Results 81 to 90 of about 45,362 (276)

Selective and reversible 1,3-dipolar cycloaddition of 6-aryl-1,5-diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones under microwave irradiation

open access: yesBeilstein Journal of Organic Chemistry, 2020
The first example of the cycloaddition of in situ-generated azomethine imine under microwave conditions is described. The reaction of 6-aryl-1,5-diazabicyclo[3.1.0]hexanes with 1,3-diphenylprop-2-en-1-ones proceeds regio- and stereoselectively giving ...
Alexander P. Molchanov   +3 more
doaj   +1 more source

Aerobic addition of secondary phosphine oxides to vinyl sulfides: a shortcut to 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides

open access: yesBeilstein Journal of Organic Chemistry, 2015
Secondary phosphine oxides react with vinyl sulfides (both alkyl- and aryl-substituted sulfides) under aerobic and solvent-free conditions (80 °C, air, 7–30 h) to afford 1-hydroxy-2-(organosulfanyl)ethyl(diorganyl)phosphine oxides in 70–93% yields.
Svetlana F. Malysheva   +6 more
doaj   +1 more source

Study on the Alkylation Reactions of N(7)-Unsubstituted 1,3-Diazaoxindoles

open access: yesMolecules, 2017
The chemistry of the 5,7-dihydro-6H-pyrrolo[2,3-d]pyrimidin-6-one (1,3-diazaoxindole) compound family, possessing a drug-like scaffold, is unexplored. In this study, the alkylation reactions of N(7)-unsubstituted 5-isopropyl-1,3-diazaoxindoles bearing ...
Eszter Kókai   +5 more
doaj   +1 more source

Chemoselective or Regioselective?

open access: yesChemistryEurope
Over the past two decades, there has been a notable increase in the number of reactions that have been classified as chemoselective and/or regioselective. It is somewhat surprising that neither of these terms is clearly defined, as this often leads to conflicting and confusing designations and makes it challenging to report the results coherently. This
Andrej Kolarovič, Pavol Jakubec
openaire   +2 more sources

Regioselective One‐Step Cyclization and Aromatization towards Directly Amino‐Functionalized Covalent Organic Framework with Stable Benzodiimidazole Linkage [PDF]

open access: bronze, 2023
Xiaofeng Li   +9 more
openalex   +1 more source

An Exploratory Study of the Enzymatic Hydroxycinnamoylation of Sucrose and Its Derivatives

open access: yesMolecules
Phenylpropanoid sucrose esters are a large and important group of natural substances with significant therapeutic potential. This work describes a pilot study of the enzymatic hydroxycinnamoylation of sucrose and its derivatives which was carried out ...
Matej Cvečko   +2 more
doaj   +1 more source

Green Polymer Chemistry: Enzyme Catalysis for Polymer Functionalization

open access: yesMolecules, 2015
Enzyme catalyzed reactions are green alternative approaches to functionalize polymers compared to conventional methods. This technique is especially advantageous due to the high selectivity, high efficiency, milder reaction conditions, and recyclability ...
Sanghamitra Sen, Judit E. Puskas
doaj   +1 more source

Regioselective Arylboration of 1,3‐Butadiene

open access: yesIsrael Journal of Chemistry, 2019
AbstractA method for the regioselective 1,2‐arylboration of 1,3‐butadiene, a feedstock chemical, is reported. The reactions result in the formation of products that can be easily elaborated to other structures. The mechanistic details of this process are also discussed.
Allison M. Bergmann   +3 more
openaire   +3 more sources

Regioselective Substitution of BINOL

open access: yesChemical Reviews
1,1'-Bi-2-naphthol (BINOL) has been extensively used as the chirality source in the fields of molecular recognition, asymmetric synthesis, and materials science. The direct electrophilic substitution at the aromatic rings of the optically active BINOL has been developed as one of the most convenient strategies to structurally modify BINOL for diverse ...
openaire   +2 more sources

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