Results 71 to 80 of about 2,820 (183)
Enantioselective Growth of Chiral Serine‐Induced β‐Ag2Se Crystals from an Organoselenium Compound
Chiral amino acids direct the enantioselective crystallization of β‐Ag2Se nanocrystals from an organoselenium precursor. L‐ and D‐serine induce distinct morphologies and opposite homochiral adsorption preferences, transferring molecular handedness into the inorganic lattice.
Matan Oliel +5 more
wiley +1 more source
While H2O2 is a powerful oxidant, decomposing into environmentally benign H2O and O2, a catalyst is often required for reactions with H2O2 to proceed at synthetically useful rates.
Caitlyn M. Gatley +4 more
doaj +1 more source
Next‐Generation Antioxidant Strategies: From Nanoformulations to Gene‐Targeted Therapies
ABSTRACT Antioxidants play a pivotal role in neutralizing oxidative stress, a key factor in aging and chronic diseases such as cancer, cardiovascular disorders, and neurodegeneration. Although traditional antioxidants such as vitamins C and E, polyphenols, and endogenous enzymes have shown efficacy in laboratory and clinical studies, their therapeutic ...
Lina M. Shaker, Ahmed Al‐Amiery
wiley +1 more source
Various unsymmetric bis(heteroaryl) selenides are synthesized by the rhodium‐catalyzed exchange reaction of heteroaryl fluorides and ethers with Se‐heteroaryl 1‐adamatanecarboselenoates. The synthetic method is applicable to a broad range of five‐ and six‐membered heteroaryl derivatives and provides compounds containing multiple heteroatoms.
Masana Yazaki +3 more
wiley +1 more source
Synthetic Access to Alkali Metal Selenides via Ball Milling
We report the synthesis of alkali metal selenides through reactive ball milling under an argon atmosphere. This mechanochemical pathway is solvent‐free and can be performed at room temperature within minutes to hours. The synthesis of several sodium polyselenides (Na2Sen) and alkali metal selenides (A2Se, A = K, Rb, Cs) is investigated and the received
Anahita I. A. Emminghaus +3 more
wiley +1 more source
Organoselenium-Catalyzed Asymmetric Cyclopropanations of (E)‑Chalcones
We report a new class of chiral tetrahydroselenophene based on (S)-diphenyl(tetrahydroselenophen-2-yl)methanol, which was prepared from (R)-3-(3-bromopropyl)-2,2-diphenyloxirane and sodium selenide.
Rong-Jie Chein (1796227) +2 more
core +1 more source
Novel five- to ten-membered organoselenium heterocycles from the selenation of aromatic diols
This work is funded by the EPSRC UKReaction of Woollins' reagent ― WR , 2,4-bis(phenyl)-1,3-diselenadiphosphetane 2,4-diselenide [{PhP(Se)(μ-Se)}2] ― with aromatic diols in refluxing toluene afforded a series of novel five- to ten-membered phosphorus ...
Woollins, J Derek +3 more
core +1 more source
This work establishes the ‘click’ nature of the base-catalyzed oxirane ring opening reaction by the selenolate nucleophile. The ‘click’-generated ß-hydroxy selenide can be alkylated to afford cationic selenium species.
Taejun Eom, Anzar Khan
doaj +1 more source
Preparation of Se(IV) Aryltrifluoromethylselenide Dichlorides
An efficient synthesis of dichloro(aryl)(trifluoromethyl)‐λ4‐selanes via chlorination of aryl trifluoromethylselenides with SO2Cl2 is reported. The compounds were fully characterized and their stability studied. Density functional theory studies reveal an asynchronous concerted, exergonic pathway, while formation of the Se(VI) derivative is both ...
Julien Paut +7 more
wiley +1 more source
Protecting Groups for Organoselenium Compounds
Protecting Groups for Organoselenium ...
William A. Reinerth (2665285) +1 more
core +1 more source

