Results 151 to 160 of about 51,028 (331)
Advanced Science, EarlyView.We have developed a Pd‐catalyzed oxidative cyclopropanation of 1,n‐enynes employing cyclic diacyl peroxides as bifunctional reagents that serve as both tether‐tunable oxidants and spatially controlled dicarboxylate anions. ABSTRACT Bicyclo[n.1.0]alkanes are highly valuable scaffolds in drug discovery and synthetic chemistry.
Ting Yuan, Lei Shi
wiley +1 more source
Atroposelective Suzuki–Miyaura Coupling to Form 2‐Amino‐2′‐Hydroxybiphenyls Enabled by sRuPhos
Angewandte Chemie, EarlyView.We report a new chiral phosphine ligand, sRuPhos, which permits the highly enantioselective Suzuki–Miyaura coupling of ortho‐aniline and ortho‐phenol building blocks. This results in 2‐amino‐2′‐hydroxybiphenyls with very high enantiomeric excesses, products that will have application in pharmaceutical synthesis and ligand design for catalysis ...
Hamzah Sharif +3 more
wiley +2 more sources
Synthesis and evaluation of a novel natural-based phosphine antioxidant for the thermal stabilization of polyethylene [PDF]
, 2022 Kata Takács +4 more
openalex +1 more source
Stretchable Energy Storage with Eutectic Gallium Indium Alloy
Advanced Energy Materials, Volume 15, Issue 11, March 18, 2025.A highly stretchable liquid metal‐based electrode is developed via a one‐step process, retaining conductivity and capacitance after mechanical deformation up to 900% strain. The stretchable all‐solid‐state device provides a areal energy density of 43 µWh cm⁻2 after 150% strain.
Adit Gupta +6 more
wiley +1 more source
Synthesis and Characterization of Unusual S=1 Fe(0)‐Silyl Complexes Supported by Styrene Ligands
Angewandte Chemie, EarlyView.Despite the long‐standing importance of iron‐silicon bonds as related to catalysis, high‐spin Fe(0)‐silyl complexes remain a historical synthetic challenge in the field. Herein, we report the first series of high‐spin S = 1, styrene‐stabilized Fe(0)‐silyl complexes followed by extensive characterization via Mössbauer spectroscopy, single crystal X‐ray ...
Alexis K. Bauer +2 more
wiley +2 more sources
Three Dimensional Printing of Bioinspired Composite Aerogels for Solar Steam Generation
Advanced Energy and Sustainability Research, EarlyView.Freshwater scarcity demands efficient purification strategies. Inspired by desert grasses, reduced graphene oxide‐doped polyacrylamide aerogels with longitudinal grooves are fabricated via high‐speed three‐dimensional printing and freeze‐drying. The biomimetic design enables dual‐mode water transport, achieving a capillary flow of 2.16 cm in 10 minutes
Luyang Liu +7 more
wiley +1 more source
(Poly)Borylated Species as Modern Reactive Groups toward Unusual Synthetic Applications
Angewandte Chemie, EarlyView.In this review, we spotlight recent breakthroughs in α‐polyboron‐substituted carbon‐centered intermediates (carbanion, carbocation, radical, and carbene) and polyborylated alkenes. By bridging fundamental reactivity with the application potential of these extraordinary species, we hope this review will serve as a roadmap for harnessing these unique ...
Nadim Eghbarieh +5 more
wiley +2 more sources
Advanced Intelligent Discovery, EarlyView.Two‐photon polymerization enables high‐resolution microfabrication, but performing alignment when printing multiple structures is difficult. Here, we present a fast, robust, and open‐source protocol for automated alignment on Nanoscribe systems. Achieving ≈0.4 μm accuracy in under 5 s, our protocol reduces time and error in multimaterial printing. This
Daniel Maher +4 more
wiley +1 more source
Carbonyl(h5-Cyclopentadienyl)(tetrafluoroborato)molybdenum and tungsten complexes [PDF]
, 1989 Beck, Wolfgang +3 more
core +2 more sources
Mechanically Triggered Chemical Recyclable Polyethylene‐Like Materials
Angewandte Chemie, EarlyView.Polyethylene‐like copolymers with benchmark properties are prepared by embedding latent cyclobutene mechanophores to overcome PE's end‐of‐life limits. The mechanophores are inert in service but are selectively opened by solvent‐free ball milling to yield well‐defined telechelic oligomers.
Menghe Xu +3 more
wiley +2 more sources