Results 81 to 90 of about 46,961 (245)

Dual Ligand‐Enabled Nondirected C─H Olefination of (Hetero)Arenes for the Synthesis of Clickable Derivatives

open access: yesChemistry – A European Journal, EarlyView.
We report an efficient method for late‐stage installation of “clickable” alkyne groups into diverse (hetero)arenes. Using a dual‐ligand palladium catalyst that combines an NASA ligand with an N‐heterocycle, an acrylate unit bearing a terminal alkyne can be introduced via nondirected C─H activation.
Tommaso Braga   +2 more
wiley   +1 more source

Boosting Zinc‐Ion Hybrid Capacitors with Mesoporous Carbon Derived from Highly Graphitized Carbon Quantum Dots

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The work presents an innovative method for the preparation of mesoporous carbon materials (MCs) from highly graphitized carbon quantum dots. The zinc‐ion hybrid capacitors assembled with MCs deliver high rate performance and stability, providing promising advancements for future energy storage solutions.
Guoli Zhang   +6 more
wiley   +1 more source

Toward Safer and Sustainable Lithium Metal Batteries: Fluorine‐Free Solid Polymer Electrolytes

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
An analysis to assess the impact of fluorine in polymer electrolyte‐based lithium metal batteries has been conducted. It has been demonstrated that fluorine‐free LiTIM salt delivers a electrochemical performance similar to that of its fluorinated analogue salts, given the complete lithium dissociation in coordination with PEO and the restricted anion ...
David Fraile‐Insagurbe   +10 more
wiley   +1 more source

Syntheses, Antibacterial and Antifungal Activities of Substituted-Thiazolo-1,3,4-Thiadiazoles, 1,3,4-Oxadiazoles and 1,2,4-Thiazoles [PDF]

open access: yesIranian Journal of Chemistry & Chemical Engineering, 1998
Starting from readily available 2-substituted-4-methylthiazole-5-carboxylic acid hydrazide (1), The title compounds were prepared. The reaction of compound 1 (R=CH3) with formic acid yielded 1-(formyl)-2-(2,4-dimethylthiazole-5-carboxyl) hydrazine (2 ...
Abbas Shafiee   +2 more
doaj  

Synthesis of Heterocyclic Scaffolds from Nitrobenzyl Alcohols Using Reduction‐Generated Azaquinone Methides and Cyclization

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Intramolecular cyclization to quench an in situ reduction‐generated azaquinone methide is a strategy that could be used for late‐stage heterocycle synthesis. Herein, synthetically accessible 4‐nitrobenzyl alcohols with a nucleophilic handle adjacent to the benzyl alcohol group are reduced under mild conditions to afford six‐ and seven‐membered ...
Harrison M. Lewin   +4 more
wiley   +1 more source

Monosaccharide‐Based Macrocyclic Receptors—History and Recent Applications

open access: yesHelvetica Chimica Acta, EarlyView.
This perspective provides an overview of most common applications of monosaccharide‐based macrocycles in molecular recognition over the past four decades. The most recent achievements, such as fluorescent ion sensing and selective amino acid binding in aqueous media, including the work from the author's lab, are highlighted. Potential future directions
Bartosz Lewandowski
wiley   +1 more source

A personal 360° view of applications of ‘biomimetic’ molecular recognition

open access: yesJournal of Chemical Technology &Biotechnology, EarlyView.
Abstract Molecular recognition between biological molecules has formed the basis for innumerable applications in biotechnology for the last seven decades or so. Techniques such as affinity chromatography, solid‐phase and aqueous two‐phase extraction, affinity precipitation, biomimetic catalytic systems, biosensors and molecular imprinting all exploit ...
Christopher R Lowe
wiley   +1 more source

Agar: a natural and environmentally-friendly support composed of copper oxide nanoparticles for the green synthesis of 1,2,3–triazoles

open access: yesGreen Chemistry Letters and Reviews, 2019
A novel, green and cost-effective heterogeneous nanocatalyst was synthesized by supporting copper (I) oxide nanoparticles on magnetic agar (Cu2O/Agar@Fe3O4).
Ali Maleki   +2 more
doaj   +1 more source

Evaluation of antifungal and antimycotoxigenic activity of selected natural antioxidants against Fusarium culmorum: in vitro and in planta assays

open access: yesJournal of the Science of Food and Agriculture, EarlyView.
Abstract BACKGROUND Fusarium culmorum causes Fusarium head blight (FHB) in cereals, leading to significant yield losses and contamination with type B trichothecene mycotoxins such as deoxynivalenol (DON) and its acetylated derivatives 3‐ADON and 15‐ADON.
Safa Oufensou   +8 more
wiley   +1 more source

Diacetylene‐Functionalized Glycan Mimetics for Receptor‐Mediated Cluster Imprinting in Model Membranes

open access: yesMacromolecular Rapid Communications, EarlyView.
Diacetylene‐containing glycan mimetics cluster upon selective lectin binding in GUVs. Subsequent irradiation leads to the formation of fluorescent polymer clusters, while non‐clustered glycan mimetics remain unaffected in the membrane. ABSTRACT The glycocalyx, a dense layer of glycoproteins and glycolipids on eukaryotic cells, is essential for cellular
Luca‐Cesare Blawitzki   +5 more
wiley   +1 more source

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