Results 11 to 20 of about 2,492,262 (305)

Sequential curing of thiol-acetoacetate-acrylate thermosets by latent Michael addition reactions [PDF]

open access: yes, 2017
Thiol-acetoacetate-acrylate ternary dual-curing thermosets were prepared by a sequential process consisting of thiol-Michael addition to acrylates at room temperature followed by Michael addition of acetoacetates to acrylates at moderately elevated ...
Fernández Francos, Xavier   +5 more
core   +2 more sources

Synthesis and Spectral Characterization of Some New Substituted Bis-spirocyclohexanones Derived from Acetone

open access: yesScience Journal of University of Zakho, 2018
Diarylidene acetones (DAA) (1-5) had been prepared by the condensation of acetone with substituted benzaldehydes via Claisen-Schmidt reaction, DAA’s brought to condense with anthrone to afford the title compounds (6-10) through Michael addition.
Mohammed S. Hussein   +2 more
doaj   +1 more source

Acetoacetate based thermosets prepared by dual-Michael addition reactions [PDF]

open access: yes, 2019
A novel set of dual-curable multiacetoacetate-multiacrylate-divinyl sulfone ternary materials with versatile and manipulable properties are presented.
Fernández Francos, Xavier   +3 more
core   +2 more sources

A new class of phthalimido-quinones synthesis

open access: yesOrbital: The Electronic Journal of Chemistry, 2012
Four new Michael adducts from the reaction between 1,4-naphthoquinone and 2,3-dibromo-1,4-naphthoquinone with w-amino-N-alkylphthalamide derivatives were presented in this work.
Jeziane S. Alves   +2 more
doaj   +1 more source

Electrooxidation of Catechols in the Presence of Sulfite: Presentation of a Facile and Green Method for Aromatic Sulfonation

open access: yesInternational Journal of Electrochemical Science, 2007
Electrochemical oxidation of catechols (1a-e) has been studied in the presence of sulfite ion (3) as nucleophile in aqueous solution, using cyclic voltammetry and controlled-potential coulometry. The results indicate the participation of catechols (1a-e)
D. Nematollahi, E. Tammari, H. Karbasi
doaj   +1 more source

Superelastic and pH-Responsive Degradable Dendrimer Cryogels Prepared by Cryo-aza-Michael Addition Reaction [PDF]

open access: yes, 2018
Dendrimers exhibit super atomistic features by virtue of their well-defined discrete quantized nanoscale structures. Here, we show that hyperbranched amine-terminated polyamidoamine (PAMAM) dendrimer G4.0 reacts with linear polyethylene glycol (PEG ...
Wang, Juan, Yang, Hu
core   +3 more sources

Enantioselective Michael Addition of Water [PDF]

open access: yesChemistry – A European Journal, 2014
AbstractThe enantioselective Michael addition using water as both nucleophile and solvent has to date proved beyond the ability of synthetic chemists. Herein, the direct, enantioselective Michael addition of water in water to prepare important β‐hydroxy carbonyl compounds using whole cells of Rhodococcus strains is described.
Chen, B.S. (author)   +3 more
openaire   +4 more sources

Dual-functional materials via CCTP and selective orthogonal thiol-Michael addition/epoxide ring opening reactions [PDF]

open access: yes, 2013
Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two points for post polymerisation functionalisation; the activated terminal vinyl bond and in chain ...
Haddleton, David M.   +3 more
core   +1 more source

Sequential curing of amine-acrylate-methacrylate mixtures based on selective aza-Michael addition followed by radical photopolymerization [PDF]

open access: yes, 2016
Dual curing systems find various uses in industry with the process flexibility they provide which allows tailoring properties at different curing stages in accordance with application requirements. A safe and efficient dual curing scheme is proposed here
Fernández Francos, Xavier   +3 more
core   +1 more source

1,4-Dihydro-4-(nitromethyl)-2-phenyl-1-tosylquinoline-3-carbaldehyde

open access: yesMolbank, 2016
An aza-Michael/Michael cascade reaction of 2-((E)-2-nitrovinyl)-N-tosylbenzenamine with 3-phenylpropiolaldehyde catalyzed by pyrrolidine has produced a new compound, 1,4-dihydro-4-(nitromethyl)-2-phenyl-1-tosylquinoline-3-carbaldehyde.
Kwang Min Ko, Sung-Gon Kim
doaj   +1 more source

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