Results 71 to 80 of about 2,820 (183)

Enantioselective Growth of Chiral Serine‐Induced β‐Ag2Se Crystals from an Organoselenium Compound

open access: yesAdvanced Functional Materials, Volume 36, Issue 22, 16 March 2026.
Chiral amino acids direct the enantioselective crystallization of β‐Ag2Se nanocrystals from an organoselenium precursor. L‐ and D‐serine induce distinct morphologies and opposite homochiral adsorption preferences, transferring molecular handedness into the inorganic lattice.
Matan Oliel   +5 more
wiley   +1 more source

Xerogel-Sequestered Silanated Organochalcogenide Catalysts for Bromination with Hydrogen Peroxide and Sodium Bromide

open access: yesMolecules, 2015
While H2O2 is a powerful oxidant, decomposing into environmentally benign H2O and O2, a catalyst is often required for reactions with H2O2 to proceed at synthetically useful rates.
Caitlyn M. Gatley   +4 more
doaj   +1 more source

Next‐Generation Antioxidant Strategies: From Nanoformulations to Gene‐Targeted Therapies

open access: yescScience, Volume 2, Issue 1, March 2026.
ABSTRACT Antioxidants play a pivotal role in neutralizing oxidative stress, a key factor in aging and chronic diseases such as cancer, cardiovascular disorders, and neurodegeneration. Although traditional antioxidants such as vitamins C and E, polyphenols, and endogenous enzymes have shown efficacy in laboratory and clinical studies, their therapeutic ...
Lina M. Shaker, Ahmed Al‐Amiery
wiley   +1 more source

Synthesis of Unsymmetric Bis(heteroaryl) Selenides by Rhodium‐Catalyzed Exchange Reaction of Heteroaryl Fluorides and Ethers Using Se‐Heteroaryl Carboselenoates

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 5, 7 February 2026.
Various unsymmetric bis(heteroaryl) selenides are synthesized by the rhodium‐catalyzed exchange reaction of heteroaryl fluorides and ethers with Se‐heteroaryl 1‐adamatanecarboselenoates. The synthetic method is applicable to a broad range of five‐ and six‐membered heteroaryl derivatives and provides compounds containing multiple heteroatoms.
Masana Yazaki   +3 more
wiley   +1 more source

Synthetic Access to Alkali Metal Selenides via Ball Milling

open access: yesZeitschrift für anorganische und allgemeine Chemie, Volume 652, Issue 2, 5 February 2026.
We report the synthesis of alkali metal selenides through reactive ball milling under an argon atmosphere. This mechanochemical pathway is solvent‐free and can be performed at room temperature within minutes to hours. The synthesis of several sodium polyselenides (Na2Sen) and alkali metal selenides (A2Se, A = K, Rb, Cs) is investigated and the received
Anahita I. A. Emminghaus   +3 more
wiley   +1 more source

Organoselenium-Catalyzed Asymmetric Cyclopropanations of (E)‑Chalcones

open access: yes
We report a new class of chiral tetrahydroselenophene based on (S)-diphenyl­(tetrahydroselenophen-2-yl)­methanol, which was prepared from (R)-3-(3-bromopropyl)-2,2-diphenyloxirane and sodium selenide.
Rong-Jie Chein (1796227)   +2 more
core   +1 more source

Novel five- to ten-membered organoselenium heterocycles from the selenation of aromatic diols

open access: yes, 2016
This work is funded by the EPSRC UKReaction of Woollins' reagent ― WR , 2,4-bis(phenyl)-1,3-diselenadiphosphetane 2,4-diselenide [{PhP(Se)(μ-Se)}2] ― with aromatic diols in refluxing toluene afforded a series of novel five- to ten-membered phosphorus ...
Woollins, J Derek   +3 more
core   +1 more source

Selenium-Epoxy ‘Click’ Reaction and Se-Alkylation—Efficient Access to Organo-Selenium and Selenonium Compounds

open access: yesChemistry, 2020
This work establishes the ‘click’ nature of the base-catalyzed oxirane ring opening reaction by the selenolate nucleophile. The ‘click’-generated ß-hydroxy selenide can be alkylated to afford cationic selenium species.
Taejun Eom, Anzar Khan
doaj   +1 more source

Preparation of Se(IV) Aryltrifluoromethylselenide Dichlorides

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 1, January 12, 2026.
An efficient synthesis of dichloro(aryl)(trifluoromethyl)‐λ4‐selanes via chlorination of aryl trifluoromethylselenides with SO2Cl2 is reported. The compounds were fully characterized and their stability studied. Density functional theory studies reveal an asynchronous concerted, exergonic pathway, while formation of the Se(VI) derivative is both ...
Julien Paut   +7 more
wiley   +1 more source

Protecting Groups for Organoselenium Compounds

open access: yes, 2016
Protecting Groups for Organoselenium ...
William A. Reinerth (2665285)   +1 more
core   +1 more source

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