Phosphine-Catalyzed Annulations of Azomethine Imines: Allene-Dependent [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] Pathways [PDF]
In this paper we describe the phosphine-catalyzed [3 + 2], [3 + 3], [4 + 3], and [3 + 2 + 3] annulations of azomethine imines and allenoates. These processes mark the first use of azomethine imines in nucleophilic phosphine catalysis, producing ...
Benitez, Diego+12 more
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Coordinatively unsaturated ruthenium complexes as efficient alkyne-azide cycloaddition catalysts [PDF]
The performance of 16-electron ruthenium complexes with the general formula Cp*Ru(L)X (in which L = phosphine or N-heterocyclic carbene ligand; X = Cl or OCH2CF3) was explored in azide−alkyne cycloaddition reactions that afford the 1,2,3- triazole ...
Broggi, Julie+6 more
core +2 more sources
The study presents an injectable hydrogel with tunable microporosity to improve mesenchymal stem cell delivery for volumetric muscle loss treatment. Mesenchymal stem cells encapsulated in porous hydrogels significantly promote the spreading, proliferation, and cytokine secretion of mesenchymal stem cells.
Hana Yasue+3 more
wiley +1 more source
Crystal Structure of Bis(2,4,6-trimethylphenyl)-phosphine Oxide
The single crystal structure of bis(2,4,6-trimethylphenyl)phosphine oxide has been determined. All interatomic distances and angles can be considered normal.
Alex J. Veinot+3 more
doaj +1 more source
3D Printing of Functional Mesoporous Silica Monoliths with Embedded Metal and MOF Components
This article presents the development of silica nanocage‐based nano‐inks tailored for digital light processing 3D printing, enabling automated additive manufacturing of mesoporous monoliths. Novel strategies for incorporating metal sites and inducing in situ growth of metal‐organic frameworks are introduced.
Thomas Gaillard+7 more
wiley +1 more source
We previously revealed that phosphine–boranes can function as molecular frameworks for biofunctional molecules. In the present study, we exploited the diversity of available phosphines to design and synthesize a series of B-(trifluoromethyl)phenyl ...
Yu Miyajima, Kotaro Ochiai, Shinya Fujii
doaj +1 more source
Screening of phosphine resistance in Sitophilus oryzae (L.) (rice weevil) populations in Turkey
In this study, the status and prevalence of phosphine resistance in Sitophilus oryzae (L.) (Coleoptera: Curculionidae) populations collected from Mersin and Konya Province in Turkey were investigated by conducting the discrimination concentration tests ...
Tingiş, Ahmet+4 more
doaj +1 more source
Ferrocenyl hydroxymethylphosphines (η⁵-C₅H₅)Fe[η⁵⁻C₅H₄P(CH₂OH)₂] and 1,1′-[Fe{η⁵-C₅H₄P(CH₂OH)₂}₂] and their chalcogenide derivatives [PDF]
The ferrocenyl hydroxymethylphosphines FcP(CH₂OH)₂ [Fc=(η⁵-C₅H₅)Fe(η⁵-C₅H₄)] and 1,1′-Fc′[P(CH₂OH)₂]₂ [Fc′=Fe(η⁵⁻C₅H₄)₂] were prepared by reactions of the corresponding primary phosphines FcPH₂ and 1,1′-Fc′(PH₂)₂ with excess aqueous formaldehyde.
Alley, Steven R., Henderson, William
core +2 more sources
Exciton Dynamics in Layered Halide Perovskite Light‐Emitting Diodes
This review discusses the exciton dynamics in layered halide perovskitelight‐emitting diodes (PeLEDs). It opens with a summary of the structural and photophysical aspects, followed by an exploration of controlling dimensionality and cascade exciton transfer in quasi‐2D PeLEDs.
Sung‐Doo Baek+5 more
wiley +1 more source
Phosphine Functionalization of GaAs(111)A Surfaces [PDF]
Phosphorus-functionalized GaAs surfaces have been prepared by exposure of Cl-terminated GaAs(111)A surfaces to triethylphosphine (PEt3) or trichlorophosphine (PCl3), or by the direct functionalization of the native-oxide terminated GaAs(111)A surface ...
Biteen, Julie S.+5 more
core +1 more source