Results 61 to 70 of about 1,162 (178)
Nanodiamond Quantum Sensors for Probing Free Radical Biology
Free radicals play key roles in cellular signaling and disease but remain difficult to measure in living systems. Nanodiamonds (NDs) with nitrogen‐vacancy (NV) centers enable quantum sensing of local magnetic noise via T₁ relaxometry, providing nondestructive radical detection in living cells.
Qi Lu, Yingke Wu, Tanja Weil
wiley +1 more source
Polycyclic intermediates enable stereocontrolled synthesis of densely functionalized cis‐1,3‐diamine and amino alcohol carbocycles and heterocycles via structural‐to‐functional complexity transformations from low‐complexity starting material. Cis‐1,3‐functionalized carbocycles and saturated heterocycles are ubiquitous motifs in natural products ...
Jiayi Zhu +2 more
wiley +1 more source
mechanistic investigation of the oxidation of N,a-diphenylnitrones by dichloramine-T in aqueous acetonitrile medium – a non-linear Hammett plot [PDF]
The kinetics of oxidation of a number of meta- and para-substituted N,a-diphenylnitrones (nitrone) by dichloramine-T (DCT) was investigated in the presence of alkali in aqueous acetonitrile medium.
SUBRAMANIAN MANIVARMAN +5 more
doaj
On the Reaction Mechanism of Nitrate Radical and DMPO in Non‐aqueous Photocatalytic Media
This work identifies 2‐oxo‐5,5‐dimethyl‐1‐pyrroline 1‐oxyl (DMPOX), formed via the selective oxidation of 5,5‐dimethyl‐1‐pyrroline N‐oxide (DMPO) by nitrate radicals (NO3•) in nonaqueous media, as a distinctive EPR fingerprint of NO3•. The DFT‐supported mechanism clarifies its formation pathway and highlights DMPOX detection as a robust tool for ...
Alessandro Gottuso +4 more
wiley +1 more source
A method for the one-step construction of 3,3,4,4-tetrafluorinated piperidines from nitrones and readily accessible tetrafluorinated iodobromobutane is described.
Vyacheslav I. Supranovich +2 more
doaj +1 more source
A stereodivergent synthesis of enantiopure 3,6-dihydro-2H-pyrans is presented. The addition of lithiated enol ethers to carbohydrate-derived nitrones afforded syn- or anti-configured hydroxylamine derivatives 4a–d that were cyclized under Lewis acidic ...
Fabian Pfrengle, Hans-Ulrich Reissig
doaj +1 more source
Neuroprotection by Radical Avoidance: Search for Suitable Agents
Neurodegeneration is frequently associated with damage by free radicals. However, increases in reactive oxygen and nitrogen species, which may ultimately lead to neuronal cell death, do not necessarily reflect its primary cause, but can be a consequence ...
Rüdiger Hardeland
doaj +1 more source
New compounds with carbohydrate-similar structure (carbohydrate mimetics) are presented in this article. Starting from enantiopure nitrones and lithiated TMSE-allene we prepared three 1,2-oxazine derivatives which underwent a highly stereoselective Lewis
Léa Bouché +2 more
doaj +1 more source
Synthesis of a New Chiral Pyrrolidine
The synthesis of a new chiral pyrrolidine has been performed using 2,3-O-isopropylidene-D-erythronolactol as a suitable starting material.
Pilar García +7 more
doaj +1 more source
Citation: 'nitronic acids' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.N04165 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire +1 more source

