Results 31 to 40 of about 4,197 (216)

Synthesis of γ‑Pyrones from Formal [4 + 2] Cyclization of Ketene Dithioacetals with Acyl Chlorides [PDF]

open access: yes, 2019
A formal [4 + 2] cyclization of easily available ketene dithioacetals with acyl chlorides has been developed. Mediated by lithium bis­(trimethylsilyl)­amide, a series of γ-pyrones were obtained with a broad substrate scope. This unprecedented formal [4 +
Yifei Li (198040)   +4 more
core   +3 more sources

CRISPR-Cas9 Gene Editing and Secondary Metabolite Screening Confirm Fusarium graminearum C16 Biosynthetic Gene Cluster Products as Decalin-Containing Diterpenoid Pyrones

open access: yesJournal of Fungi, 2023
Fusarium graminearum is a causal organism of Fusarium head blight in cereals and maize. Although a few secondary metabolites produced by F. graminearum are considered disease virulence factors, many molecular products of biosynthetic gene clusters ...
Carmen Hicks   +9 more
doaj   +1 more source

Facile Synthesis, Fluorescence, and Photochromism of Novel Helical Pyrones and Chromenes [PDF]

open access: yes, 2016
Aryl coumaryl ethylenes undergo oxidative photocyclization readily to yield helical pyrone-annulated condensed aromatics. The pyrones are conveniently converted to the corresponding photochromic diphenylpyrans/chromenes.
Sanchita Sengupta (1776892)   +3 more
core   +3 more sources

Pd/C-Catalyzed Intramolecular C–H Arylation for the Synthesis of Phenanthridinones and Dibenzo-α-pyrones

open access: yesSynOpen, 2017
Pd/C was found to be an efficient and convenient metal catalyst for intramolecular C–H arylation reactions in the synthesis of phenanthridinones and dibenzo-α-pyrones. A variety of phenanthridinones and dibenzo-α-pyrones were synthesized under the highly
Lingyu Zhao   +4 more
doaj   +1 more source

Étude théorique des pyrones 2 et 4 [PDF]

open access: yes, 2017
Les molécules de pyrones 2 et 4 sont étudiées par deux types de méthode LCAOMO, l'une tenant compte uniquement des électrons π et l'autre des électrons π et σ. Avec la méthode LCAO améliorée de JULG, le calcul conduit à des résultats en bon accord avec l'
Jean-Claude Bery   +2 more
core   +1 more source

Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin

open access: yesAngewandte Chemie, Volume 138, Issue 23, 1 June 2026.
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu   +3 more
wiley   +2 more sources

New Naphtho-γ-Pyrones Isolated from Marine-Derived Fungus Penicillium sp. HK1-22 and Their Antimicrobial Activities

open access: yesMarine Drugs, 2019
Three novel monomeric naphtho-γ-pyrones, peninaphones A−C (compounds 1−3), along with two known bis-naphtho-γ-pyrones (compounds 4 and 5) were isolated from mangrove rhizosphere soil-derived fungus Penicillium sp. HK1-22.
Yao-Yao Zheng   +7 more
doaj   +1 more source

One-pot synthesis of salicylaldehyde containing biaryl frameworks via an aminocatalytic Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones

open access: yesGreen Synthesis and Catalysis, 2020
Salicylaldehyde containing biaryls are efficiently synthesized via an unprecedented amine promoted Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones in good yields.
Xixi Song   +5 more
doaj   +1 more source

Emission solvatochromic, solid-state and aggregation-induced emissive α-pyrones and emission-tuneable 1H-pyridines by Michael addition–cyclocondensation sequences

open access: yesBeilstein Journal of Organic Chemistry, 2019
Starting from substituted alkynones, α-pyrones and/or 1H-pyridines were generated in a Michael addition–cyclocondensation with ethyl cyanoacetate. The peculiar product formation depends on the reaction conditions as well as on the electronic substitution
Natascha Breuer   +3 more
doaj   +1 more source

Nocapyrones: α- and γ-Pyrones from a Marine-Derived Nocardiopsis sp.

open access: yesMarine Drugs, 2014
One new α-pyrone (nocapyrone R (1)), and three known γ-pyrones (nocapyrones B, H and L (2–4)) were isolated from the culture extract of a Nocardiopsis strain collected from marine sediment.
Youngju Kim   +7 more
doaj   +1 more source

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