Results 31 to 40 of about 2,480,939 (303)

Aza-Michael mono-addition using acidic alumina under solventless conditions [PDF]

open access: yes, 2016
Aza-Michael reactions between primary aliphatic and aromatic amines and various Michael acceptors have been performed under environmentally-friendly solventless conditions using acidic alumina as a heterogeneous catalyst to selectively obtain the ...
Abdilla, Roderick, Bosica, Giovanna
core   +2 more sources

Simple one pot preparation of chemical hydrogels from cellulose dissolved in cold LiOH/urea [PDF]

open access: yes, 2020
In this work, non-derivatized cellulose pulp was dissolved in a cold alkali solution (LiOH/urea) and chemically cross-linked with methylenebisacrylamide (MBA) to form a robust hydrogel with superior water absorption properties.
Lindman, Björn   +3 more
core   +1 more source

Dual-functional materials via CCTP and selective orthogonal thiol-Michael addition/epoxide ring opening reactions [PDF]

open access: yes, 2013
Poly(glycidyl methacrylate) (PGMA) has been synthesised by cobalt catalysed chain transfer polymerisation (CCTP) yielding, in one step, polymers with two points for post polymerisation functionalisation; the activated terminal vinyl bond and in chain ...
Haddleton, David M.   +3 more
core   +1 more source

Enantioselective Michael Addition of Water [PDF]

open access: yesChemistry – A European Journal, 2014
AbstractThe enantioselective Michael addition using water as both nucleophile and solvent has to date proved beyond the ability of synthetic chemists. Herein, the direct, enantioselective Michael addition of water in water to prepare important β‐hydroxy carbonyl compounds using whole cells of Rhodococcus strains is described.
Chen, B.S. (author)   +3 more
openaire   +4 more sources

6-exo-trig Michael addition-lactonizations for catalytic enantioselective chromenone synthesis [PDF]

open access: yes, 2017
The authors thank the EPSRC Centre for Doctoral Training in Critical Resource Catalysis (CRITICAT, grant code EP/L016419/1, RMNP) for funding.The European Research Council under the European Union’s Seventh Framework Programme (FP7/2007-2013) ERC Grant ...
Cordes, David Bradford   +3 more
core   +1 more source

Regioselective 1,4-trifluoromethylation of α,β-unsaturated ketones via a S-(trifluoromethyl)diphenylsulfonium salts/copper system

open access: yesBeilstein Journal of Organic Chemistry, 2013
Regioselective conjugate 1,4-trifluoromethylation of α,β-unsaturated ketones by the use of shelf-stable electrophilic trifluoromethylating reagents, S-(trifluoromethyl)diphenylsulfonium salts and copper under mild conditions is described. A wide range of
Satoshi Okusu   +3 more
doaj   +1 more source

Elimination Reaction-Based Benzimidazole Probe for Cysteine Detection and Its Application in Serum Sample Analysis

open access: yesBiosensors, 2022
Benzimidazole-based compound 2-(p-tolyl)-1H-benzo[d]imidazole (3) and its derivative probe A-B have been synthesized for the highly selective detection and quantification of Cys in human serum.
In-ho Song   +3 more
doaj   +1 more source

Recent Advances in Asymmetric Organocatalyzed Conjugate Additions to Nitroalkenes

open access: yesMolecules, 2017
The asymmetric conjugate addition of carbon and heteroatom nucleophiles to nitroalkenes is a very interesting tool for the construction of highly functionalized synthetic building blocks.
Diego A. Alonso   +6 more
doaj   +1 more source

A stereoselective synthesis of (R)-(-)-rolipram from L-glutamic acid [PDF]

open access: yes, 1997
A stereoselective synthesis of (R)-(-)-rolipram from L-glutamic acid is described. The key step is a stereoselective Michael addition of an arylcuprate to a modified pyroglutamic derivative which acts as the template to induce the stereoselectivity ...
Díaz Martínez, Adolfo   +4 more
core   +3 more sources

Asymmetric Conjugate Addition of α,α-Disubstituted Aldehydes to Nitroalkenes Organocatalyzed by Chiral Monosalicylamides from trans-Cyclohexane-1,2-Diamines

open access: yesMolecules, 2018
Primary amine-salicylamides derived from chiral trans-cyclohexane-1,2-diamines are used as organocatalysts for the enantioselective conjugate addition of α,α-disubstituted aldehydes to arylated and heteroarylated nitroalkenes.
José R. Martínez-Guillén   +4 more
doaj   +1 more source

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