Results 71 to 80 of about 85,504 (285)

Synthetic utility and reactivity of N-alkynylazoles [PDF]

open access: yes, 2015
textThe chemistry of N-alkynylazoles is a newly emerging area of chemistry with particular interest in heterocycle synthesis. Synthetic preparations of this class of molecule have shown an increasing presence in literature, however, the synthetic ...
Gilbreath, Bradford Lynd
core  

Synthesis of formyl-thienylpyrroles : versatile building blocks for NLO materials [PDF]

open access: yes, 2006
Several formyl-substituted 1-alkyl(aryl)-2-(2´-thienyl)pyrroles 3-7 were synthesized by functionalization of the pyrrole or thiophene ring of thienylpyrroles 2 using different methods: Vilsmeier formylation or metalation followed by reaction with DMF ...
Fonseca, A. Maurício C.   +3 more
core   +1 more source

Azirinyl-Substituted Nitrile Oxides: Generation and Use in the Synthesis of Isoxazole Containing Heterocyclic Hybrids

open access: yesMolecules
The procedure for the generation of azirinyl-substituted nitrile oxides by the reaction of 2-(diazoacetyl)-2H-azirines with tert-butyl nitrite while preserving the azirine ring has been developed.
Alexander S. Dudik   +4 more
doaj   +1 more source

Spatial separation of pyrrole and pyrrole-water clusters [PDF]

open access: yesChemical Physics Letters, 2019
We demonstrate the spatial separation of pyrrole and pyrrole(H$_2$O) clusters from the other atomic and molecular species in a supersonically-expanded beam of pyrrole and traces of water seeded in high-pressure helium gas. The experimental results are quantitatively supported by simulations.
Johny, Melby   +5 more
openaire   +4 more sources

Metal-free C-H sulfonamidation of pyrroles by visible light photoredox catalysis.

open access: yesChemical Communications, 2016
We report a one-step procedure for the preparation of N-(2-pyrrole)-sulfonamides from sulfonamides and pyrroles. The reaction uses visible light, an acridinium dye as photocatalyst and oxygen as the terminal oxidant for the oxidative C-N bond formation ...
Andreas Uwe Meyer, A. Berger, B. König
semanticscholar   +1 more source

Deproto-metallation of N-arylated pyrroles and indoles using a mixed lithium–zinc base and regioselectivity-computed CH acidity relationship

open access: yesBeilstein Journal of Organic Chemistry, 2015
The synthesis of N-arylated pyrroles and indoles is documented, as well as their functionalization by deprotonative metallation using the base in situ prepared from LiTMP and ZnCl2·TMEDA (1/3 equiv).
Mohamed Yacine Ameur Messaoud   +12 more
doaj   +1 more source

Carbohydrate-auxiliary assisted preparation of enantiopure 1,2-oxazine derivatives and aminopolyols

open access: yesBeilstein Journal of Organic Chemistry, 2012
An approach to enantiopure hydroxylated 2H-1,2-oxazine derivatives is presented utilizing the [3 + 3] cyclisation of lithiated alkoxyallenes and an L-erythrose-derived N-glycosyl nitrone as precursors.
Marcin Jasiński   +2 more
doaj   +1 more source

Three-component reactions of aromatic amines, 1,3-dicarbonyl compounds, and α-bromoacetaldehyde acetal to access N-(hetero)aryl-4,5-unsubstituted pyrroles

open access: yesBeilstein Journal of Organic Chemistry, 2020
N-(Hetero)aryl-4,5-unsubstituted pyrroles were synthesized from (hetero)arylamines, 1,3-dicarbonyl compounds, and α-bromoacetaldehyde acetal by using aluminum(III) chloride as a Lewis acid catalyst through [1 + 2 + 2] annulation.
Wenbo Huang   +5 more
doaj   +1 more source

Synthesis and characterization of novel second-order NLO-chromophores bearing pyrrole as an electron donor group [PDF]

open access: yes, 2012
Two series of novel push-pull 1-(4-(thiophen-2-yl)phenyl)-1H-pyrroles 3-5 were designed to explore the consequence of using different electron accepting moieties linked to the thiophene at the arylthiophene bridge or to the pyrrole heterocycle which ...
Belsley, M.   +3 more
core   +1 more source

An efficient and facile access to highly functionalized pyrrole derivatives

open access: yesBeilstein Journal of Organic Chemistry, 2018
A straightforward and one-pot synthesis of pyrrolo[3,4-c]pyrrole-1,3-diones via Ag(I)-catalyzed 1,3-dipolar cycloaddition of azomethine ylides with N-alkyl maleimide, followed by readily complete oxidation with DDQ, has been successfully developed ...
Meng Gao   +5 more
doaj   +1 more source

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