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Stereoselective radical reactions
Chemical Society Reviews, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Gregory, Bar, Andrew F, Parsons
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Stereoselective synthesis of (−)-jimenezin
Tetrahedron Letters, 2005AbstractFor Abstract see ChemInform Abstract in Full Text.
Cheol Hee Hwang +4 more
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Stereoselective synthesis of (+)-boronolide
Tetrahedron Letters, 2005Abstract An efficient enantio- and stereocontrolled total synthesis of (+)-boronolide from valeraldehyde is described. The key steps include a Sharpless asymmetric dihydroxylation, a chelation controlled Grignard reaction followed by Sharpless asymmetric epoxidation and a ring closing metathesis.
S. Vasudeva Naidu +2 more
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Stereoselective Cyclopropanation Reactions
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Hélène, Lebel +3 more
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Stereoselective Synthesis of (‐)‐Allosedamine.
ChemInform, 2004Abstract A stereoselective synthesis of (−)-allosedamine is disclosed. β-Aminosulfoxide 4 was generated stereoselectively by condensation of the sulfinyl anion 2 with N-Ts imine 3 . The bromohydrin 5 was obtained by intramolecular sulfinyl group participation and the piperidine ring of allosedamine was elaborated using the ring-closing ...
Sadagopan Raghavan, A. Rajender
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Stereoselective synthesis of (+)-hyptolide
Tetrahedron Letters, 2003Abstract The first total synthesis of the naturally occurring lactone (+)-hyptolide is described. Ethyl l -lactate was the chiral starting material. Key steps of this 15-step synthesis were a Brown's asymmetric allylation, a Carreira's asymmetric ethynylation and a ring closing metathesis.
Juan Murga +3 more
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Stereoselective Bromofunctionalization of Alkenes
Chirality, 2013ABSTRACTThe stereoselective bromofunctionalization of alkenes, particularly the enantioselective format, has been a subject of intense research in recent years. The ground‐breaking works are documented in recent reviews. On the other hand, this account will provide an insight into our group's approach in tackling the challenges in enantioselective ...
Chong Kiat, Tan +2 more
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Stereoselective neuroimaging in vivo
European Neuropsychopharmacology, 2007Stereoselectivity is a basic property of many neuronal processes due to the spatial features of molecules involved in neurotransmission. Today, neuroimaging procedures are available for studying stereoselectivity in the living brain. Mirror-image radiotracers are the molecular tools that are used, together with single photon emission tomography (SPECT)
Smith, Donald F., Jakobsen, Steen
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Control of Stereoselectivity in Phosphotriesterase
2004Publisher Summary This chapter describes the control of stereoselectivity in phosphotriesterease (PTE). PTE originally isolated from the soil bacterium Pseudomonas diminuta , catalyzes the hydrolysis of a wide range of organophosphate compounds, including agricultural insecticides and chemical warfare agents. The mechanism of hydrolysis and overall
Suk-Bong, Hong, Frank M, Raushel
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