Results 21 to 30 of about 3,217 (192)
Regiochemical aspects and the molecular mechanism of the [3 + 2] cycloaddition between nitrous oxide and conjugated nitroalkenes were evaluated on the basis of the wb97xd/6-311 + G(d) (PCM) computational study.
Ewa Dresler +2 more
doaj +1 more source
A chiral primary amine-salicylamide is used as an organocatalyst for the enantioselective conjugate addition of α,α-disubstituted aldehydes to maleimides and nitroalkenes.
Alejandro Torregrosa-Chinillach +3 more
doaj +1 more source
Nitro Fatty Acids (NO2-FAs): An Emerging Class of Bioactive Fatty Acids
Unsaturated nitro fatty acids (NO2-FAs) constitute a category of molecules that may be formed endogenously by the reaction of unsaturated fatty acids (UFAs) with secondary species of nitrogen monoxide and nitrite anions.
Giorgos S. Koutoulogenis, George Kokotos
doaj +1 more source
An Improved and Easy Method for the Preparation of 2,2-Disubstituted 1-Nitroalkenes
Reactions of ketones 1, nitromethane 2, and catalytic amount of piperidine 3 in the presence of mercaptan 6 generate β-nitroalkyl sulfides 7−9. At 0 °C and by the use of dichloromethane as solvent, β-nitroalkyl sulfides 7−9 can be oxidized by m ...
Yeh Wang (3026685) +6 more
core +2 more sources
Nickel-catalysed asymmetric Michael Additions of 2-acetylazaarenes to nitroalkenes.
Azaarenes are of widespread chemical significance, being present in numerous chiral, biologically active natural products, and serving as building blocks for the discovery of new medicines, agrochemicals, and functional molecules.
Simpson, Alain
core +3 more sources
An enantio- and diastereodivergent [2+2+1] annulation reaction of allyl ketones, acidic methylene compounds, and nitroalkenes to assemble highly functionalized cyclopentanes from readily available substances enabled by asymmetric relay catalysis of ...
Lian-Feng Fan +3 more
doaj +1 more source
Enantioselective nickel-catalysed Michael additions of azaarylacetates and acetamides to nitroalkenes [PDF]
I. Catalytic Conjugate Allylation of Alkylidene Malonates Nucleophilic conjugate addition of allylsilanes and allylstannanes to alkylidene malonates under the action of ytterbium catalysis in the presence of hexafluoro-isopropanol has been developed ...
Fallan, Charlene
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An Efficient Method for the N-Bromosuccinimide Catalyzed Synthesis of Indolyl-Nitroalkanes
An efficient and practical method for the synthesis of indolyl-nitroalkane derivatives catalyzed by N-bromosuccinimide is described. The generality of this method was demonstrated by synthesizing an array of diverse 3-substituted indole derivatives by ...
Ching-Fa Yao +6 more
doaj +1 more source
Post-Translational Modification of Proteins Mediated by Nitro-Fatty Acids in Plants: Nitroalkylation
Nitrate fatty acids (NO2-FAs) are considered reactive lipid species derived from the non-enzymatic oxidation of polyunsaturated fatty acids by nitric oxide (NO) and related species.
Lorena Aranda-Caño +7 more
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The solution photochemistry of nitroalkenes and nitroketones. [PDF]
The thesis describes an investigation or the solution photochemistry of nitroalkenes and α-nitroketones, The introduction discusses the general concepts of photochemistry and provides a detailed review of the photochemistry of nitroalkenes, nitroalkanes ...
Moles, Peter J.
core +1 more source

