Mukaiyama-Michael vinylogous additions to nitroalkenes under solvent-free conditions
Open Chemistry, 2012 The first Mukaiyama-Michael vinylogous reaction of a dioxinone-derived silyl ether to nitroalkenes is reported. The conjugate addition is performed in absence of any catalyst under solvent-free conditions, proceeding with satisfactory efficiency with ...
Scettri Arrigo +3 more
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The Puzzle of the New Type of Intermediate in the Course of [2 + 2] Cycloaddition with the Participation of Conjugated Nitroalkenes: MEDT Computational Study [PDF]
MoleculesThe phenomena of regio- and stereoselectivity and the molecular mechanism of the [2 + 2] cycloaddition reaction between (E)-2-arylnitroethenes and the ynamine molecular system were analyzed using wb97xd/6-311 + G(d) (PCM) quantumchemical calculations. It
Radomir Jasiński, Agnieszka Kącka-Zych
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, 2009 The literature up to July 2008 dealing with catalytic enantioselective FC alkylation of aromatic compounds with nitroalkenes has been reviewed. Both metal-mediated and organocatalysis have been employed leading to a vast array of enantiomerically pure compounds most of them of interest in medicinal chemistry.
BERNARDI, LUCA, RICCI, ALFREDO MARCO
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Small molecule nitroalkenes inhibit RAD51-mediated homologous recombination and amplify triple-negative breast cancer cell killing by DNA-directed therapies [PDF]
Redox Biology, 2023 Nitro fatty acids (NO2-FAs) are endogenously generated lipid signaling mediators from metabolic and inflammatory reactions between conjugated diene fatty acids and nitric oxide or nitrite-derived reactive species.
Lisa Hong +20 more
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Chemoselective synthesis of functionalized conjugated nitroalkenes
The Journal of Organic Chemistry, 1992 The present one-pot methodology to obtain conjugated nitroalkenes from aldehydes and nitroalkanes is mild, and highly selective, and proceedsin good yields also on a large scale.
BALLINI, Roberto +2 more
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Enantioselective addition of sodium bisulfite to nitroalkenes. A convenient approach to chiral sulfonic acids [PDF]
, 2021 An enantioselective organocatalytic addition of sodium bisulfite to (E)-nitroalkenes has been developed by using a chiral bifunctional organocatalyst. The present methodology provides a variety of chiral β-nitroethanesulfonic acid compounds (17 examples)
Muñoz, M. Carmen +20 more
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Molecules, 2019 A chiral primary amine-salicylamide is used as an organocatalyst for the enantioselective conjugate addition of α,α-disubstituted aldehydes to maleimides and nitroalkenes.
Alejandro Torregrosa-Chinillach +3 more
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Nitro Fatty Acids (NO2-FAs): An Emerging Class of Bioactive Fatty Acids
Molecules, 2021 Unsaturated nitro fatty acids (NO2-FAs) constitute a category of molecules that may be formed endogenously by the reaction of unsaturated fatty acids (UFAs) with secondary species of nitrogen monoxide and nitrite anions.
Giorgos S. Koutoulogenis, George Kokotos
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The solution photochemistry of nitroalkenes and nitroketones. [PDF]
, 2023 The thesis describes an investigation or the solution photochemistry of nitroalkenes and α-nitroketones, The introduction discusses the general concepts of photochemistry and provides a detailed review of the photochemistry of nitroalkenes, nitroalkanes ...
Moles, Peter J.
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An Improved and Easy Method for the Preparation of 2,2-Disubstituted 1-Nitroalkenes
, 2016 Reactions of ketones 1, nitromethane 2, and catalytic amount of piperidine 3 in the presence of mercaptan 6 generate β-nitroalkyl sulfides 7−9. At 0 °C and by the use of dichloromethane as solvent, β-nitroalkyl sulfides 7−9 can be oxidized by m ...
Yeh Wang (3026685) +6 more
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