Results 121 to 130 of about 1,650 (181)
Unveiling the Phosphine-Mediated N-Transfer from Azide to Isocyanide en Route to Carbodiimides and 4-Imino-1,3,2-diazaphosphetidines. [PDF]
Org LettPastor A +7 more
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<i>O</i>-Vinylhydroxylamines for <i>De Novo</i> Pyrrole Synthesis. [PDF]
J Am Chem SocRandolph C +4 more
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Revisiting CNC<sub>6</sub>F<sub>5</sub>: The Quest for Isocyanide Ligands with Strong π‑Acceptor Properties Evaluated by Energy Decomposition Analysis. [PDF]
ACS OmegaStreit TN +3 more
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Multicomponent Reactions with Isocyanides
Angewandte Chemie - International Edition, 2000Multicomponent reactions (MCRs) are fundamentally different from two-component reactions in several aspects. Among the MCRs, those with isocyanides have developed into popular organic-chemical reactions in the pharmaceutical industry for the preparation of compound libraries of low-molecular druglike compounds.
Alexander Domling
exaly +3 more sources
2022
Isocyanides are powerful functionalities by virtue of the carbene-like terminal carbon that imparts unique reactivity. Capable of functioning as electrophiles, nucleophiles, radical acceptors, and in transition metal-catalyzed insertions, isocyanides engage in a plethora of methodologies that generate complex molecules from relatively simple starting ...
Abdullah Bilal Altundas +1 more
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Isocyanides are powerful functionalities by virtue of the carbene-like terminal carbon that imparts unique reactivity. Capable of functioning as electrophiles, nucleophiles, radical acceptors, and in transition metal-catalyzed insertions, isocyanides engage in a plethora of methodologies that generate complex molecules from relatively simple starting ...
Abdullah Bilal Altundas +1 more
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Fluoromethyl isocyanide and difluoromethyl isocyanide
Journal of Fluorine Chemistry, 1991Abstract Whereas methyl isocyanide is known since more than a hundred years, the chemistry of its perfluorinated derivative CNCF 3 , has been developed only recently. Both compounds differ drastically. Herein we report the syntheses of the missing partially fluorinated compounds CNCH 2 F and CNCHF 2 via their pentacarbonyl chromium complexes.
Dagmar Preugschat, Dieter Lentz
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Journal of the American Chemical Society, 1978
H/sub 2/Os/sub 3/(CO)/sub 10/ was reacted with phenyl isocyanide to form H/sub 2/Os/sub 3/(CO)/sub 10/(CNC/sub 6/H/sub 5/), which upon refluxing loses 1 mol CO to form a new complex that is believed to be a possible intermediate in the phenyl isocyanide reduction process. The molecular structure of the last complex was determined. (DLC)
Richard D. Adams, Nancy M. Golembeski
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H/sub 2/Os/sub 3/(CO)/sub 10/ was reacted with phenyl isocyanide to form H/sub 2/Os/sub 3/(CO)/sub 10/(CNC/sub 6/H/sub 5/), which upon refluxing loses 1 mol CO to form a new complex that is believed to be a possible intermediate in the phenyl isocyanide reduction process. The molecular structure of the last complex was determined. (DLC)
Richard D. Adams, Nancy M. Golembeski
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The Nef Reaction of Isocyanides
Synthesis, 2014The interaction of isocyanides with acyl chlorides was first reported by Nef in 1892. The resulting α-keto imidoyl chlorides may be hydrolyzed to form α-keto amides. Relatively few data are available on this reaction and the chemistry of α-keto imidoyl chlorides has been largely underestimated until some recent uses in intra- and intermolecular ...
Fabio La Spisa +2 more
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2,4,6-Trimethylphenyl isocyanide
Acta Crystallographica Section C Crystal Structure Communications, 2002The title compound, C(10)H(11)N, displays a crystallographic mirror plane that incorporates all the non-H atoms, as well as the H atoms attached to the aromatic ring. The isocyano group is almost linear and shows an N[triple bond]C bond distance of 1.158 (3) A.
Manuel A, Fernandes +2 more
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Isocyanide-Based Multicomponent Reaction ‘without’ Isocyanides
Synlett, 2009We present here a one-pot, four-component sequence that affords Ugi-type adducts starting from simple benzyl or allyl bromides. The isocyanides are prepared in situ under alkylation of silver cyanide salts and the resulting mixture is directly used in a Ugi―Smiles coupling.
El Kaim, Laurent +2 more
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