(8) motifs are formed by pairs of N—H...N hydrogen bonds.
Olga V. Repina, Elena Yu. Nevskaya, Ilya S. Kritchenkov, Victor N. Khrustalev, Alexander S. Novikov, Alexander G. Tskhovrebov, Namiq Q. Shikhaliyev, Aytan A. Niyazova, Mehmet Akkurt, Ajaya Bhattarai   +9 more
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HETEROCYCLES FROM BIARYL ISOCYANIDES: PHENYLNAPHTHYL AND NAPHTHYLPHENYL SYSTEMS.

, 1977
HETEROCYCLES FROM BIARYL ISOCYANIDES: PHENYLNAPHTHYL AND NAPHTHYLPHENYL ...
JAYANTIBHAI R. PATEL (7986260)
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