Results 61 to 70 of about 22,593 (123)

Synthesis of 1,2,3-triazole functionalized hyperbranched poly(ethyleneimine) and its use as multifunctional anionic macroinitiator for diglycidyl ether of bisphenol A curing [PDF]

open access: yes, 2016
Hyperbranched poly(ethyleneimine) (PEI) has been modified by the addition of propargyl acrylate following a Michael addition reaction. On this polymer (PEI-yne) a copper (I)-catalyzed azide alkyne cycloaddition (CuAAC) has been performed to obtain a ...
Acebo Gorostiza, Cristina   +4 more
core   +2 more sources

Development of a Copper‐Free Click Reaction for Asymmetric Rh Diene Catalysis Under Confinement

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 1, January 2026.
A copper‐free amino–yne click reaction enables the selective functionalization of chiral diene ligands with both soluble and immobilized amines. Substituent‐controlled stereoselectivity affords (E)‐ and (Z)‐enaminone ligands, which are converted into Rh complexes for asymmetric catalysis under homogeneous and heterogeneous conditions.
Manuel Kirchhof   +10 more
wiley   +1 more source

Synthesis of some isoxazoline, isoxazole and pyrazole carboxylic acids as the precursors of new 1,2-diacyl-1-alkylhydrazines [PDF]

open access: yes, 2013
A number of isoxazoline, isoxazole and pyrazole carboxylic acids or their esters has been synthesized via the 1,3-dipolar cycloaddition of corresponding nitrile oxides or diazomethane to unsaturated dipolarophiles.
Antonevich, I. P., Katok, Ya. M.
core  

The Chemistry of Subphthalocyanines: Synthetic Strategies for their Axial, Peripheral, and Remote Postfunctionalization

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
From axial and peripheral reactivity to remote derivatization, the chemical versatility of subphthalocyanines (SubPcs) renders them ideal scaffolds for the design of advanced functional materials. This review assembles the synthetic toolbox, key reaction conditions, and future challenges in SubPc functionalization, guiding the development of next ...
Marta Gómez‐Gómez   +4 more
wiley   +1 more source

Imidazoline‐Proline and Imidazoline‐Prolinate Ligands for Copper‐Catalyzed Asymmetric Exo‐Selective [3 + 2] Cycloaddition of Iminoesters with Nitroalkenes

open access: yesChemistryEurope, Volume 4, Issue 1, January 2026.
From a modular synthesis of nonphosphine chiral nitrogen‐based chiral imidazoline–amino acid ligands, two new chiral imidazoline–proline‐copper catalysts are developed for targeting exo‐selective [3 + 2] cycloaddition reaction. Density functional theory studies rationalize the observed stereoselectivity and the distinct chiral pockets of the two ...
Yan Yu   +4 more
wiley   +1 more source

Molecular Engineering of Donor–Acceptor Structures in Fullerene‐Indacenodithiophene Photocatalysts for Efficient Hydrogen Evolution

open access: yesCarbon Neutralization, Volume 5, Issue 1, January 2026.
A molecular engineering strategy is applied to tune donor side chains and fullerene cage size in supramolecular organic photocatalysts. Structural modulation enhances π–π stacking, charge transport, and light absorption. The optimized SA‐C70‐IDTT architecture achieves efficient hydrogen evolution of 17.16 mmol g−1 h−1, highlighting donor–acceptor ...
Yupeng Song   +10 more
wiley   +1 more source

Exploring Isophorone‐Based Dienones: Comprehensive Insights Into Their Synthesis, Reactivity, and Diverse Applications

open access: yesJournal of Chemistry, Volume 2026, Issue 1, 2026.
Isophorone is an important motif in synthetic organic chemistry, as it is highly reactive and can get involved in a diverse array of functional group transformations to access various synthetic intermediates and molecular targets. In this context, an important group of compounds is the conjugated or nonconjugated isophorone‐cored dienones, which are ...
M. Saeed Abaee   +2 more
wiley   +1 more source

Cyaphide-Azide 1,3-Dipolar Cycloaddition Reactions: Scope and Applicability. [PDF]

open access: yesChemistry, 2023
Yang ES   +4 more
europepmc   +1 more source

Catalytic asymmetric synthesis of highly substituted pyrrolizidines [PDF]

open access: yes, 2012
A catalytic asymmetric double (1,3)-dipolar cycloaddition reaction has been developed. Using a chiral silver catalyst, enantioenriched pyrrolizidines can be prepared in one flask from inexpensive, commercially available starting materials.
Codelli, Julian A.   +2 more
core  

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