Synthesis of chiral Nβ-protected amino diselenides from the corresponding amino alkyl iodides using NaBH2Se3 as a selenating reagent and their conversion to seleninic acids [PDF]
A convenient approach has been presented for the synthesis of Nβ-protected amino diselenides from the corresponding amino alkyl iodides using in situ generated NaBH2Se3 as an efficient selenating reagent.
Panduranga, V. +4 more
core +1 more source
Synthetic Access to Alkali Metal Selenides via Ball Milling
We report the synthesis of alkali metal selenides through reactive ball milling under an argon atmosphere. This mechanochemical pathway is solvent‐free and can be performed at room temperature within minutes to hours. The synthesis of several sodium polyselenides (Na2Sen) and alkali metal selenides (A2Se, A = K, Rb, Cs) is investigated and the received
Anahita I. A. Emminghaus +3 more
wiley +1 more source
Structure-activity relationships of hypervalent organochalcogenanes as inhibitors of cysteine cathepsins V and S [PDF]
A new series of organotelluranes were synthesized and investigated, and the structure-activity relationships in cysteine proteases inhibition were determinated.
Alves, Marcio Fernando +5 more
core +1 more source
Synthesis and characterization of novel organic heteroatom compounds from reaction of Woollins’ Reagent with various organic substrates [PDF]
A series of new selenium-containing heteroatom compounds were synthesized in good yields by the reactions of Woollins’ reagent with various organic substrates such as cyclohexanamine, N-benzoylbenzamide, benzoic anhydride, 4-fluoro-N-(2-oxo-2-phenylethyl)
Athukorala Arachchige, Kasun Sankalpa +5 more
core +2 more sources
Discovery of new organoselenium compounds as antileishmanial agents [PDF]
We report new organoselenium compounds bearing the sulfonamide moiety as effective inhibitors of the β-isoform of Carbonic Anhydrase from the unicellular parasitic protozoan L. donovani chagasi. All derivatives were evaluated in vitro for their leishmanicidal activities against Leishmania infantum amastigotes along with their cytotoxicities in human ...
Al-Tamimi A. -M. S. +9 more
openaire +4 more sources
Preparation of Se(IV) Aryltrifluoromethylselenide Dichlorides
An efficient synthesis of dichloro(aryl)(trifluoromethyl)‐λ4‐selanes via chlorination of aryl trifluoromethylselenides with SO2Cl2 is reported. The compounds were fully characterized and their stability studied. Density functional theory studies reveal an asynchronous concerted, exergonic pathway, while formation of the Se(VI) derivative is both ...
Julien Paut +7 more
wiley +1 more source
Product ion distributions for the reactions of NO+ with some N-containing and O-containing heterocyclic compounds obtained using SRI-TOF-MS [PDF]
Product ion distributions for the reactions of NO+ with nine O-containing and six N-containing heterocyclic compounds present in human volatilome have been determined under the conditions of a Selective Reagent Ionization Time of Flight Mass Spectrometer
Amann, A +4 more
core +2 more sources
Tellurium‐containing heterocycles represent an emerging class of organochalcogen compounds with notable redox properties and antimicrobial potential. Incorporation of tellurium into sulfur‐ and nitrogen‐containing frameworks can enhance biological activity through increased polarizability and favorable noncovalent interactions.
Olha Haleha +5 more
wiley +1 more source
This work establishes the ‘click’ nature of the base-catalyzed oxirane ring opening reaction by the selenolate nucleophile. The ‘click’-generated ß-hydroxy selenide can be alkylated to afford cationic selenium species.
Taejun Eom, Anzar Khan
doaj +1 more source
Copper catalyzed cross-coupling reactions of diaryl ditellurides with potassium aryltrifluoroborate salts [PDF]
We present here results of the cross-coupling reaction of diaryl ditellurides with potassium aryltrifluoroborate salts using a catalytic amount of Cu(OAc)2 and bypiridine in DMSO/H2O under air atmosphere.
ALVES, Diego +5 more
core +2 more sources

