Results 71 to 80 of about 18,166 (271)
Flash Vacuum Pyrolysis of Azides, Triazoles, and Tetrazoles.
Flash vacuum pyrolysis (FVP) of azides is an extremely valuable method of generating nitrenes and studying their thermal rearrangements. The nitrenes can in many cases be isolated in low-temperature matrices and observed spectroscopically. NH and methyl,
C. Wentrup
semanticscholar +1 more source
Diverse reactivity of maleimides in polymer science and beyond
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick+2 more
wiley +1 more source
Through the directed evolution of an underexploited nonheme Fe extradiol dioxygenase, we developed a unified cooperative photobiocatalytic strategy to allow for three types of enantioconvergent radical transformations, including azidation, thiocyanation, and isocyanation.
Liu‐Peng Zhao+8 more
wiley +2 more sources
Polymethylenetetrazole: Synthesis, Characterization, and Energetic Properties
The tetrazole moiety remains one of the most interesting scaffolds in the development of new high-energy density materials (HEDMs) because of its desired characteristics, such as high nitrogen content and heat of formation (HOF).
Ljubica Brenjo+6 more
doaj +1 more source
In Vitro Studies of Chromone-Tetrazoles against Pathogenic Protozoa, Bacteria, and Fungi
In vitro studies to fourteen previously synthesized chromone-tetrazoles and four novel fluorine-containing analogs were conducted against pathogenic protozoan (Entamoeba histolytica), pathogenic bacteria (Pseudomonas aeruginosa, and Staphylococcus aureus)
Pedro A. Cano+8 more
doaj +1 more source
A high‐quality set of 229 crystal structures of various isoforms of human and mouse fatty acid‐binding proteins in apo and ligand‐bound forms is presented. Many ligands have associated affinity data, which may help in the development of affinity‐ and pose‐predicting algorithms.Fatty acid‐binding protein isoforms 4 and 5 are potential diabetes and ...
Andreas Ehler+2 more
wiley +1 more source
Silica sulfuric acid (SSA) was found to be an efficient heterogeneous catalyst for the synthesis of 1-substituted 1H-1,2,3,4-tetrazoles from the reaction of primary amines with triethyl orthoformate and sodium azide under thermal and solvent-free ...
Davood Habibi+2 more
doaj +1 more source
Tetrazoles of manno- and rhamno- furanoses
Abstract The synthesis of [3.3.0] bicyclic tetrazoles derived from D-manno and D-rhamnofuranose starting from D-mannose, and of L-rhamnofuranose starting from L-rhamnose is described. The key step in the formation of all three examples of this novel class of sugar mimics is an intramolecular [1,3]-dipolar cycloaddition of azide and nitrile moieties.
Benjamin G. Davis+5 more
openaire +4 more sources
Very high‐resolution fatty acid‐binding protein structures identified a substantial number of ligands that differ strongly from their expected structure. If different ligand chemistry is a potentially overlooked problem in other, lower resolution, crystal structures of protein–ligand complexes, it has repercussions for any study using such structures ...
Andreas Ehler+4 more
wiley +1 more source
NMR studies on human FABP4 in solution and bound to micelles and bicelles delineate its dynamics in a ligand‐dependent fashion. Residual ligands are co‐purified with the protein, which may negatively influence binding studies with low‐affinity ligands.Fatty acid‐binding proteins (FABPs) are involved in the uptake and intracellular trafficking of fatty ...
Fabio Casagrande+5 more
wiley +1 more source