Alcohol‐Directed Carboamination of Conjugated Enynes
The first general three‐component intermolecular Pd‐catalyzed carboamination of conjugated enynes enables the coupling of anilines and aryl triflates to produce functionalized allenic amines, utilizing a native alcohol directing group to control regioselectivity.
Helena Solé‐Àvila +3 more
wiley +1 more source
Mechanochemical ligand-controlled regiodivergent hydroarylation of alkenes via iron-catalyzed C-H activation. [PDF]
Zhang ZJ, Liu Z, Chen X, Ackermann L.
europepmc +1 more source
A light mediated direct regioselective B─H functionalization, via hydrogen atom transfer (HAT), is described. Unexplored xanthyl‐closo‐carboranes as novel bench‐stable and versatile platforms to access sulfur‐containing boron clusters are reported for the first time.
Marco Rusconi +9 more
wiley +1 more source
Enantioselective synthesis of configurationally stable [5]helicenes containing 1,2-azaborine units. [PDF]
Olguin C +10 more
europepmc +1 more source
Regioselectivity Study of Contrasteric Aromatic Claisen Rearrangements and Their Utilization in the Total Syntheses of 5-Hydroxymellein and Botyroisocoumarin A. [PDF]
Tanas DK +14 more
europepmc +1 more source
Modular and diverse synthesis of oxaheterocycles <i>via</i> Pd-catalyzed migratory 1,<i>n</i>-cycloannulation of alkenes. [PDF]
Wang JP, Wu Y, Wang P.
europepmc +1 more source
Regioselective synthesis of 3-halo-2<i>H</i>-chromenes via decarboxylative halogenation of oxygenated 3-carboxy-2<i>H</i>-chromenes: Application to isoflavonoid synthesis. [PDF]
Kang B +3 more
europepmc +1 more source
Rhodium-Catalyzed Arene Alkenylation Using Benzoquinone Derivatives as Oxidants. [PDF]
Bennett MT +4 more
europepmc +1 more source
Tuning aromatic cage occupancy in prenyltransferases enables selective and efficient production of rare c-prenylated flavonoids. [PDF]
Qiu R +15 more
europepmc +1 more source
HFIP-Induced Formation of <i>O</i>-Aryl Oxyallyl Cation and Nucleophilic Addition with Sodium Sulfinate Salt. [PDF]
Aldás-Bedón J +6 more
europepmc +1 more source

