Results 71 to 80 of about 24,842 (217)

Intramolecular Hydrogen Bond Activation: Thiourea-Organocatalyzed Enantioselective 1,3-Dipolar Cycloaddition of Salicylaldehyde-Derived Azomethine Ylides with Nitroalkenes

ACS Catalysis, 2018
An organocatalytic strategy for the synthesis of tetrasubstituted pyrrolidines with monoactivated azomethine ylides in high enantiomeric excess and excellent exo/endo selectivity is presented.
F. Esteban, Wioleta Cieślik, E. Arpa, Andrea Guerrero-Corella, S. Dı́az-Tendero, J. Perles, Jose A. Fernández‐Salas, A. Fraile, J. Alemán   +8 more
semanticscholar   +1 more source

5-Benzoyl-N,4-diphenyl-4,5-dihydro-1H-pyrazole-3-carboxamide

Acta Crystallographica Section E, 2009
The title compound, C23H19N3O2, was synthesized by the 1,3-dipolar cycloaddition reaction of N-phenyl-α-diazoacetamide and chalcone. In the molecule, the pyrazoline ring assumes an envelope conformation.
Long He
doaj   +1 more source

Electrochemistry and Antioxidant Activities of Substituted Furanyl Nitrone: The Role of the Nitro Group

ChemElectroChem, EarlyView.
N‐methyl‐nitroaryl‐furanyl‐nitrone (LQB‐569) suffers a 10‐electron reduction, forming a hydrazine group with two terminal hydroxylamine groups. Nitrones’ antioxidant capacity (AO), despite being very low, correlates with their oxidation profiles, and the ones able to oxidize more easily have better results on DPPH• scavenging and ferric‐reducing ...
Danyelle Cândido Santos, Débora de Souza dos Santos Costa, Paulo R. R. Costa, Ayres Guimarães Dias, Messias de Oliveira Silva, Taualia Achira Aly, Vinícius Del Colle, Jadriane Almeida Xavier, Marília O. F. Goulart, Thaissa Lúcio Silva   +9 more
wiley   +1 more source

Kinetic Resolution of Alkylidene Norcamphors via a Ligand-Controlled Umpolung-Type 1,3-Dipolar Cycloaddition

iScience, 2019
Summary: Development of a general catalytic and highly efficient method utilizing readily available precursors for the regio- and stereoselective construction of bioactive natural-product-inspired spiro architectures remains a formidable challenge in ...
Chong Shen, Yuhong Yang, Liang Wei, Wu-Wei Dong, Lung Wa Chung, Chun-Jiang Wang   +5 more
doaj  

1,3-Dipolar Cycloadditions of N-Benzyl Furfuryl Nitrones with Electron-rich Alkenes

Molecules, 2000
The 1,3-dipolar cycloaddition reaction of N-benzyl-C-(2-furyl)nitrones with electron-rich alkenes gives preferentially trans-substituted 3,5-disubstituted isoxazolidines (endo approach).
Tomas Tejero, Francisco L. Merchan, Sonia Anoro, Pedro Merino   +3 more
doaj   +1 more source

The Azidofunctionalization of Alkenes

ChemistryEurope, EarlyView.
The azidofunctionalization of alkenes offers a powerful strategy for synthesizing nitrogen‐containing compounds by installing both an azide and a second functional group in one step. This approach, employing photoredox catalysis, transition metals, and radical methods, is efficient, selective, and versatile, with applications in pharmaceuticals and ...
Pierre Palamini, Jerome Waser
wiley   +1 more source

Synthesis of Pyrrole via a Silver-Catalyzed 1,3-Dipolar Cycloaddition/Oxidative Dehydrogenative Aromatization Tandem Reaction.

Journal of Organic Chemistry, 2017
Pyrroles are an important group of heterocyclic compounds with a wide range of interesting properties, which have resulted in numerous applications in a variety of fields.
Y. Liu, Huayou Hu, Xiang Wang, Sanjun Zhi, Y. Kan, Chao Wang   +5 more
semanticscholar   +1 more source

One-pot Microwave-Assisted Synthesis of 1H-Phenanthro[9,10- d][1,2,3]triazole

Molbank, 2008
In this study, a fast and good yield one-pot microwave-assisted synthesis (45 seconds) of 1H-phenanthro[9,10-d][1,2,3]triazole by a 1,3-dipolar cycloaddition reaction of sodium azide and 9-bromophenanthrene in the presence of potassium tert-butoxide in ...
Mehrak Faraji, Avat Arman Taherpour
doaj   +1 more source

Bioorthogonal Click‐to‐Release of Branched Pro‐Fluorophores

Chemistry – A European Journal, EarlyView.
Alkene‐azide click‐to‐release branched prodrugs can amplify the amount of cargo activated. However, balance between the “click” and “release” steps is essential. Branched pro‐fluorophores provided the fastest‐to‐date click reaction of aryl azides and TCOs. The second branched core enabled the self‐immolation, releasing higher levels of fluorophore than
Thomasin Brind, Aggie Lawer, Tobias Todd, Sushant Aryal, Sarah Hook, Allan B. Gamble   +5 more
wiley   +1 more source

Tandem Intramolecular Diels-Alder/1,3-Dipolar Cycloaddition Cascade of 1,3,4-Oxadiazoles: Initial Scope and Applications.

Accounts of Chemical Research, 2016
A summary of the development and initial studies on the scope of a powerful tandem intramolecular [4 + 2]/[3 + 2] cycloaddition cascade of 1,3,4-oxadiazoles is detailed and provides the foundation for its subsequent use in organic synthesis.
J. Sears, D. Boger
semanticscholar   +1 more source