Asymmetric Hydrogenation with Chiral Aminophosphine–Rhodium Complexes and Chiral Recognition by Bisphosphine–Rhodium Complexes in the Asymmetric Hydrogenation of Olefins through the Chiral Helical Conformation of Phenyl Groups on the Phosphorus Atom [PDF]
Ken-ichi Onuma +2 more
openalex +1 more source
Pullulan, a biomass‐derived polysaccharide, is transformed into transparent optical fibers using a solvent‐free borax hydrogel‐spinning method. The fibers outperform PMMA with ≈200 MPa tensile strength and 200 °C stability, while uniquely guiding visible‐to‐NIR light and enabling additive‐free humidity sensing.
Yuya Fukata +4 more
wiley +1 more source
Diphosphine-Substituted Rhodium Carbonyl Clusters: Synthesis and Structural and Spectroscopic Characterization of the Heteroleptic Rh<sub>4</sub>(CO)<sub>8+2n</sub>(L)<sub>2-n</sub> (n = 0, 1) and {Rh<sub>4</sub>(CO)<sub>10</sub>L}<sub>2</sub> Monomeric and Dimeric Species. [PDF]
Scorzoni G +5 more
europepmc +1 more source
Electron beam induced deposition of rhodium nanostructures
F. Cicoira
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Hydrocarbon membranes are a greener alternative to PFSA in PEM fuel cells, but degrade rapidly from radical attack. We present a novel strategy using poly(vinylphosphonic acid) (PVPA) as a local radical scavenger. Incorporated as an interfacial barrier, PVPA enhances chemical stability and significantly extends membrane lifetime under accelerated ...
Hendrik Sannemüller +6 more
wiley +1 more source
Skeletal Rearrangement of Biaryls via Rhodium-Azirine Intermediate: A Route to Solid-State Emissive Polycyclic Sulfamates. [PDF]
Insa-Carreras N +6 more
europepmc +1 more source
Strong exciton‐photon coupling is achieved by integrating porphyrin ligand‐based MOF nanoparticles in optical cavities, as evidenced by pronounced polariton branch anticrossing. The porous nature of the resonator enables precise, reversible tuning via vapor pressure, unlocking unprecedented chemical‐environment controlled dynamic polaritonic platforms ...
Beatriz de Sola‐Báez +7 more
wiley +1 more source
Catalytic enantioselective synthesis of selenium-containing atropisomers via C-Se bond formations. [PDF]
Gao QS, Wei ZW, Chen ZM.
europepmc +1 more source
Reactivity of Novel N,N′-Diphosphino-Silanediamine-Based Rhodium(I) Derivatives
Vincenzo Passarelli, F. Benetollo
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Corrigendum: Ligand‐Controlled Regio‐divergent Pathways of Rhodium(III)‐Catalyzed Dihydroisoquinolone Synthesis – Experimental and Computational Studies of Different Cyclopentadienyls [PDF]
Matthew D. Wodrich +4 more
openalex +1 more source

