Results 111 to 120 of about 93,015 (287)

Decarboxylation-Driven Double Annulations: Innovative Multi-Component Reaction Pathways

Molecules
A concerted five-component reaction strategy has been developed, featuring double [3+2] cycloadditions utilizing aspartic acid. This approach provides valuable insights into mechanistic pathways, allowing for the distinction between concerted and ...
Desheng Zhan, Gang Yang, Tieli Zhou, Sashirekha Nallapati, Xiaofeng Zhang   +4 more
doaj   +1 more source

One-Pot Solvent-Free Three-Component Synthesis of Conjugated Enaminones Containing Three Alkyl Carboxylate Groups

Journal of Chemistry, 2013
An effective, one-pot, multicomponent, and solvent-free reaction for synthesis of conjugated enaminones containing three alkyl carboxylate groups is described. The reaction of primary amine, alkyl acetoacetate, and dialkyl acetylenedicarboxylate obtained
N. Zohreh, A. Alizadeh, M. Babaki
doaj   +1 more source

Biolipid Film‐Fused Electrochemiluminescence for Multipurpose In Situ Bioassays

Advanced Science, EarlyView.
An ECL‐emissive, membrane‐interactive scaffold was fabricated, and facilely fused with natural and non‐native phospholipids into multifactorial mimicries of cytomembranes and vesicles for in vitro representative membrane‐process probing. Such a biointerface‐based, state‐sensitive ECL paradigm not only pinpointed proximal phenomena, including channeling
Jialiang Chen, Bin Li, Yingying Wang, Fulin Zhu, Wenxuan Yang, Xuanyu Fu, Tiantian Man, Qiuyue Wu, Kewei Ren, Shengyuan Deng   +9 more
wiley   +1 more source

Active Methylene-based Multicomponent Reactions under Microwave Heating

CHIMIA, 2011
The use of emerging multicomponent reactions (MCRs) in conjunction with microwave (MW)-assisted chemistry techniques is dramatically reducing chemical waste and reaction times in several organic syntheses and chemical transformations.
Bo Jiang, Shu-Jiang Tu
doaj   +1 more source

High‐Throughput Screening and Interpretable Machine Learning for Rational Design of Bimetallic Catalysts for Methane Activation

Advanced Science, EarlyView.
ABSTRACT Methane's efficient catalytic removal is vital for sustainable development. Bimetallic catalysts, though promising for methane activation, pose a design challenge due to their complex compositional space. This work introduces an integrated framework that combines high‐throughput density functional theory (DFT) and interpretable machine ...
Mingzhang Pan, Tian Zhang, Jiawei Dong, Yubao Xie, Kaifeng Zhong, Wei Guan, Haiqiao Wei, Changcheng Fu, Yaqiong Su   +8 more
wiley   +1 more source

Formaldehyde surrogates in multicomponent reactions

Beilstein Journal of Organic Chemistry
Formaldehyde emerges as a cornerstone in multicomponent reactions, mainly prized for its robust reactivity. Yet, alongside these beneficial traits, this highly reactive C1-building block raises concerns, primarily regarding its toxicity. One notable issue is the challenge of controlling the formation of undesired byproducts during its reactions.
Cecilia I Attorresi, Javier A Ramírez, Bernhard Westermann   +2 more
openaire   +3 more sources

Tracing the Dynamic Chemical Transformations of Spiro‐OMeTAD in Operating Perovskite Solar Cells

Advanced Science, EarlyView.
Mapping of Spiro‐OMeTAD layer's chemistry and electronic properties in PSC: Advanced cluster ion‐beam sputtering depth profile XPS reveals that environmental stressors (light, potential, and moisture) trigger the decomposition of LiTFSI dopants in Spiro‐OMeTAD.
Chittaranjan Das, Mayank Kedia, Kenedy Tabah Tanko, Yunshan Wang, Christian Njel, Monica Lira‐Cantu, Michael Saliba   +6 more
wiley   +1 more source

Studies on the Synthesis of DMAP Derivatives by Diastereoselective Ugi Reactions

Molecules, 2011
Diastereoselective Ugi reactions of DMAP-based aldehydes with α-amino acids and tert-butyl isocyanide were examined. The reactions of 4-(dimethylamino)-2-pyridine-carboxaldehyde with various α-amino acids afforded 2-substituted DMAP derivatives with low ...
Koichi Mitsudo, Seiji Suga, Hiroki Mandai, Shunsuke Irie   +3 more
doaj   +1 more source

Multicomponent Reactions (MCRs) [PDF]

, 2019
Multicomponent reactions (MCRs) involving three or more components have good pot, atom and step economy. There are dozens of well-known MCRs in literature. Selective examples of newly introduced MCRs, high–order MCRs, MCRs followed by post-condensation modifications, and consecutive MCRs are presented in this chapter.
Wei Zhang, Wen-Bin Yi
openaire   +1 more source

Nanocurvature‐Activated Dipolar Polarization in M–N4 Single‐Atom Sites for High‐Performance Electromagnetic Wave Absorption

Advanced Science, EarlyView.
Increasing nanocurvature effectively enriches the local electron density of the M–N4 motif, which facilitates electron transfer from the metal center to nitrogen atoms. This electronic behavior intensifies the localization and asymmetric distribution of charge, thereby significantly amplifying the dipole moment and polarizability.
Daohu Sheng, Siyao Cheng, Mengmeng Zhang, Jinglei Zhang, Xufei Zhu, Weijin Li, Bo Zhang, Aming Xie   +7 more
wiley   +1 more source