Results 261 to 270 of about 253,250 (328)

The Chemistry of Subphthalocyanines: Synthetic Strategies for their Axial, Peripheral, and Remote Postfunctionalization

open access: yesChemistryEurope, EarlyView.
From axial and peripheral reactivity to remote derivatization, the chemical versatility of subphthalocyanines (SubPcs) renders them ideal scaffolds for the design of advanced functional materials. This review assembles the synthetic toolbox, key reaction conditions, and future challenges in SubPc functionalization, guiding the development of next ...
Marta Gómez‐Gómez   +4 more
wiley   +1 more source

The Importance of Denaturing Conditions for Protein and Peptide Quantification by Tryptophan Fluorescence. [PDF]

open access: yesACS Omega
Desire CT   +6 more
europepmc   +1 more source

Activation of the CN Single Bond in Iso(thio)cyanates by a Phosphinine‐Borane Lewis Pair: Unravelling a Complex Reaction Network

open access: yesChemistryEurope, EarlyView.
The Lewis pair 1, comprising an aromatic phosphinine and the strong Lewis acid B(C6F5)3, selectively activates the CN bonds in tBuNCO and tBuNCS. The experimental and computational studies confirmed the formation of a 1‐tBu‐phosphininium salt, acting as a key intermediate. Unlike classical frustrated Lewis pairs, this method allows the alkylation of
Samantha Frank   +6 more
wiley   +1 more source

Bis(phenolate) N‐Heterocyclic Carbene [OCO] Pincer Ligands: A Unique Family for the Stabilization of Transition Metal Centers and Main Group Elements

open access: yesChemistryEurope, EarlyView.
This review highlights the coordination chemistry of NHC bis‐phenolate ligands with metal centers, emphasizing structural features, redox and optical properties, and catalytic applications. Key roles in polymerization, nitrogen reduction catalysis, and small molecule activation are discussed, showcasing the versatility and potential of [OCO]M complexes
Johanna Frey   +3 more
wiley   +1 more source

Biocompatible decarboxylative coupling enabled by N-hydroxynaphthalimide esters. [PDF]

open access: yesNat Commun
Liao H   +12 more
europepmc   +1 more source

Unlocking Biomolecule Modification with Light‐Promoted Photocatalyst‐Free Approaches: Current Tools, Challenges, and Perspectives

open access: yesChemistryEurope, EarlyView.
This Perspective focuses on photocatalyst‐free, photoinduced modifications of biomolecules, emphasizing transformations mediated by electron donor–acceptor complexes. Mechanistic aspects, current limitations, and future opportunities are discussed, providing insight into the field of bioconjugation.
Milene Hornink   +3 more
wiley   +1 more source

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