Results 71 to 80 of about 13,481 (259)
Metal-assisted reactions. Part 25. Heterogeneous and homogeneous catalytic transfer hydrogenolysis of allyloxytetrazoles to yield alkenes or alkanes [PDF]
Transfer hydrogenolysis of 5-allyloxy- 1-phenyltetrazoles using either a heterogeneous or a homogeneous palladium catalyst and a hydrogen donor leads to cleavage of the allyloxy C-O bond to yield an alkane or an alkene and 1-phenyltetrazolone, depending ...
Cristiano, Maria Lurdes Santos +2 more
core +1 more source
Dieser Mini‐Review behandelt die neuesten Fortschritte bei der Synthese, Reaktivität und metallfreien katalytischen Verwendung von mesoionischen N‐heterocyclischen Olefinen (mNHOs), Iminen (mNHIs), Thionen (mNHTs) und Phosphinidenen (mNHPs). Kurzzusammenfassung Übergangsmetallverbindungen sind allgemein für ihre Fähigkeit bekannt, kleine Moleküle zu ...
Subir Maji +3 more
wiley +1 more source
ChemInform Abstract: Synthesis of Boc‐Amino Tetrazoles Derived from α‐Amino Acids [PDF]
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option ...
Nagendra, G. +2 more
core +1 more source
Mesoionic N‐Heterocyclic Olefins, Imines, Thiones, Phosphinidenes and Their Application in Catalysis
This minireview covers recent advances in the synthesis, reactivity, and metal‐free catalytic uses of mesoionic N‐heterocyclic olefins (mNHOs), imines (mNHIs), thiones (mNHTs), and phosphinidenes (mNHPs). Abstract Transition metal compounds are widely known for their ability to activate small molecules and are excellent catalysts for a wide range of ...
Subir Maji +3 more
wiley +1 more source
Sodium azide or trimethylsilylazide react with N,N-dimethylphosgenimonium chloride by monosubstitution yielding N,N-dimethyl-azidochloromethylen-imonium chloride which can be isolated.
H.G. Viehe, P. George
doaj +1 more source
Low temperature matrix-isolation and solid state vibrational spectra of tetrazole [PDF]
Infrared spectra of tetrazole (CN isolated in an argon matrix (T \10 K) and in the solid state (at room 4H2) temperature) were investigated. In the crystalline phase, tetrazole exists in its 1H-tautomeric form and new assignments of the vibrational ...
Bugalho, Susana C. S. +3 more
core +2 more sources
The design and synthesis of a linear tetradentate NCCN ligand incorporating two 1,2,3‐triazolin‐5‐ylidene mesoionic carbene donors, and its application to asymmetric iron catalysis is reported. This work represents the first example of an iron complex derived from a cis‐α‐coordinating tetradentate NCCN ligand, and notably, the first chiral iron ...
Lukas Hinterlang +3 more
wiley +1 more source
In silico identification, synthesis and biological evaluation of novel tetrazole inhibitors of MurB [PDF]
In the context of antibacterial drug discovery resurgence, novel therapeutic targets and new compounds with alternative mechanisms of action are of paramount importance. We focused on UDP-N- acetylenolpyruvylglucosamine reductase (i.e.
Barreteau, Hélène +7 more
core +3 more sources
Concise Synthesis of Tetrazole Macrocycle [PDF]
A concise two step synthesis of tetrazole containing macrocycles from readily accessible starting materials is presented. The first step comprises a chemoselective amidation of amino acid derived isocyanocarboxylicacid esters with unprotected symmetrical diamines to afford diverse α-isocyano-ω-amines. In the second step, the α-isocyano-ω-amines undergo
Abdelraheem +7 more
openaire +4 more sources
Cyclopropenes in Photochemical Reactions
The photochemical side of cyclopropenes. Cyclopropenes are valuable synthetic tools in organic chemistry. In particular, this review focuses on the photochemistry of cyclopropenes. The reactivity of cyclopropenes excited by irradiation is discussed showing their unique potential for organic synthesis.
David Suárez‐García +2 more
wiley +1 more source

