Results 51 to 60 of about 3,716,677 (247)
Emerging experimental and computational methods for studying redox‐regulated structural transitions
FEBS Letters, EarlyView.Redox reactions can reshape proteins and alter how they behave in cells, with important consequences for health and disease. This review explores emerging experimental and computational approaches for discovering these redox‐sensitive protein switches, revealing their structural effects, and predicting their behavior, opening new opportunities to ...
Tasneem Rass +2 more
wiley +1 more source
Bis(2,2,2 trifluoroethyl) Phosphonate as a Convenient Precursor for the Synthesis of H-Phosphonates
MoleculesA microwave-assisted synthesis of dialkyl and cyclic H-phosphonates via bis(2,2,2 trifluoroethyl) phosphonate (BTFEP) is described. This method enables the synthesis of various cyclic H-phosphonates and hetero-substituted dialkyl H-phosphonates by simple
Jean-Marie Pohl +4 more
doaj +1 more source
Bioorganic and Bioinorganic Chemistry
CHIMIA, 2010 The interdisciplinary projects in bioinorganic and bioorganic chemistry of the Department of Chemistry, University of Basel led to the preparation of new systems that mimic biologically important processes and to the discovery of compounds from ...
Edwin C. Constable +7 more
doaj +1 more source
Synthesis of Ti(OH)OF ⋅ 0.66 H2O in Imidazolium‐based Ionic Liquids
ChemistryOpen, 2021 The influence of the cation of imidazolium‐derived ionic liquids (ILs) on a low‐temperature solution‐based synthesis of hexagonal tungsten bronze (HTB) type Ti(OH)OF ⋅ 0.66 H2O and bronze‐type TiO2(B) is investigated.
Melanie Sieland +3 more
doaj +1 more source
Synergistic perspectives—How single‐molecule biophysics complement biochemical understanding
FEBS Letters, EarlyView.In this review, we discuss how ensemble biochemistry and single‐molecule approaches are complementary, outline commonly used single‐molecule techniques, and illustrate their relevance through two representative case studies: chromatin organization by SMC complexes and pathway choice during DNA double‐strand break repair.
Sara De Bragança +2 more
wiley +1 more source
Excited-State Relaxation in Luminescent Molybdenum(0) Complexes with Isocyanide Chelate Ligands
Inorganics, 2020 Diisocyanide ligands with a m-terphenyl backbone provide access to Mo0 complexes exhibiting the same type of metal-to-ligand charge transfer (MLCT) luminescence as the well-known class of isoelectronic RuII polypyridines.
Patrick Herr, Oliver S. Wenger
doaj +1 more source
FEBS Letters, EarlyView.Encapsulins are protein nanocompartments that play an important role in iron storage. In the Myxococcus xanthus encapsulin system, two cargo proteins called EncB and EncC contribute to iron mineralization. Here, we show that EncB and EncC generate iron‐containing minerals with distinct chemical compositions, suggesting that the composition of stored ...
Harry B. McDowell +2 more
wiley +1 more source
, 2016 The growing interest towards cyclizations under thermodynamic control is witnessed by the large number of papers dedicated to ring-chain equilibria, dynamic combinatorial chemistry, cooperativity and self-assembly.
G. Ercolani +7 more
core +1 more source
Structural and biochemical analysis of a B12 superbinder
FEBS Letters, EarlyView.BtuG proteins are vitamin B12 scavengers in Bacteroides thetaiotaomicron, a dominant human gut bacterium. We present crystal structures of three BtuG homologs bound to cobalamin and its precursor cobinamide, revealing picomolar binding affinities, among the highest known for any natural protein.
Jose M. Martinez Felices +3 more
wiley +1 more source
Determining Inversion Barriers in Atrop- isomers – A Tutorial for Organic Chemists
CHIMIA, 2016 Dynamic behavior is a fascinating property of natural and artificial systems and its understanding has significantly impacted the transformation of molecular interchanges into controlled molecular motion. In this tutorial, the key descriptors of
Michel Rickhaus +2 more
doaj +1 more source