Results 81 to 90 of about 8,819 (284)
This review summarizes the synthetic methodologies of the nitro‐substituted Donor‐Acceptor cyclopropanes (NCPs). Particularly from nitroalkenes including the Michael Initiated Ring Closure and the Oxidative Ring Closure of Michael Adducts, from Diazo Compounds bearing Nitro Group, from Nitromethane and its Derivatives; and after Oxidation of ...
Andriani G. Chaidali+2 more
wiley +1 more source
An unexpected transformation by reduction of isoxazolines
Abstract Aromatic nitrile oxides undergo regio- and stereo-specific 1,3-dipolar cycloaddition reactions with racemic 5-hydroxy-4-methyl-1,5-dihydropyrrol-2-one derivatives 1 . In each case, a single product 3 results from an anti approach to the hydroxyl group, the oxygen of the 1,3-dipole being attached to C-5 of pyrrolidinones.
Moncef Msaddek, Naoufel Ben Hamadi
openaire +2 more sources
Asymmetric 1,3-dipolar cycloadditions of acrylamides [PDF]
This critical review, which is relevant to researchers in synthetic organic chemistry, focuses on asymmetric 1,3-dipolar cycloadditions with acrylamides.
Kissane, Marie, Maguire, Anita R.
core +1 more source
Electrochemical Synthesis of Isoxazoles and Isoxazolines via Anodic Oxidation of Oximes
Isoxazol(in)es are widely featured structural motifs in natural products, agrochemicals, and pharmaceuticals. The first intermolecular approach for a direct electrochemical synthesis from readily available aldoximes is reported.
Silja Hofmann+4 more
doaj +1 more source
A nitrogen‐doped carbon nitride (NCN) has been synthesized and applied for the sustainable generation of reactive nitrogen and oxygen radicals. The NCN catalyst facilitates radical carboamination, oxyamination, and deoxygenation reactions, as well as the oxidation of boronic acids and alcohols, all under mild photocatalytic conditions.
Lan Qin+4 more
wiley +1 more source
A dehydrogenative photoredox catalyzed formal C(sp3)‐H intramolecular cyclization of indolyl‐oximes to generate indolyl Δ2‐isoxazolines is reported. In contrast to the current state‐of‐the‐art, the reaction avoids the use of super stoichiometric chemical oxidants and high reaction temperatures and is proposed to operate via two sequential single ...
Jonathan Da Luz+5 more
wiley +1 more source
Glucopyranosylidene-Spiro-Thiazolinones: Synthetic Studies and Determination of Absolute Configuration by TDDFT-ECD Calculations [PDF]
Reactions of O-peracylated C-(1-bromo-β-d-glucopyranosyl)formamides with thioamides furnished the corresponding glucopyranosylidene-spiro-thiazolin-4-one.
Kun, Sándor+4 more
core +2 more sources
Recent Development of DNA‐based Biohybrid Systems Driven by Light
Merging the fields of photochemistry and DNA‐based materials paved the way for unprecedented reactivities and applications. This review focuses on recent developments around the design of biohybrid DNA‐based nanosystems driven by light with a particular emphasis on cross‐linking and ligation reactions, programmable photo‐release and DNA‐encoded ...
Zachary Pastorel+4 more
wiley +1 more source
Background The human botfly, Dermatobia hominis, is a common cause of furuncular myiasis in dogs in Latin America. Lesions can be single or multiple, each harboring an individual larva, presented as an erythematous nodule that causes pruritus and pain ...
Paula A. Andriotti+5 more
doaj +1 more source
There are continuous efforts to improve total syntheses of natural products, particularly their sustainability, such as developing effective chiral pool approaches relying on a wide spectrum of natural chirons, including (−)‐sclareol as one of the most useful natural chirons.
Ayyoub Selka+5 more
wiley +1 more source