Results 101 to 110 of about 29,422 (294)

On the functionalization of benzo[e][2,1]thiazine

open access: yesBeilstein Journal of Organic Chemistry, 2009
The reactions of benzo[e][2,1]thiazine-4-chloro-3-carbaldehydes 1 and benzo[e][2,1]thiazine-4-chloro-3-carbonitriles 2 with a number of oxidizing and reducing agents are reported.
Kirill Popov   +2 more
doaj   +1 more source

Regioselectivity in the Nitration of Dialkoxybenzenes

open access: yes, 2016
Dinitrodialkoxybenzene derivatives are important precursors for Schiff base macrocycles and a variety of other molecules. During our investigations, we have found that the dinitration reaction of 1,2-dialkoxybenzenes proceeds with unusual ...
Kevin Shopsowitz (2226526)   +2 more
core   +1 more source

A Molecular Electron Density Theory Study of the Chemoselectivity, Regioselectivity, and Diastereofacial Selectivity in the Synthesis of an Anticancer Spiroisoxazoline derived from α-Santonin

open access: yesMolecules, 2019
The [3 + 2] cycloaddition (32CA) reaction of an α-santonin derivative, which has an exocyclic C⁻C double bond, with p-bromophenyl nitrile oxide yielding only one spiroisoxazoline, has been studied within the molecular electron density theory ...
Luis R. Domingo   +2 more
doaj   +1 more source

Engineering the substrate specificity and regioselectivity of Burkholderia thailandensis lipoxygenase [PDF]

open access: yes
Lipoxygenases (LOXs) catalyze the regioselective dioxygenation of polyunsaturated fatty acids (PUFAs), generating fatty acid hydroperoxides (FAHPs) with diverse industrial applications.
Vincken, Jean-Paul   +4 more
core   +1 more source

Regioselective Palmitoylation of 9-(2,3-Dihydroxy- propyl)adenine Catalyzed by a Glycopolymer-enzyme Conjugate

open access: yesMolecules, 2016
The enzymatic regioselective monopalmitoylation of racemic 9-(2,3-dihydroxypropyl)- adenine (DHPA), an approved antiviral agent, has been performed by an immobilized form of Candida antarctica B lipase (CAL-B) using a 4:1 DMF/hexane mixture as the ...
Jana Brabcová   +5 more
doaj   +1 more source

Regioselectivity in Hetero Diels–Alder Reactions

open access: yes, 2019
Regioselectivity in hetero Diels-Alder reactions can be observed in a simple reaction between a nonsymmetrical heterodiene and an unsymmetrical heterodienophile.
Liber, Marta   +9 more
core   +1 more source

1,1,4,4-Tetracyanobutadiene-Functionalized Anthracenes: Regioselectivity of Cycloadditions in the Synthesis of Small Near-IR Dyes

open access: yes, 2020
Two small 1,1,4,4-tetracyanobutadiene-functionalized chromophores were obtained by careful leverage of the regioselectivity of the cycloaddition reaction of tetracyanoethylene with anthracene-ynamide derivatives, inducing either a [2+2] or a [4+2] Diels ...
Trevor, Hamlin   +9 more
core   +1 more source

Pattern-recognition-based Prediction of Metabolic Regioselectivity Mediated by Human Cytochromes P450 3A4

open access: yes, 2010
P450 3A4, the most important human CYP enzyme, is responsible for the metabolism of more than 50%-60% of clinically used drugs. Early knowing the site of metabolism will help the medicinal chemist to decide how best to block the metabolism of candidates ...
艾纯芝, 杨凌, 毛玉玺
core  

Spin effect on redox acceleration and regioselectivity in Fe-catalyzed alkyne hydrosilylation

open access: yes, 2023
Iron catalysts are ideal transition metal catalysts because of the Earth abundant, cheap, biocompatible features of the iron salts. Iron catalysts often have unique open-shell structures that easily undergo spin crossover in chemical transformations, a ...
Tian-Zhang, Qiao   +5 more
core   +1 more source

Regioselectivity-Switchable Hydroarylation of Styrenes

open access: yes, 2016
Cobalt−phosphine and cobalt−carbene catalysts have been developed for the hydroarylation of styrenes via chelation-assisted C−H bond activation, to afford branched and linear addition products, respectively, in a highly regioselective fashion.
Ke Gao (1521607)   +1 more
core   +1 more source

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