Results 51 to 60 of about 6,898 (201)

Selective Separation of the Rare Earth Elements Dysprosium and Neodymium via Tailoring Nanocellulose Chemical Structure

open access: yesAdvanced Functional Materials, EarlyView.
Dicarboxylate‐modified anionic hairy cellulose nanocrystals exhibit a high selectivity for dysprosium(III) over neodymium(III). This selectivity arises from disordered dicarboxylate cellulose “hairs” that enable cooperative ionic coordination, hydrogen bonding, and strain‐induced conformational shrinkage.
Roya Koshani   +6 more
wiley   +1 more source

Synthesis of Azoles Condensed with, or Linked to, Nitroxides [PDF]

open access: yes, 2015
Nitroxides connected to indoles, tetrazoles, or 1,3,4-oxadiazoles were synthesized by conventional and microwave-assisted cyclization reactions. New approaches to pyrrole-, pyrazole-, and triazoleannulated nitroxides are described.
Bognár, Balázs   +4 more
core   +1 more source

Re(i)-nitroxide complexes

open access: yesRSC Advances, 2021
Stable nitroxide-substituted cyrhetrenes were synthesized and characterized by EPR, CV, XRD, magnetochemistry and quantum chemistry methods.
Kseniya Maryunina   +11 more
openaire   +3 more sources

Light Activated Induction of Cuproptosis in Resistant Cancer Cells Using Polymeric BODIPY Nanoparticles for Photoactivated Chemotherapy

open access: yesAdvanced Functional Materials, EarlyView.
This article presents a photo‐responsive nanoparticle platform that precisely triggers copper‐dependent cuproptotic cell death in (drug‐resistant) cancer cells. The system remains stable and inactive in the dark but releases cytotoxic species upon red‐light irradiation, achieving potent activity in drug‐resistant breast cancer cells.
Ricarda Zimmermann   +2 more
wiley   +1 more source

Enhancing the Efficacy of Metal‐Free MRI Contrast Agents via Conjugating Nitroxides onto PEGylated Cross‐Linked Poly(Carboxylate Ester)

open access: yesAdvanced Science, 2020
Herein, two water‐soluble PROXYL‐based magnetic resonance imaging (MRI) macromolecular organic contrast agents (mORCAs) are designed and synthesized: linear and cross‐linked PCE‐mPEG‐Ppa‐PROXYL.
Shiwei Guo   +10 more
doaj   +1 more source

Silver-Polystyrene (Ag/PS) Nanocomposites Doped with Polyvinyl Alcohol (PVA)—Fabrication and Bactericidal Activity

open access: yesNanomaterials, 2020
In the present work, we report the studies on perfectly homogeneous nanocomposites composed of polystyrene-grafted silver nanoparticles (Ag@PS) as a bioactive fulfilment and a mixture of polystyrene (PS) and polyvinyl alcohol (PVA) as a matrix.
Anna Krzywicka, Elżbieta Megiel
doaj   +1 more source

New Developments in Spin Labels for Pulsed Dipolar EPR [PDF]

open access: yes, 2014
Spin labelling is a chemical technique that enables the integration of a molecule containing an unpaired electron into another framework for study. Given the need to understand the structure, dynamics, and conformational changes of biomacromolecules ...
Concilio, M   +3 more
core   +2 more sources

Nitroxide‐Mediated Photo‐Polymerization: A Swiss Army Knife for Microfluidic Design

open access: yesAdvanced Materials Technologies, EarlyView.
This article illustrates the application of NMP2 to the rapid (less than 1 h) photostructuring and sealing of model structures intended for microfluidic applications. Remarkably, the careful design of resin composition allows completing these steps by simply spreading bare monomer (i.e., no added photoinitiator) on top of the bottom layer embedding ...
Carlo Gonzato   +5 more
wiley   +1 more source

DFT Study of Nitroxide Radicals. 1. Effects of solvent on structural and electronic characteristics of 4-amino-2,2,5,5-tetramethyl-3-imidazoline-N-oxyl

open access: yes, 2003
Imidazoline-based nitroxide radicals are often used as spin probes for medium acidity and polarity in different systems. In this work, using the density functional theory (DFT) approach, we have studied how physico-chemical characteristics (geometry ...
Ikryannikova, Larissa N.   +2 more
core   +1 more source

Facile syntheses of 3,4-disubstituted pyrroline nitroxides and their further synthetic applications [PDF]

open access: yes, 2016
Lithiation of an alfa,beta-unsaturated pyrroline nitroxide ester with LTMP at the beta-carbon followed by treatment with electrophiles led to a new series of 3,4-disubstituted pyrroline nitroxides, which could be used as valuable paramagnetic building ...
Hideg, Kálmán   +2 more
core   +1 more source

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