Results 121 to 130 of about 12,782 (291)

Syntheses of Isoxazoline-Based Amino Acids by Cycloaddition of Nitrile Oxides and Their Conversion into Highly Functionalized Bioactive Amino Acid Derivatives [PDF]

open access: yes, 2012
The present account illustrates the syntheses of isoxazoline- based amino acids by the cycloaddition of 1,3-dipolar nitrile oxides to the C–C double bond of unsaturated amino acid derivatives, with focus on the regio- and stereoselectivities of the ...
Fülöp, Ferenc   +2 more
core  

Monolithic UV‐Laser Programming of Photothermally Meta‐Morphing SMA Structures: Dual‐Encoded Kirigami Mechanics and Photonic Absorbance

open access: yesAdvanced Science, EarlyView.
A monolithic manufacturing strategy is presented for photothermal shape memory alloy (SMA) meta‐morphing structures. Using a single‐step UV‐laser process, the mechanical compliance is programmed via kirigami patterning while optical absorbance is simultaneously tuned through surface oxidation.
Hyunsoo Kim   +8 more
wiley   +1 more source

Reaction of pyrroles with ethyl 2-nitroso- and 2-azo-propenoates, and with ethyl cyanoformate N-oxide: a comparison of the reaction pathways [PDF]

open access: yes, 2012
The reaction of ethyl 2-nitrosopropenoate 2a with 1 -methylpyrrole, 2.5-dimethylpyrrole and 2.5- diphenylpyrrole has been investigated. In every case the products result from highly regioselective attack at C-2 of the pyrrole by the electrophile.
Gilchrist, Thomas L., Lemos, A.
core  

Toward Fast‐Charging Polymer‐Electrolyte Based All‐Solid‐State Li–S Batteries: Insights into Limiting Factors and Perspectives

open access: yesAdvanced Science, EarlyView.
The schematic illustrates the important design strategies for polymer solid electrolyte‐based all‐solid‐state lithium‐sulfur batteries (ASSLSBs), including improved ionic conductivity, reduced polysulfide shuttling, stabilized electrode‐electrolyte interfaces, and lithium dendrite mitigation for developing high power and fast charging ASSLSBs ...
S. Jayasubramaniyan   +5 more
wiley   +1 more source

Heterointerface‑Enabled Electrocatalysis for Efficient Energy Conversion

open access: yesAdvanced Science, EarlyView.
Functionally distinct A/B materials can be integrated at the nanoscale to create customized heterointerfaces with tunable band alignment and charge redistribution, providing fast electron and ion transport channels as well as cooperative dual active sites.
Liuru Fang   +3 more
wiley   +1 more source

Epimerization of chlorophyll derivatives [PDF]

open access: yes, 1992
Mazaki, Hitoshi   +4 more
core   +1 more source

Kinsenoside Targets IDH1 to Restore Microglial Immune‐Metabolic Homeostasis for Alzheimer's Disease Therapy

open access: yesAdvanced Science, EarlyView.
Dysregulated TCA cycle contributes to Alzheimer's disease (AD) pathogenesis. Here, we show that microglial isocitrate dehydrogenase 1 (IDH1) is a critical driver. Elevated IDH1 disrupts citrate metabolism and mitochondrial function, exacerbating AD pathology.
Qianqian Li   +13 more
wiley   +1 more source

A Comprehensive Study of the Synthesis, Spectral Characteristics, Quantum–Chemical Molecular Electron Density Theory, and In Silico Future Perspective of Novel CBr3-Functionalyzed Nitro-2-Isoxazolines Obtained via (3 + 2) Cycloaddition of (E)-3,3,3-Tribromo-1-Nitroprop-1-ene

open access: yesMolecules
The search for new heterocyclic compounds with biological potential is one of the current challenges in modern chemistry. Therefore, the comprehensive study of (3 + 2) cycloaddition (32CA) reactions between a series of aryl-substituted nitrile N-oxides ...
Karolina Zawadzińska-Wrochniak   +5 more
doaj   +1 more source

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