Results 1 to 10 of about 116,437 (362)
Electrochemical Hydroboration of Alkynes [PDF]
AbstractHerein we reported the electrochemical hydroboration of alkynes by using B2Pin2as the boron source. This unprecedented reaction manifold was applied to a broad range of alkynes, giving the hydroboration products in good to excellent yields without the need of a metal catalyst or a hydride source.
Thomas Poisson +4 more
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Stereoselective synthesis of (E)-vinyl alkyl sulfides via hydrozirconation of terminal alkynes [PDF]
Terminal alkynes react with Cp2Zr(H)Cl (Cp = μ5-C5H5) to give organozirconium complexes, which are trapped with alkylsulfenyl chlorides to afford (E)-vinyl alkyl sulfides in good yield.
Ping Zhong, Xian Huang
doaj +3 more sources
In the current study, the conjugate of 3-oxo-lithocholic acid with N-methylpiperazine and paraform was synthesized using the Mannich reaction and evaluated for antiviral activity.
Anastasiya V. Petrova +7 more
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Hydrostannation of Alkynes [PDF]
In this review, we present an overview of hydrostannation of alkynes until the end of 2018. Mechanism of the tin hydride addition on a triple bond is discussed at the beginning of this review in the presence of metal catalysts as Pd, Ru-based complexes, Lewis acids and under radical conditions.
Mouad Alami +2 more
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HUISGEN AND HIS ADVENTURES IN A PLAYGROUND OF MECHANISMS AND NOVEL REACTIONS [PDF]
The death of professor Rolf Huisgen (1920-2020) was announced on March 26th 2020, in the midst of the COVID-19 pandemic. Professor Huisgen was professor emeritus at the University of Munich in Germany, and studied in detail the mechanism of the 1,3 ...
Daniel T. G. Gonzaga +5 more
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Electrochemical Hydrosilylation of Alkynes
Herein, the electrochemical hydrosilylation of alkynes is reported. In the presence of the Suginome reagent (PhMe2Si-Bpin), a large panel of terminal alkynes and internal alkynes was successfully converted into the hydrosilylated product in good to excellent yields and good selectivity in favor of the linear product.
Tony Biremond +2 more
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A terminal alkyne is one of the most useful reactants for the synthesis of alkyne and alkene derivatives. Because an alkyne undergoes addition reaction at a C–C triple bond or cross-coupling at a terminal C–H bond. Combining those reaction patterns could
Goki Hirata +4 more
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Alkynylzirconation of Alkynes and Application to One‐Pot Bisalkynylation of Alkynes. [PDF]
AbstractFor Abstract see ChemInform Abstract in Full Text.
Tamotsu Takahashi +3 more
openaire +4 more sources
A single pot, wet chemical route has been applied for the synthesis of polymer supported copper azide, CuN3, nanoparticles (CANP). The hybrid system was used as ‘catalyst-cum-reagent’ for the azide-alkyne cyclo-addition reaction to construct triazole ...
Debkumar Nandi +4 more
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Azide-Alkyne Cycloaddition Catalyzed by a Glucose/Benedict Reagent System
Benedict’s Reagent is commonly used in identifying reducing sugars through a redox process where a Cu(I) species is generated. Despite the simplicity of this reaction, this has barely been investigated as a copper (I) source for catalytic processes.
Jesús G. García Torres +5 more
doaj +1 more source

