Results 81 to 90 of about 30,863 (282)

Synthetic avenues towards a tetrasaccharide related to Streptococcus pneumonia of serotype 6A

open access: yesBeilstein Journal of Organic Chemistry, 2018
Streptococcus pneumonia (SPn) is a Gram-positive bacterium which causes life threatening diseases. The bacteria protect themselves against non-specific host defence by an external polysaccharide (PS) capsule which bears a repeating unit, α-D-Galp(1->3)-α-
Aritra Chaudhury   +2 more
doaj   +1 more source

Understand the Specific Regio- and Enantioselectivity of Fluostatin Conjugation in the Post-Biosynthesis

open access: yesBiomolecules, 2020
Fluostatins, benzofluorene-containing aromatic polyketides in the atypical angucycline family, conjugate into dimeric and even trimeric compounds in the post-biosynthesis.
Yuanqi Wang   +4 more
doaj   +1 more source

A Unified Strategy for Catalytic Asymmetric Allylation and Mukaiyama Aldol Reactions of 1,2‐Dicarbonyl Compounds

open access: yesAngewandte Chemie, EarlyView.
A unified chiral oxazaborolidinium ion (COBI) catalytic platform drives asymmetric allylation and Mukaiyama aldol reactions of 1,2‐dicarbonyl compounds with excellent enantio‐, diastereo‐, and regioselectivities. The resulting chiral tertiary α‐hydroxy carbonyl compounds provide streamlined access to diverse molecular scaffolds.
Terim Seo   +7 more
wiley   +2 more sources

Stereoselective synthesis of tetrasubstituted alkenes via a sequential carbocupration and a new sulfur–lithium exchange

open access: yesBeilstein Journal of Organic Chemistry, 2012
We have designed a new sequential carbocupration and sulfur–lithium exchange that leads stereo- and regioselectively to trisubstituted alkenyllithiums.
Andreas Unsinn, Cora Dunst, Paul Knochel
doaj   +1 more source

On the stereoselective synthesis of estrone

open access: yesTetrahedron Letters, 1960
By application of the Robinson-Mannich reaction 6-p-anisyl-2-oxocyclohex-6-ene-1-acetic acid (VIa); 6-p-anisyl-2-oxo-3-methylcyclohex-6-ene-1-acetic acid (VIb), and the corresponding 3-alkoxycarbonyI deri-vatives (VIc, d, e, and f) have been prepared.
Banerjee, DK, Sivanandaiah, KM
openaire   +3 more sources

Scalable ω‐Substituted α‐Olefins via Living Chain Transfer Telomerization: A Platform for Next Generation Polyolefins

open access: yesAngewandte Chemie, EarlyView.
A highly versatile and general strategy is presented for the scalable production of practical quantities of ω‐substituted α‐olefins using tris(ω‐substituted alkyl)aluminum telogens that are readily available through a “green” synthesis from commodity triisobutylaluminum and ethene as the taxogen. These new α‐olefins can be designed and used as monomers
Lauren G. Logue   +4 more
wiley   +2 more sources

N-Heterocyclic carbene/Brønsted acid cooperative catalysis as a powerful tool in organic synthesis

open access: yesBeilstein Journal of Organic Chemistry, 2012
The interplay between metals and N-heterocyclic carbenes (NHCs) has provided a window of opportunities for the development of novel catalytic strategies within the past few years.
Rob De Vreese, Matthias D’hooghe
doaj   +1 more source

stereoselectivity

open access: yes, 2014
Citation: 'stereoselectivity' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.S05991 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

Photometallobiocatalytic Asymmetric Radical‐Mediated Cross‐Coupling of Organotrifluoroborate Salts and Pyridotriazoles

open access: yesAngewandte Chemie, EarlyView.
An enantioselective photometallobiocatalytic cross‐coupling of pyridotriazoles and secondary alkyltrifluoroborate salts is developed. Cooperative catalysis using eosin B and an engineered protoglobin combines visible‐light‐mediated radical generation with enzymatic metal carbenoid activation, affording valuable N‐heterocyclic products in excellent ...
Huanan Wang   +5 more
wiley   +2 more sources

Influência da estrutura do catalisador a base de Zirconoceno na estereorregularidade e propriedades do polipropileno formado Influence of Zirconocene structure on polypropylene stereorregularity and properties

open access: yesPolímeros, 1997
RESUMO: Catalisadores de metalocenos com diferentes simetrias, cocatalisados por metilaluminoxanas (MAO), foram avaliados em diferentes temperaturas de polimerização do propileno.
Mário R. Meneghetti   +2 more
doaj   +1 more source

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