Results 91 to 100 of about 4,726 (220)
Palladium-Catalyzed Synthesis of α‑Diimines from Triarylbismuthines and Isocyanides
In this study, we report a highly selective coupling reaction between triarylbismuthines and isocyanides using palladium diacetate as the catalyst, affording α-diimines, with the formation of three C–C bonds. Among several aryl sources (Ar–YLn: Y = B, Sn,
Yohsuke Kobiki (1667290) +2 more
core +1 more source
PHOTOCHEMICAL OXIDATION AND ISOMERIZATION OF ISOCYANIDES.
PHOTOCHEMICAL OXIDATION AND ISOMERIZATION OF ...
ANTHONY JACOB JR. SPAK (7964411)
core
Pyrrolidinone and Piperidinone Isocyanides from Isocyano Esters
International audienceThe alkylation of isocyano esters with 1,2- and 1,3-dibromoalkanes affords bromo isocyanides. Under treatment with various amines the latter form new isocyano-substituted lactams, which can be further used in Passerini or Ugi ...
Legras, Laetitia +3 more
core +1 more source
Upon photoirradiation of o-alkynylaryl isocyanides in the presence of iodine, the intramolecular cyclization of o-alkynylaryl isocyanides proceeds to afford the corresponding 2,4-diiodoquinolines in good yields.
Takenori Mitamura (2198395) +1 more
core +3 more sources
Passerini Reactions on Biocatalytically Derived Chiral Azetidines
The purpose of this study was to explore a series of Passerini reactions on a biocatalytically derived enantiopure azetidine-2-carboxyaldehyde in order to obtain, in a diastereoselective manner, polyfunctionalised derivatives having the potential to be ...
Lisa Moni +6 more
doaj +1 more source
Palladium-Catalyzed Multicomponent Reaction (MCR) of Propargylic Carbonates with Isocyanides
A palladium-catalyzed multicomponent reaction (MCR) of propargylic carbonates with isocyanides is reported. Remarkably, the orderly insertion of isocyanides affords two types of valuable N-heterocyclic products (Z)-6-imino-4,6-dihydro-1H-furo[3,4-b ...
Yanwei Ren (1392910) +7 more
core +1 more source
We have recently reported a novel multicomponent reaction between arylacetic acids and isocyanides, affording α-acyloxyacrylamides through an unusual mechanism.
Renata Riva, Andrea Basso, Luca Banfi
doaj +1 more source
Developments in chiral counterion-directed asymmetric reactions
The research outlined herein consists of two projects, each relating to the investigation and development of asymmetric phase-transfer catalysed reactions.
Cavell, Alexander, Alexander Cavell
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Multicomponent Reaction-Based Trimethoprim Analogues as Potential Antibiotics for Resistant Bacteria
Aminoimidazoles are relevant scaffolds in medicinal. [...]
Rodolfo Lavilla +6 more
doaj +1 more source
Isocyanides have emerged as valuable C1 building blocks in palladium catalysis. Their potential has, however, mainly been exploited for the synthesis of amidines and amidine-containing heterocycles. To illustrate the broader applicability of isocyanides,
Tjøstil Vlaar (1863328) +3 more
core +1 more source

