Results 191 to 200 of about 292,300 (359)

Domino Synthesis of Functionalized Cyclic Acetals From Organic Carbonates

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Cyclic carbonates equipped with acrylic functional groups are shown to undergo a domino process in the presence of a suitable alkoxide to deliver novel types of decorated cyclic acetals. The developed protocol combines practical conditions and a wide scope and features a new reactivity modus for these carbon dioxide‐derived heterocyclic precursors.
Natalia Kulbacka   +5 more
wiley   +1 more source

Asymmetric Synthesis of Atropisomeric Amines via Transaminase‐Catalyzed Dynamic Kinetic Resolution

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A dynamic kinetic resolution approach is developed for the atroposelective synthesis of heterobiaryl primary amines. Using transaminases and leveraging Lewis acid‐base interactions to induce racemization, a variety of axially chiral primary amines are produced in high yields and enantioselectivities.
Juan M. Coto‐Cid   +8 more
wiley   +1 more source

aldehydes [PDF]

open access: yesChemical & Engineering News Archive, 1953
openaire   +1 more source

Synthesis of Polysubstituted Tetrahydro‐1,4‐Thiazepines by Rhodium‐Catalyzed Ring Expansion of Dihydro‐1,3‐Thiazines with Diazoesters

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A rhodium(II)‐catalyzed ring expansion of stereodefined dihydro‐1,3‐thiazines with diazomalonates gives 1,4‐thiazepines via a sulfonium ylide rearrangement. The reaction shows a cis/trans reactivity divergence arising from different metal coordination, as revealed by experiments and density functional theory studies.
Laurine Tual   +3 more
wiley   +1 more source

Gene expression analysis in epileptic hippocampi reveals a promoter haplotype conferring reduced aldehyde dehydrogenase 5a1 expression and responsiveness [PDF]

open access: hybrid, 2020
Despina Tsortouktzidis   +8 more
openalex   +1 more source

Smart REASSURED Sensors via Machine‐Augmented Printable On‐Paper Arrays

open access: yesAdvanced Sensor Research, EarlyView.
This perspective highlights the emerging role of pattern‐recognition, printable on‐paper sensor arrays for intelligent PoC diagnostics. It discusses how paper's inherent limitations can be overcome through surface modification and scalable printing, and how machine‐learning analysis of cross‐reactive arrays enables multiplexed, low‐cost, and REASSURED ...
Naimeh Naseri, Saba Ranjbar
wiley   +1 more source

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