Interaction of solid organic acids with carbon nanotube field effect transistors [PDF]
A series of solid organic acids were used to p-dope carbon nanotubes. The extent of doping is shown to be dependent on the pKa value of the acids. Highly fluorinated carboxylic acids and sulfonic acids are very effective in shifting the threshold voltage and making carbon nanotube field effect transistors to be more p-type devices.
arxiv +1 more source
Radical Titanocene Promoted Coupling of Epoxides and Vinyl Sulfones [PDF]
[EN]A radical coupling reaction of diverse vinyl sulfones and epoxides was mediated by Cp2TiCl (Cp = cyclopentadienyl) to provide a straightforward synthetic pathway to hydroxy sulfones. The reaction was successfully achieved by using either an excess or
Encinas Madrazo, Soledad+3 more
core +1 more source
Enantioselective Synthesis of cis-Decalins Using Organocatalysis and Sulfonyl Nazarov Reagents
The first organocatalytic synthesis of cis-decalins using sulfonyl Nazarov reagents is reported. The Jørgensen’s catalyst directs this highly enantioselective synthesis using different cyclohexenal derivatives.
Javier Peña+6 more
doaj +1 more source
Cu-Catalyzed Silylation of Alkynes: A Traceless 2-Pyridylsulfonyl Controller Allows Access to either Regioisomer on Demand [PDF]
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher.
Carretero, Juan C.+4 more
core +3 more sources
Desulfurization of Dibenzothiophene and Oxidized Dibenzothiophene Ring Systems
Lithium, used in conjunction with sodium metal, produces a high yield of biphenyl when reacted with dibenzothiophene, dibenzothiophene sulfoxide or dibenzothiophene sulfone.
Diego P. Morales+2 more
doaj +1 more source
Exploring electrical conductivity within mesoscopic phases of semi-conducting PEDOT:PSS films by Broadband Dielectric Spectroscopy [PDF]
Poly(3,4-ethylenedioxythiophene) : poly(styrene sulfonic acid (PEDOT:PSS), an optically transparent organic semi-conductor, constitutes a suspension of conducting PEDOT:PSS grains, shelled by an insulating layer of PSS. While a percolation network enhances dc conductivity, structural and electrical inhomogenity hinters electric charge flow giving rise ...
arxiv +1 more source
Studies on the Synthesis, Stability and Conformation of 2-Sulfonyl-Oxetane Fragments [PDF]
A library of 2-sulfonyl oxetane fragments has been synthesised and elaborated into lead-like compounds. The oxetane derivatives were stable to acidic and basic conditions and have 3-preferred conformations.
Bull, JA, Hollingsworth, IA, Morgan, KF
core +1 more source
A variety of different novel functionalized ferrocenyl chalcone and organic chalcone based sulfones and bis-sulfones were synthesized in excellent yield under mild reaction condition.
Naseem Ahmed+2 more
doaj
Synthesis and Promising in Vitro Antiproliferative Activity of Sulfones of a 5-Nitrothiazole Series
 The synthesis in water of new sulfone derivatives under microwave irradiation is described. This eco-friendly process leads to the expected products in good yields by reaction of various substituted sulfinates (commercially available or ...
Nadine Azas+4 more
doaj +1 more source
Tuning effective hyperfine fields in PEDOT:PSS thin films by doping [PDF]
Using electrically detected magnetic resonance spectroscopy, we demonstrate that doping the conducting polymer poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate) (PEDOT:PSS) with ethylene glycol allows for the control of effective local charge carrier hyperfine fields through motional narrowing.
arxiv +1 more source