Results 61 to 70 of about 13,292 (250)

Synthesis of Pyrrolidin‐3‐Ones and Spiropyrrolidinones by 1,3‐Dipolar Cycloadditions of Nitrones with Allenylphosphonates

open access: yesEuropean Journal of Organic Chemistry, Volume 28, Issue 27, July 25, 2025.
This work introduces an efficient and gram‐scale microwave‐assisted (3+2) cycloaddition of nitrones with fluorinated allenylphosphonates, yielding diverse 4‐phosphinyl‐pyrrolidin‐3‐ones with exclusive 4,5‐trans diastereoselectivity in moderate to good yields.
Rayhane Hammami   +6 more
wiley   +1 more source

Solvent-Free 1,3-Dipolar Cycloadditions of Nitrones for a More Sustainable Synthesis of Glycomimetics

open access: yesReactions
1,3-Dipolar cycloadditions on nitrone dipoles are key reactions to access five-membered heterocycles, which are useful intermediates in the synthesis of biologically relevant glycomimetics.
Debora Pratesi   +4 more
doaj   +1 more source

Polymergebundene Nitrone

open access: yes, 2002
In den letzten Jahren ist die Nachfrage nach Datenspeichern und ihrer Speicherkapazität immer größer geworden. Dazu sind neue Speichermaterialien notwendig sind, wofür sich in vielen Fällen polymere schaltbare Materialien eignen.Aus diesem Grunde wurden in der vorliegenden Arbeit polymergebundene Nitrone hergestellt, um diese als photoreaktives ...
openaire   +3 more sources

Electrochemistry and Antioxidant Activities of Substituted Furanyl Nitrone: The Role of the Nitro Group

open access: yesChemElectroChem, Volume 12, Issue 13, July 3, 2025.
N‐methyl‐nitroaryl‐furanyl‐nitrone (LQB‐569) suffers a 10‐electron reduction, forming a hydrazine group with two terminal hydroxylamine groups. Nitrones’ antioxidant capacity (AO), despite being very low, correlates with their oxidation profiles, and the ones able to oxidize more easily have better results on DPPH• scavenging and ferric‐reducing ...
Danyelle Cândido Santos   +9 more
wiley   +1 more source

mechanistic investigation of the oxidation of N,a-diphenylnitrones by dichloramine-T in aqueous acetonitrile medium – a non-linear Hammett plot [PDF]

open access: yesJournal of the Serbian Chemical Society, 2009
The kinetics of oxidation of a number of meta- and para-substituted N,a-diphenylnitrones (nitrone) by dichloramine-T (DCT) was investigated in the presence of alkali in aqueous acetonitrile medium.
SUBRAMANIAN MANIVARMAN   +5 more
doaj  

Enoldiazosulfones for Highly Enantioselective [3 + 3]-Cycloaddition with Nitrones Catalyzed by Copper(I) with Chiral BOX Ligands.

open access: yesOrganic Letters, 2018
Enoldiazosulfones undergo [3 + 3]-cycloaddition with nitrones when catalyzed by copper(I) catalysts, but not with dirhodium(II) catalysts. Under mild reaction conditions with chiral bisoxazoline ligands, copper(I) catalysts produce 1,2-oxazine-sulfone ...
Frady G. Adly   +4 more
semanticscholar   +1 more source

Emerging Therapeutic Strategies for Hearing Loss

open access: yesAdvanced Therapeutics, Volume 8, Issue 7, July 2025.
Challenges still exist in treating hearing loss in cases of severe damage to hair cells or spiral ganglion neurons. Here, a schematic diagram of cochlear sensory hair cells and auditory nerves is presented. It is found that in normal Corti organs, hair cells have upright stereocilia at the top and auditory neurons at the base. Ototoxic drugs, noise, or
Shanying Han   +9 more
wiley   +1 more source

Fluorescent Antibiotics: Bridging Diagnostic and Therapy in the Fight against Bacterial Infections

open access: yesSmall Science, Volume 5, Issue 7, July 2025.
This review critically evaluates fluorescent antibiotics as promising agents combining diagnostic precision with therapeutic efficacy. It highlights advances in probe design, chemical conjugation strategies, real‐time imaging applications, selective pathogen detection, and targeted therapy. The potential to combat antimicrobial resistance is discussed,
Tan Phuoc Ton   +3 more
wiley   +1 more source

Valdiazen Derivatives for Chemoproteomic Studies in Burkholderia cenocepacia H111

open access: yesChemBioChem, Volume 26, Issue 11, June 3, 2025.
Valdiazen is a quorum‐sensing signal isolated from B. c. H111. Using diazeniumdiolate chemical probes, several valdiazen‐binding proteins are identified, many of which are involved in structural and metabolic processes. This study offers valuable chemical tools and advances our understanding of the interactome associated with diazeniumdiolate signaling
Jiajun Ren   +8 more
wiley   +1 more source

Synthesis of tetrafluorinated piperidines from nitrones via a visible-light-promoted annelation reaction

open access: yesBeilstein Journal of Organic Chemistry, 2020
A method for the one-step construction of 3,3,4,4-tetrafluorinated piperidines from nitrones and readily accessible tetrafluorinated iodobromobutane is described.
Vyacheslav I. Supranovich   +2 more
doaj   +1 more source

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