Results 21 to 30 of about 10,194,470 (308)

Synthesis and Spectral Characterization of Some New Substituted Bis-spirocyclohexanones Derived from Acetone

open access: yesScience Journal of University of Zakho, 2018
Diarylidene acetones (DAA) (1-5) had been prepared by the condensation of acetone with substituted benzaldehydes via Claisen-Schmidt reaction, DAA’s brought to condense with anthrone to afford the title compounds (6-10) through Michael addition.
Mohammed S. Hussein   +2 more
doaj   +1 more source

Solvent- and catalyst-free aza-Michael addition of imidazoles and related heterocycles [PDF]

open access: yes, 2020
This work demonstrates the scope and limitations of the aza-Michael addition of imidazoles and related heterocycles with electron deficient olefins under solvent- and catalyst-free conditions. The reaction proceeds at 80°C within hours towards completion
Florian, Gobec   +2 more
core   +2 more sources

A new class of phthalimido-quinones synthesis

open access: yesOrbital: The Electronic Journal of Chemistry, 2012
Four new Michael adducts from the reaction between 1,4-naphthoquinone and 2,3-dibromo-1,4-naphthoquinone with w-amino-N-alkylphthalamide derivatives were presented in this work.
Jeziane S. Alves   +2 more
doaj   +1 more source

Study of Michael-Michael-retro Michael addition catalyzed, by 9-amino-9-deoxyepiquinine using ESI-MS [PDF]

open access: yes, 2007
The Michael-Michael-retro Michael addition catalyzed by 9-amino-9-deoxyepiquinine was monitored and the major intermediates and catalyst in the catalytic cycle were detected and characterized using ESI-MS/MS for the first time.
Xie, JW   +6 more
core   +2 more sources

Electrooxidation of Catechols in the Presence of Sulfite: Presentation of a Facile and Green Method for Aromatic Sulfonation

open access: yesInternational Journal of Electrochemical Science, 2007
Electrochemical oxidation of catechols (1a-e) has been studied in the presence of sulfite ion (3) as nucleophile in aqueous solution, using cyclic voltammetry and controlled-potential coulometry. The results indicate the participation of catechols (1a-e)
D. Nematollahi, E. Tammari, H. Karbasi
doaj   +1 more source

Enantioselective Michael Addition: An Experimental Introduction to Asymmetric Synthesis [PDF]

open access: yes, 2019
We adapted a classical asymmetric Michael addition for a 1-day experimental session (6-8 hrs) for third or fourth-year undergraduate students. The experiment follows up three steps : synthesis of a chiral Lewis Acid, LiAl(BINOL)2, then its use as a ...
Martin Tiano (5934035)   +3 more
core   +2 more sources

1,4-Dihydro-4-(nitromethyl)-2-phenyl-1-tosylquinoline-3-carbaldehyde

open access: yesMolbank, 2016
An aza-Michael/Michael cascade reaction of 2-((E)-2-nitrovinyl)-N-tosylbenzenamine with 3-phenylpropiolaldehyde catalyzed by pyrrolidine has produced a new compound, 1,4-dihydro-4-(nitromethyl)-2-phenyl-1-tosylquinoline-3-carbaldehyde.
Kwang Min Ko, Sung-Gon Kim
doaj   +1 more source

Organocatalytic Enantioselective Michael Reaction of Aminomaleimides with Nitroolefins Catalyzed by Takemoto’s Catalyst

open access: yesMolecules, 2022
Known as electrophiles, maleimides are often used as acceptors in Michael additions to produce succinimides. However, reactions with maleimides as nucleophiles for enantioselective functionalization are only rarely performed.
Hongwen Mu   +4 more
doaj   +1 more source

Electron-rich triarylphosphines as nucleophilic catalysts for oxa-Michael reactions

open access: yesBeilstein Journal of Organic Chemistry, 2021
Electron-rich triarylphosphines, namely 4-(methoxyphenyl)diphenylphosphine (MMTPP) and tris(4-trimethoxyphenyl)phosphine (TMTPP), outperform commonly used triphenylphosphine (TPP) in catalyzing oxa-Michael additions.
Susanne M. Fischer   +3 more
doaj   +1 more source

A Simple Zinc-Mediated Method for Selenium Addition to Michael Acceptors

open access: yesMolecules, 2020
In this work, we focused our attention on seleno-Michael type reactions. These were performed using zinc-selenolates generated in situ from diphenyl diselenide 1, 1,2-bis(3-phenylpropyl)diselenide 30, and protected selenocystine 31 via an efficient ...
Francesca Giulia Nacca   +4 more
doaj   +1 more source

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