Results 151 to 160 of about 106,522 (343)

Iron-catalyzed fluoroalkylative alkylsulfonylation of alkenes via radical-anion relay

open access: yesNature Communications
Transition metal-catalyzed reductive difunctionalization of alkenes with alkyl halides is a powerful method for upgrading commodity chemicals into densely functionalized molecules.
Xiaoya Hou, Hongchi Liu, Hanmin Huang
doaj   +1 more source

Metal Nanoparticles on Halloysite Applied in Stereoselective Hydrogenation of Tetrasubstituted Alkenes

open access: yesChemistry – A European Journal, EarlyView.
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich   +9 more
wiley   +1 more source

Iron‐Mediated Electrochemical Cyclopropanation of Borodiiodomethane with Alkenes†

open access: yesChinese Journal of Chemistry, EarlyView.
This work describes an electrochemical iron‐mediated cyclopropanation of borodiiodomethane with alkenes, resulting in the formation of boro‐substituted cyclopropanes. A key feature of this study is the unexpected discovery that the cathodically generated iron ion coordinates with a biquinoline ligand in situ, facilitating the electrochemical ...
Jie Li   +3 more
wiley   +1 more source

Synthesis of (E)‐β‐SF5‐Styrenes via a Heck Reaction of in situ Generated Vinylsulfur Pentafluoride†

open access: yesChinese Journal of Chemistry, EarlyView.
A Heck cross‐coupling reaction between aryl(hetero)iodides and in situ generated vinylsulfur pentafluoride is reported. This reaction provides β‐SF5‐styrenes in one‐step as a single (E)‐stereoisomer and tolerates a broad range of functional groups. Comprehensive Summary The synthesis of (E)‐(1‐alken‐1‐yl)pentafluoro‐λ6‐sulfanes, a valuable class of ...
Nicolas DeGrâce   +1 more
wiley   +1 more source

Membrane Engineering for Battery Systems: Bridging Design Principles and Frontier Applications

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The review emphasizes membrane separators' role in battery performance and safety, covering redox flow, lithium‐ion, and solid‐state batteries. It reviews advances in membrane materials (e.g., polymer electrolytes, hybrid composites) and ion transport mechanisms, while addressing challenges like dendrite growth and crossover losses.
Xiaoqun Zhou   +3 more
wiley   +1 more source

SULFONATION [PDF]

open access: yesChemical & Engineering News Archive, 1998
openaire   +1 more source

Onium ions. 18. Static protonated and exchanging diprotonated ambivalent heteroorganic systems. hydroxylamines, acetone oxime, and dimethyl sulfoxide [PDF]

open access: yes, 1978
Andreozzi, Patricia   +5 more
core   +1 more source

Electrolyte Design Strategies for High‐Energy‐Density Li/Na/K‐Metal Batteries Toward Grid‐Scale Energy Storage: From Liquid to Solid

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This review summarizes key parameters including cathode loading and electrolyte consumption, clarifies the practical application scope of alkali metal batteries, and research progress on advanced electrolytes for grid‐scale energy storage systems. The growing demand for grid‐scale battery energy storage systems (BESSs) has prompted researchers to turn ...
Hui Shao, Zhiwei Ni, Jinkui Feng
wiley   +1 more source

Hydrophobic eutectic solvent‐engineered membranes for highly permeable, selective, and antifouling pharmaceutical removal from municipal wastewater

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Single‐step incorporation of a hydrophobic deep eutectic solvent (HDES) into polyethersulfone ultrafiltration membranes via non‐solvent induced phase separation creates selective, antifouling membranes for pharmaceutical removal. The HDES nanodomains enhance permeability, electrostatic interactions, and adsorption affinity, enabling efficient and ...
Anjali Goyal   +8 more
wiley   +1 more source

Crystal Orientation Regulation and Dynamic Protection via Dual Interface Engineering for Dendrite‐Free Zinc Deposition

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A dual‐interface engineering strategy is innovatively proposed to achieve dendrite‐free Zn anodes through crystallographic orientation regulation and adaptive interfacial protection. By pre‐coating eco‐friendly di‐pentaerythritol, horizontal growth of ZHS along the (001) plane is induced, which in turn guides epitaxial Zn deposition on the (002) plane.
Xin Wu   +8 more
wiley   +1 more source

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