Results 121 to 130 of about 10,063 (262)
Preparation of Some Pentose Oximes
Oximes of arabinose, ribose and xylose have been prepared from each pentose and hydroxylamine in anhydrous ethanol. Free hydroxylamine prepared from its hydrochloride by neutralization with sodium ethoxide was added dropwise into a pentose solution ...
飯尾, 雅嘉 +4 more
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Advancements in Mass Spectrometry‐Based Glycomics in Food and Nutritional Science
ABSTRACT This review highlights advancements in mass spectrometry (MS)‐based glycomics in food and nutritional science. Carbohydrates, which are vital for human health, exhibit complex structures, making their analysis challenging. MS has become an indispensable tool for elucidating the structures of carbohydrates, including glycans, through soft ...
JaeHui Song +3 more
wiley +1 more source
The halide-bridge cleavage reaction of the [Pd(C2 ,N-bzox)(µ-Cl)]2 compound (bzox = benzaldehydeoxime) with ethylenethiourea (L) in the 1:2 molar ratio at room temperature yielded the cyclopalladated compound [Pd(C2 ,N-bzox)(Cl)(L)] (1) whose replacement
Nathália A. Thomazella +6 more
doaj +1 more source
The use of transition‐metal catalysts and design of chiral ligands have allowed chemists to access highly functionalized benzofused 5‐ and 6‐ membered rings in high yield and enantioselectivity. A common strategy used relies on an intermolecular carbometalation across alkynes and olefins, usually followed by a subsequent intramolecular carbometalation.
Clara Jans +3 more
wiley +2 more sources
Aziridinierung eines einzelnen Kohlenstoffatoms in Alkenen mittels Energietransferkatalyse
Im Gegensatz zur traditionellen Alken‐Aziridinierung über (formalen) Nitren‐Transfer berichten wir hier über eine Strategie zur intermolekularen Aziridinierung eines einzelnen Alken‐Kohlenstoffatoms bei zusätzlicher Funktionalisierung der anderen Position. Durch Energietransfer‐ (EnT‐)Katalyse werden Alkenylboronate und ‐silane in reaktive Intermediate
Fritz Paulus +7 more
wiley +1 more source
Gold-catalyzed rearrangement of O-vinyl oximes for the synthesis of highly substituted pyrroles.
O-Vinyl oximes were synthesized from the reaction of oximes with activated alkynes and subsequently rearranged using gold catalysis to afford highly substituted pyrroles in an efficient and regiocontrolled process.
Jason E. Camp +3 more
core +1 more source
Aziridination of a Single Carbon Atom in Alkenes via Energy Transfer Catalysis
Contrary to traditional alkene aziridination via (formal) nitrene transfer, we herein report a strategy that achieves intermolecular aziridination of a single alkene carbon atom and installs an additional group at the other. Enabled by metal‐free energy transfer (EnT) catalysis, alkenyl boronates and silanes are transformed into reactive intermediates ...
Fritz Paulus +7 more
wiley +1 more source
Organophosphorus (OP) compounds are irreversible inhibitors of acetylcholinesterase (AChE) commonly used as pesticides and, unfortunately, as nerve agents in terrorist attacks.
Rezende, Claudia M. +11 more
core +1 more source
1,1‐and 1,2‐Diborylalkenes: Preparation and Synthetic Applications
In this review, we highlight recent advances in the synthesis and reactivity of 1,1‐diborylalkenes and 1,2‐diborylalkenes, along with various transformations leading to C‐C, C‐heteroatom, and multicomponent products. By providing a comprehensive and practical resource, this review aims to assist researchers in exploring the synthetic utility of 1,1 and
Jayaram Vankudoth +2 more
wiley +1 more source
On the inhibitory properties of oximes I. action of oximes on the chemiluminescence of luminol
Utvrđeno je da razni oksimi djelomično veoma izrazito inhibiraju luminolsku reakciju (gase kemiluminescenciju luminola), koja je katalizirana utjecajem organofosfornih spojeva, odnosno kompleksnih spojeva željeza.
Jelka Matković +7 more
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